The high-pressure hydrogenation heat exchanger is an impoltmlt equipment of the refinery, but it is exposed tothe problem of leakage caused by ammonium salt corrosion. Therefore, it is very important to evaluate the o...The high-pressure hydrogenation heat exchanger is an impoltmlt equipment of the refinery, but it is exposed tothe problem of leakage caused by ammonium salt corrosion. Therefore, it is very important to evaluate the operating statusof flae hydrogenation heat exchanger. To improve flae method for evaluating the operating status of hydrogenation heat ex-chmagers by using flae traditional method, flais paper proposes a new method for evaluating the operation of hydrogenationheat exchangers based on big data. To address flae noisy data common in flae industry, this paper proposes an automatednoisy interval detection algorithm. To deal with flae problem that the sensor parameters have voluminous and mtrelateddimensions, flais paper proposes a key parameter detection algorithm based on flae Pearson correlation coefficient. Finally,this paper presents a system-based health scoring algorithm based on PCA （Principal Component Analysis） to assist site op-erators in assessing the healfla of hydrogenation heat exchangers. The evaluation of flae operating status of flae hydrorefiningheat exchange device based on big data technology will help the operators to more accurately grasp the status of flae indus-trial system mad have positive guiding significance for the early warning offlae failure.展开更多
In this work,azobenzene-containing polyurethane liquid crystal networks(PULCN(AZO)s)were synthesized using a one-pot strategy to demonstrate excellent two-way free-standing thermo-/photo-responsive shape memory effect...In this work,azobenzene-containing polyurethane liquid crystal networks(PULCN(AZO)s)were synthesized using a one-pot strategy to demonstrate excellent two-way free-standing thermo-/photo-responsive shape memory effects.Based on the step-growth nature of hydroxyls and isocyanates,the architectures of the networks were adjusted by controlling the stoichiometries of chemical materials.A uniform monodomain sample was prepared by external stress relaxation via a reversible addition reaction of a dynamic carbamate bond.Two independent transition temperatures assigned to glass transition temperature/melting temperature and liquid crystal phase transition temperature were employed to thermally trigger triple shape memory effects and two-way autonomous actuation.In addition,taking advantage of the trans-cis photoisomerization of azobenzene,the programmed network showed a reversible bending and unbending shape change upon irradiation by visible light at450 and 550 nm,respectively.Coupling the autonomously thermo-induced contraction/extension actuation and reversible photo-induced bending/unbending behaviors of PULCN(AZO)s in one system will expand their potential applications in emerging multifunctional devices.展开更多
基金supported by the National Natural Science Foundation of China (U1534201)the open project of Science and Technology on Communication Networks Laboratorythe National Key Research and Development Program of China (2016QY01W0200)
文摘The high-pressure hydrogenation heat exchanger is an impoltmlt equipment of the refinery, but it is exposed tothe problem of leakage caused by ammonium salt corrosion. Therefore, it is very important to evaluate the operating statusof flae hydrogenation heat exchanger. To improve flae method for evaluating the operating status of hydrogenation heat ex-chmagers by using flae traditional method, flais paper proposes a new method for evaluating the operation of hydrogenationheat exchangers based on big data. To address flae noisy data common in flae industry, this paper proposes an automatednoisy interval detection algorithm. To deal with flae problem that the sensor parameters have voluminous and mtrelateddimensions, flais paper proposes a key parameter detection algorithm based on flae Pearson correlation coefficient. Finally,this paper presents a system-based health scoring algorithm based on PCA （Principal Component Analysis） to assist site op-erators in assessing the healfla of hydrogenation heat exchangers. The evaluation of flae operating status of flae hydrorefiningheat exchange device based on big data technology will help the operators to more accurately grasp the status of flae indus-trial system mad have positive guiding significance for the early warning offlae failure.
基金supported financially by the National Natural Science Foundation of China(51773131 and 51721091)the Fundamental Research Funds for the Central Universities。
文摘In this work,azobenzene-containing polyurethane liquid crystal networks(PULCN(AZO)s)were synthesized using a one-pot strategy to demonstrate excellent two-way free-standing thermo-/photo-responsive shape memory effects.Based on the step-growth nature of hydroxyls and isocyanates,the architectures of the networks were adjusted by controlling the stoichiometries of chemical materials.A uniform monodomain sample was prepared by external stress relaxation via a reversible addition reaction of a dynamic carbamate bond.Two independent transition temperatures assigned to glass transition temperature/melting temperature and liquid crystal phase transition temperature were employed to thermally trigger triple shape memory effects and two-way autonomous actuation.In addition,taking advantage of the trans-cis photoisomerization of azobenzene,the programmed network showed a reversible bending and unbending shape change upon irradiation by visible light at450 and 550 nm,respectively.Coupling the autonomously thermo-induced contraction/extension actuation and reversible photo-induced bending/unbending behaviors of PULCN(AZO)s in one system will expand their potential applications in emerging multifunctional devices.
