Accurate calculation of thermodynamic properties of electrolyte solution is essential in the design and optimization of many processes in chemical industries. A new electrolyte equation of state is developed for aqueo...Accurate calculation of thermodynamic properties of electrolyte solution is essential in the design and optimization of many processes in chemical industries. A new electrolyte equation of state is developed for aqueous electrolyte solutions. The Carnahan-Starling repulsive model and an attractive term based on square-well potential are adopted to represent the short range interaction of ionic and molecular species in the new electrolyte EOS. The long range interaction of ionic species is expressed by a simplified version of Mean Spherical Approximation theory （MSA）. The new equation of state also contains a Born term for charging free energy of ions. Three adjustable parameters of new eEOS per each electrolyte solution are size parameter, square-well potential depth and square-well potential interaction range. The new eEOS is applied for correlation of mean activity coefficient and prediction of osmotic coefficient of various strong aqueous electrolyte solutions at 25℃ and 0.1 MPa. In addition, the extension of the new eEOS for correlation of mean activity coefficient and solution density of a few aqueous electrolytes at temperature range of 0 to 100℃ is carried out.展开更多
By means of a method of analytic number theory the following theorem is proved. Letp be a quasi-homogeneous linear partial differential operator with degreem,m > 0, w.r.t a dilation $\left\{ {\delta _\tau } \right\...By means of a method of analytic number theory the following theorem is proved. Letp be a quasi-homogeneous linear partial differential operator with degreem,m > 0, w.r.t a dilation $\left\{ {\delta _\tau } \right\}{\text{ }}_{\tau< 0} $ given by ( a1, …, an). Assume that either a1, …, an are positive rational numbers or $m{\text{ = }}\sum\limits_{j = 1}^n {\alpha _j \alpha _j } $ for some $\alpha {\text{ = }}\left( {\alpha _1 ,{\text{ }} \ldots {\text{ }},\alpha _n } \right) \in l _ + ^n $ Then the dimension of the space of polynomial solutions of the equationp[u] = 0 on ?n must be infinite展开更多
文摘Accurate calculation of thermodynamic properties of electrolyte solution is essential in the design and optimization of many processes in chemical industries. A new electrolyte equation of state is developed for aqueous electrolyte solutions. The Carnahan-Starling repulsive model and an attractive term based on square-well potential are adopted to represent the short range interaction of ionic and molecular species in the new electrolyte EOS. The long range interaction of ionic species is expressed by a simplified version of Mean Spherical Approximation theory （MSA）. The new equation of state also contains a Born term for charging free energy of ions. Three adjustable parameters of new eEOS per each electrolyte solution are size parameter, square-well potential depth and square-well potential interaction range. The new eEOS is applied for correlation of mean activity coefficient and prediction of osmotic coefficient of various strong aqueous electrolyte solutions at 25℃ and 0.1 MPa. In addition, the extension of the new eEOS for correlation of mean activity coefficient and solution density of a few aqueous electrolytes at temperature range of 0 to 100℃ is carried out.
基金the National Natural Science Foundation of China (Grnat No. 19971068) .
文摘By means of a method of analytic number theory the following theorem is proved. Letp be a quasi-homogeneous linear partial differential operator with degreem,m > 0, w.r.t a dilation $\left\{ {\delta _\tau } \right\}{\text{ }}_{\tau< 0} $ given by ( a1, …, an). Assume that either a1, …, an are positive rational numbers or $m{\text{ = }}\sum\limits_{j = 1}^n {\alpha _j \alpha _j } $ for some $\alpha {\text{ = }}\left( {\alpha _1 ,{\text{ }} \ldots {\text{ }},\alpha _n } \right) \in l _ + ^n $ Then the dimension of the space of polynomial solutions of the equationp[u] = 0 on ?n must be infinite
