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不锈钢熔体中氮溶解度的热力学计算模型 被引量:19
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作者 李花兵 姜周华 《东北大学学报(自然科学版)》 EI CAS CSCD 北大核心 2007年第5期672-675,共4页
在实验研究和前人研究工作的基础上,建立了一个新的不锈钢熔体中氮溶解度与体系温度、氮分压和合金成分的热力学计算模型,在该模型中引入了氮分压对氮活度系数的作用系数.该模型的计算结果与实验值吻合很好.基于该模型的计算结果,讨论... 在实验研究和前人研究工作的基础上,建立了一个新的不锈钢熔体中氮溶解度与体系温度、氮分压和合金成分的热力学计算模型,在该模型中引入了氮分压对氮活度系数的作用系数.该模型的计算结果与实验值吻合很好.基于该模型的计算结果,讨论了氮分压、温度、合金成分对不锈钢熔体中氮溶解度的影响规律.在压力较高(大于0.1 MPa)特别是合金元素较高的不锈钢熔体中,氮分压与氮的溶解度关系不符合Sievert定律.在一定氮分压下,温度对不锈钢熔体中氮溶解度的影响取决于合金体系的化学成分.在常压(氮分压为0.1 MPa)下,20%Cr-20%Mn的合金体系在1 873 K可获得氮质量分数为0.8%的高氮无镍奥氏体不锈钢. 展开更多
关键词 氮溶解度 热力学计算模型 不锈钢 高氮钢
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稀土吸氢反应热力学计算模型及应用
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作者 罗文浪 曾小荟 +1 位作者 谢安东 虞添旸 《建模与仿真》 2015年第1期33-39,共7页
根据量子力学、热力学与统计物理学和化学反应等理论,建立了稀土氢反应热力学的理论计算模型,并编制相应的计算软件,应用于几种储氢轻稀土金属La、Ce、Pr、Nd、Sm与氢反应热力学的计算,获得了La、Ce、Pr、Nd、Sm与氢反应热力学的特性,... 根据量子力学、热力学与统计物理学和化学反应等理论,建立了稀土氢反应热力学的理论计算模型,并编制相应的计算软件,应用于几种储氢轻稀土金属La、Ce、Pr、Nd、Sm与氢反应热力学的计算,获得了La、Ce、Pr、Nd、Sm与氢反应热力学的特性,结果表明La、Ce具有比Pr、Nd、Sm更好的吸氢特性,可作为稀土储氢的重点研究材料。 展开更多
关键词 稀土 吸氢反应 热力学计算模型 应用
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电弧炉粉尘直接还原炉渣氧化和脱硫能力计算热力学
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作者 彭兵 张传福 +2 位作者 彭及 LobelJ KozinskiJA 《中南工业大学学报》 CSCD 北大核心 2000年第6期497-501,共5页
电弧炉炼钢粉尘中含有多种重金属 ,若填埋弃置会对环境造成污染 .将粉尘与还原剂碳粉混合制粒后返回电弧炉 ,并补充硅铁还原粉尘中难还原的金属 ,有价金属还原后回收于钢液中 ,不仅能生产不锈钢或特种钢 ,而且能保护环境 .制粒时使用木... 电弧炉炼钢粉尘中含有多种重金属 ,若填埋弃置会对环境造成污染 .将粉尘与还原剂碳粉混合制粒后返回电弧炉 ,并补充硅铁还原粉尘中难还原的金属 ,有价金属还原后回收于钢液中 ,不仅能生产不锈钢或特种钢 ,而且能保护环境 .制粒时使用木质磺酸钙作为粘结剂 ,而木质磺酸钙中含有硫 ,可能影响钢材质量 ,影响程度取决于冶炼过程中炉渣的条件 .经改变初始熔铁、球团、硅铁和石灰加入的量比关系进行实验 ,采用X射线荧光分析仪检测炉渣成分进行计算热力学研究 ,确定了 15 5 0℃时CaO MgO FeO Fe2 O3 SiO2 S体系炉渣中各物质的浓度 (摩尔分数 )和炉渣的氧化与脱硫能力 ,其氧化能力可用n(FetO) =n(FeO) + 6n(Fe2 O3) + 8n(Fe3O4 )表示 ;此外 ,确定了还原过程中脱硫能力与氧化能力、硅铁和石灰的加入量以及炉渣的碱度之间的关系 .通过实验 ,建立了电弧炉粉尘直接还原过程中炉渣体系的计算热力学数学模型 。 展开更多
关键词 计算热力学模型 电弧炉 粉尘 炉渣 还原剂 碳粉 粘结剂 木质磺酸钙 脱硫
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氮在Fe-Cr-Mn合金体系中的溶解度计算模型 被引量:6
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作者 李花兵 姜周华 +1 位作者 张祖瑞 许宝玉 《东北大学学报(自然科学版)》 EI CAS CSCD 北大核心 2008年第4期549-552,共4页
基于前期的研究成果和规则熔体模型,建立了氮在Fe-Cr-Mn合金体系各相中氮溶解度计算模型.对18Cr-18Mn合金体系的计算结果表明,随着氮分压的增加,氮在各相中的溶解度增加,而且δ铁素体相区逐渐减小甚至消失,因此提高氮分压可避免合金体... 基于前期的研究成果和规则熔体模型,建立了氮在Fe-Cr-Mn合金体系各相中氮溶解度计算模型.对18Cr-18Mn合金体系的计算结果表明,随着氮分压的增加,氮在各相中的溶解度增加,而且δ铁素体相区逐渐减小甚至消失,因此提高氮分压可避免合金体系在凝固过程中形成气孔.适当提高合金体系中奥氏体形成元素的含量,在合金体系凝固过程中氮溶解度较小的δ相区减小甚至消失,因此可减小氮在其凝固过程中的析出趋势.该模型的计算结果与前人的研究结果吻合得较好. 展开更多
关键词 氮溶解度 Fe—Cr—Mn 高氮不锈钢 热力学计算模型
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运用ChemCAD计算氢气在烃类中的溶解度 被引量:3
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作者 王世丽 刘永刚 张瑞芹 《现代化工》 CAS CSCD 北大核心 2013年第5期114-118,共5页
运用ChemCAD闪蒸分离模块建立模拟流程,考察了8种热力学性质计算模型,结果表明API-SRK、SRK、Peng-Rob-inson 3种方法较适合研究氢气在烃中溶解度的模拟计算。氢气、间二甲苯作为进料流股组分,以进料流股组分流率比例为考察对象,流率比... 运用ChemCAD闪蒸分离模块建立模拟流程,考察了8种热力学性质计算模型,结果表明API-SRK、SRK、Peng-Rob-inson 3种方法较适合研究氢气在烃中溶解度的模拟计算。氢气、间二甲苯作为进料流股组分,以进料流股组分流率比例为考察对象,流率比值在2/1~2 664/1可完成闪蒸分离平衡计算。在温度为305.15、353、393、433 K,压力为0.8~5.0 MPa条件下,分别对氢气在间二甲苯、环已烷、苯、环已烷和苯中进行闪蒸平衡分离计算,计算结果为氢气在烃类中溶解度变化规律随温度压力的升高而增大,溶解度计算值与实验值相对偏差在5%以内。以上结果表明,选择合适的热力学性质计算模型和进料流股组分流率比例,运用ChemCAD闪蒸分离模块可准确计算氢气在烃类中溶解度。 展开更多
