Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon （PAH） emission in China. Pyrolysis in a coal seam was simula...Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon （PAH） emission in China. Pyrolysis in a coal seam was simulated in a tubular furnace. The 16 US Environmental Protection Agency priority controlled PAHs were analyzed by HPLC. The effects of temperature, heating rate, pyrolysis atmosphere, and coal size were investigated. The results indicate that the 3-ring PAHs AcP and AcPy are the main species in the pyrolysis gas. The 2-ring NaP and the 4-ring Pyr are also of concern. Increasing temperature caused the total PAH yield to go through a minimum. The lowest value was obtained at the temperature of 600℃. Higher heating rates promote PAH formation, especially formation of the lower molecular weight PAHs. The typical heating rate in a coal seam, 5 ℃/min, results in intermediate yields of PAHs. The total PAHs yield in an atmosphere of N2 is about 1.81 times that seen without added N2, which indicates that an air flow through the coal seam accelerates the formation of PAHs. An increase in coal particle size reduces the total PAHs emission but promotes the formation of 5- and f-ring PAHs.展开更多
In the present paper system and the solutions to the the solvability condition of the linearized Gauss-Codazzi homogenous system are given. In the meantime, the ＇solvability of a relevant linearized Darboux equation...In the present paper system and the solutions to the the solvability condition of the linearized Gauss-Codazzi homogenous system are given. In the meantime, the ＇solvability of a relevant linearized Darboux equation is given. The equations are arising in a geometric problem which is concerned with the realization of the Alexandrov＇s positive annulus in R^3.展开更多
GLARE （glass fibre/epoxy reinforced aluminum laminate） is a member of the fiber metal laminate （FML） family, and is built up of alternating metal and fiber layers. About 500 m2 GLARE is employed in each Airbus A38...GLARE （glass fibre/epoxy reinforced aluminum laminate） is a member of the fiber metal laminate （FML） family, and is built up of alternating metal and fiber layers. About 500 m2 GLARE is employed in each Airbus A380 because of the superior mechanical properties over the monolithic Muminum alloys, such as weight reduction, improved damage tolerance and higher ultimate tensile strength. Many tons of new GLARE scraps have been accumulated during the Airbus A380 manufacturing. Moreover, with the increasing plane orders of Airbus A380, more and more end-of-life （EOL） GLARE scrap will be generated after retire of planes within forty years. Thermal processing is a potential method for the material recycling and re-use from GLARE with the aim of environmental protection and economic benefits. The current study indicatdes that thermal delamination is a crucial pre-treatment step for the GLARE recycling. The decomposition behavior of the epoxy resins at elevated temperatures was investigated by using the simultaneous thermal analysis, thermogravimetry analysis （TGA） and differential scanning calorimetry （DSC）. Based on the thermal analysis results, GLARE thermal delamination experiments at refined temperatures were carried out to optimize the treatment temperature and holding time.展开更多
基金provided by the National Natural Science Foundation of China (No. 50876112)the Fundamental Research Funds for the Central Universities (No. 2009QH13)the International Scientific and Technological Cooperation Project(No. 2010DFR60610)
文摘Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon （PAH） emission in China. Pyrolysis in a coal seam was simulated in a tubular furnace. The 16 US Environmental Protection Agency priority controlled PAHs were analyzed by HPLC. The effects of temperature, heating rate, pyrolysis atmosphere, and coal size were investigated. The results indicate that the 3-ring PAHs AcP and AcPy are the main species in the pyrolysis gas. The 2-ring NaP and the 4-ring Pyr are also of concern. Increasing temperature caused the total PAH yield to go through a minimum. The lowest value was obtained at the temperature of 600℃. Higher heating rates promote PAH formation, especially formation of the lower molecular weight PAHs. The typical heating rate in a coal seam, 5 ℃/min, results in intermediate yields of PAHs. The total PAHs yield in an atmosphere of N2 is about 1.81 times that seen without added N2, which indicates that an air flow through the coal seam accelerates the formation of PAHs. An increase in coal particle size reduces the total PAHs emission but promotes the formation of 5- and f-ring PAHs.
基金Project supported by the National Natural Science Foundation of China (No. 11101068)the Fundamental Research Funds for the Central Universities (No. ZYGX2010J109)the Sichuan Youth Science and Technology Foundation (No. 2011JQ0003)
文摘In the present paper system and the solutions to the the solvability condition of the linearized Gauss-Codazzi homogenous system are given. In the meantime, the ＇solvability of a relevant linearized Darboux equation is given. The equations are arising in a geometric problem which is concerned with the realization of the Alexandrov＇s positive annulus in R^3.
基金the Royal Netherlands Academy of Science and Arts(KNAW)(No.10CDP026)the National Outstanding Young Scientist Foundation of China (No.50825401)the National Natural Science Foundation of China(No.50821003)
文摘GLARE （glass fibre/epoxy reinforced aluminum laminate） is a member of the fiber metal laminate （FML） family, and is built up of alternating metal and fiber layers. About 500 m2 GLARE is employed in each Airbus A380 because of the superior mechanical properties over the monolithic Muminum alloys, such as weight reduction, improved damage tolerance and higher ultimate tensile strength. Many tons of new GLARE scraps have been accumulated during the Airbus A380 manufacturing. Moreover, with the increasing plane orders of Airbus A380, more and more end-of-life （EOL） GLARE scrap will be generated after retire of planes within forty years. Thermal processing is a potential method for the material recycling and re-use from GLARE with the aim of environmental protection and economic benefits. The current study indicatdes that thermal delamination is a crucial pre-treatment step for the GLARE recycling. The decomposition behavior of the epoxy resins at elevated temperatures was investigated by using the simultaneous thermal analysis, thermogravimetry analysis （TGA） and differential scanning calorimetry （DSC）. Based on the thermal analysis results, GLARE thermal delamination experiments at refined temperatures were carried out to optimize the treatment temperature and holding time.