关键词 氢气 溶解度 CHEMCAD 热力学性质计算模型 组分流率比例
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涡流室式柴油机工作过程计算中若干问题的研究 被引量:1
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作者 严新娟 李德桃 《江苏理工大学学报(自然科学版)》 2000年第5期1-4,共4页
建立涡流室式柴油机放热规律的热力学计算模型和缸内工作过程的零维模型 在缸内工作过程计算中 ,采用了双韦伯函数作为计算模型 探讨了两个至关重要的参数———流量系数和传热系数的影响及它们的确立 针对S1 95型柴油机的不同工况... 建立涡流室式柴油机放热规律的热力学计算模型和缸内工作过程的零维模型 在缸内工作过程计算中 ,采用了双韦伯函数作为计算模型 探讨了两个至关重要的参数———流量系数和传热系数的影响及它们的确立 针对S1 95型柴油机的不同工况进行了放热分析和循环模拟 。 展开更多
关键词 涡流室柴油机 燃烧过程 零维模型 热力学计算模型 放热规模
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低排放柴油机燃烧及放热规律研究 被引量:2
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作者 庄兵 王建勇 +2 位作者 汤东 刘胜吉 罗福强 《拖拉机与农用运输车》 北大核心 2005年第1期12-13,18,共3页
柴油机的燃烧过程对其性能及排放有较大影响,随着排放要求的日益严格,柴油机采用提高喷油压力、推迟喷油来降低NOx排放。根据实测低排放柴油机气缸压力,分析其燃烧过程特性及放热规律。结果表明,推迟喷油,柴油机在大部分工况下,燃烧在... 柴油机的燃烧过程对其性能及排放有较大影响,随着排放要求的日益严格,柴油机采用提高喷油压力、推迟喷油来降低NOx排放。根据实测低排放柴油机气缸压力,分析其燃烧过程特性及放热规律。结果表明,推迟喷油,柴油机在大部分工况下,燃烧在上止点后才开始;最大压力升高率、最大燃烧压力较低,其对应相位较迟,放热峰值也较低。 展开更多
关键词 低排放柴油机 燃烧规律 放热规律 转速 负荷 计算热力学模型
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Calculation of thermodynamic properties in liquid phase for ternary Al-Ni-Zn alloys 被引量:2
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作者 D.ZIVKOVI 杜勇 +2 位作者 N.TALIJAN A.KOSTOV Lj.BALANOVI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第12期3059-3065,共7页
The results of the calculation of thermodynamic properties in liquid state for ternary Al-Ni-Zn alloys using the newest version of the general solution model for thermodynamic prediction are presented. Nine sections w... The results of the calculation of thermodynamic properties in liquid state for ternary Al-Ni-Zn alloys using the newest version of the general solution model for thermodynamic prediction are presented. Nine sections with different molar ratios of Ni to Zn, Zn to Al and Al to Ni were investigated in a temperature interval of 1800-2000 K. Partial and integral molar thermodynamic properties in liquid phase for the Al-Ni-Zn ternary system are determined and discussed. 展开更多
关键词 ternary system Al-Ni-Zn alloys THERMODYNAMICS CALCULATION general solution model
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Numerical Simulation of Direct-contact Condensation from a Supersonic Steam Jet in Subcooled Water 被引量:16
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作者 Ajmal Shah Imran Rafiq Chughtai Mansoor Hameed Inayat 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第4期577-587,共11页
The phenomenon of direct-contact condensation,used in steam driven jet injectors,nuclear reactor emergency core cooling systems and direct-contact heat exchangers,was investigated computationally by introducing a ther... The phenomenon of direct-contact condensation,used in steam driven jet injectors,nuclear reactor emergency core cooling systems and direct-contact heat exchangers,was investigated computationally by introducing a thermal equilibrium model for direct-contact condensation of steam in subcooled water.The condensation model presented was a two resistance model which takes care of the heat transfer process on both sides of the interface and uses a variable steam bubble diameter.The injection of supersonic steam jet in subcooled water tank was simulated using the Euler-Euler multiphase flow model of Fluent 6.3 code with the condensation model incorporated. The findings of the computational fluid dynamics(CFD) simulations were compared with the published experimental data and fairly good agreement was observed between the two,thus validating the condensation model.The results of CFD simulations for dimensionless penetration length of steam plume varies from 2.73-7.33,while the condensation heat transfer coefficient varies from 0.75-0.917 MW·(m ^2 ·K)^ -1 for water temperature in the range of 293-343 K. 展开更多
关键词 computational fluid dynamics condensation model direct-contact condensation heat transfer coefficient supersonic steam jet
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Effect of nonlinear liquidus and solidus on dendrite growth in bulk undercooled melts 被引量:1
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作者 陈正 王海丰 +1 位作者 刘峰 杨伟 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第3期490-494,共5页
On the base of nonlinear liquidus and solidus,an extended model for dendrite growth in bulk undercooled melts was developed under local non-equilibrium conditions both at the interface and in the bulk liquid.In terms ... On the base of nonlinear liquidus and solidus,an extended model for dendrite growth in bulk undercooled melts was developed under local non-equilibrium conditions both at the interface and in the bulk liquid.In terms of thermodynamic calculations of the phase diagram,the model predictions are relatively realistic physically,since few fitting parameters are used in the model predictions.Adopting three characteristic velocities,i.e.the critical velocity of absolute solute stability(VC*),the velocity of maximal tip radius(VRm),and the velocity of bulk liquid diffusion(VD),a quantitative agreement is obtained between the model predictions and the experimental results in undercooled Ni-0.7%B and Ni-1%Zr(molar fraction) alloys,and the overall solidification process can be categorized. 展开更多
关键词 dendrite growth undercooled melts Ni-based alloys
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Presence of Contaminants in Refrigerant and Their Effect on Refrigeration Cycle
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作者 Dorota Skrzyniowska 《Journal of Energy and Power Engineering》 2014年第2期226-231,共6页
Refrigerant is a medium used in refrigeration cycle. Until now in thermodynamic models calculations of refrigerant is not considered with lubricant and moist air but as an ideal pure gas (without any contaminants). ... Refrigerant is a medium used in refrigeration cycle. Until now in thermodynamic models calculations of refrigerant is not considered with lubricant and moist air but as an ideal pure gas (without any contaminants). This is also the case in refrigeration cycle where the refrigerant is very often considered as an ideal one. Lubricant, air and water vapour are not considered in thermodynamic calculations in spite of their existence. The problems in the existing research are summarized. A further study is suggested on refrigerant systems. This circulation of such calculations is at the origin of a deviation from a theoretical behaviour. This article aims at reviewing the researches of oil-refrigerant, air-refrigerant, moist air-refrigerant or oil-moist air-refrigerant mixtures and focuses particularly on mixture enthalpy calculation. This paper deals with the description of the real mixture of refrigerant and contaminants (lubricant, water, moist air and other remains of refrigerants at elevated pressures and temperatures) which flow in a refrigerating cycle and the main point of this paper is to appoint thermodynamic parameters of such a mixture using the thermodynamic formulas. 展开更多
关键词 Refrigeration system compression system LUBRICATION OIL modeling air conditioning compressed air THERMODYNAMIC specific enthalpy.
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Laminar Heat Transfer Modeling and Investigation of Thermal Dispersion in a Flat Plate Heat Exchanger: Estimating Heat Transfer Coefficient, Heat Flux and Nusselt Number
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作者 Saeedeh Imani Moqadam Mojtaba Mirdrikvand Behrooz Roozbehani Amirali Rezazadeh 《Journal of Chemistry and Chemical Engineering》 2012年第7期613-618,共6页
PHEs (plate heat exchangers) are among the most common thermal equipments in diverse industries particularly in oil and gas companies. This wide usage is obviously due to significant benefits of these heat exchanger... PHEs (plate heat exchangers) are among the most common thermal equipments in diverse industries particularly in oil and gas companies. This wide usage is obviously due to significant benefits of these heat exchangers over other types. In this article, a behavioral analysis of heat transfer in fiat plates of these heat exchangers in laminar flow situation through CFD (computational fluid dynamics) simulation using FLUENT 6.3.26 software is done. The study reveals results graphically based on fluid's behavior in co-current and counter current flows and discusses thermal indexes consisting of heat transfer coefficient, Nusslet and total heat flux in both conditions. Eventually, a comparison via the graphical results is presented between the two types of flow directions. 展开更多
关键词 Flat plate heat exchanger nusslet heat flux heat transfer coefficient FLUENT CFD.
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Numerical Simulation of Air-cooling Tower 被引量:1
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作者 Lijuan Hao Huanzhi Li Zhaohu Sun Lige TongThermal Energy Department, Beijing University of Science and Technology, Beijing 100083, China 《Journal of Thermal Science》 SCIE EI CAS CSCD 2003年第3期264-269,共6页
A mathematic model for packed air-cooling tower thermodynamic calculation is set up in this paper on the basis of fundamental heat and mass transfer equations. Based on the Double Film theory, direct equation-solving ... A mathematic model for packed air-cooling tower thermodynamic calculation is set up in this paper on the basis of fundamental heat and mass transfer equations. Based on the Double Film theory, direct equation-solving method is used to simulate air-cooling tower, and variation of parameters is taken to analyze the data and results of the program. 展开更多
关键词 packing air-cooling tower computer simulation mathematic model
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