The complicated reaction mechanism and the character of competitive reactions lead to a stringent requirement for the catalyst of C_4 alkylation process. Due to their unique properties, ionic liquids(ILs) are thought ...The complicated reaction mechanism and the character of competitive reactions lead to a stringent requirement for the catalyst of C_4 alkylation process. Due to their unique properties, ionic liquids(ILs) are thought to be new potential acid catalysts for C_4 alkylation. An analysis of the regular and modified chloroaluminate ILs, novel Br?nsted ILs and composite ILs used in isobutane/butene alkylation shows that the use of either ILs or ILs coupled with mineral acid as homogeneous catalysts can help to greatly adjust the acid strength. By modifying the structural parameters of the cations and anions of the ILs, the solubility of the reactants could also be adjusted, which in turn displays a positive effect on improving the activity of ILs. Immobilization of ILs is an effective way to modulate the surface adsorption/desorption properties and acid strength distribution of the solid acid catalysts. Such a process has a tremendous potential to reduce the deactivation of catalyst and enhance the activity of the solid acid catalyst. The development of novel acid catalysts for C_4 alkylation is a comprehensive consideration of acid strength and its distribution, interfacial properties and transport characteristics.展开更多
In this paper, we established a finite element (FEM) model to analyze the dynamic characteristics of arch bridges. In this model, the effects of adjustment to the length of a suspender on its geometry stiffness matrix...In this paper, we established a finite element (FEM) model to analyze the dynamic characteristics of arch bridges. In this model, the effects of adjustment to the length of a suspender on its geometry stiffness matrix are stressed. The FEM equations of mechanics characteristics, natural frequency and main mode are set up based on the first order matrix perturbation theory. Applicantion of the proposed model to analyze a real arch bridge proved the improvement in the simulation precision of dynamical characteristics of the arch bridge by considering the effects of suspender length variation.展开更多
A type of two qubits Josephson charge system is constructed, and properties of the quantum discord （QD） as well as the differences between thermal QD and thermal entanglement are investigated. A detailed calculation...A type of two qubits Josephson charge system is constructed, and properties of the quantum discord （QD） as well as the differences between thermal QD and thermal entanglement are investigated. A detailed calculation shows that the magnetic flux is more efficient than the voltage in tuning QD. By choosing proper system parameter the maximum QD can be realized in our two qubits Josephson charge system.展开更多
Here, we propose a simple scheme to realize a one-dimensional （1D） modulated Rice-Mele model （RMM） and investigate its topological properties with a 1D circuit quantum electrodynamics （QED） lattice. The system c...Here, we propose a simple scheme to realize a one-dimensional （1D） modulated Rice-Mele model （RMM） and investigate its topological properties with a 1D circuit quantum electrodynamics （QED） lattice. The system can be mapped into a Chern insulator model by introducing a period parameter. Interestingly and surprisingly, we found that the circuit-QED lattice system always exhibits topologically nonttrvial phases if both the nearest-neighbor hopping strength between two resonators and the qubitassisted on-site potentials are alternately changed in the direction of the lattice. The numerical results show that the topological phases can be obtained by introducing an additional modulation parameter and both the edge state and topological invariant can be unambiguously seen with the existence of decay and disorders, even with few resonators in the lattice.展开更多
基金Supported by the National Natural Science Foundation of China(21276163,21576168)
文摘The complicated reaction mechanism and the character of competitive reactions lead to a stringent requirement for the catalyst of C_4 alkylation process. Due to their unique properties, ionic liquids(ILs) are thought to be new potential acid catalysts for C_4 alkylation. An analysis of the regular and modified chloroaluminate ILs, novel Br?nsted ILs and composite ILs used in isobutane/butene alkylation shows that the use of either ILs or ILs coupled with mineral acid as homogeneous catalysts can help to greatly adjust the acid strength. By modifying the structural parameters of the cations and anions of the ILs, the solubility of the reactants could also be adjusted, which in turn displays a positive effect on improving the activity of ILs. Immobilization of ILs is an effective way to modulate the surface adsorption/desorption properties and acid strength distribution of the solid acid catalysts. Such a process has a tremendous potential to reduce the deactivation of catalyst and enhance the activity of the solid acid catalyst. The development of novel acid catalysts for C_4 alkylation is a comprehensive consideration of acid strength and its distribution, interfacial properties and transport characteristics.
基金Supported by the Key Teacher Foundation of Chongqing University (No. 717411067)
文摘In this paper, we established a finite element (FEM) model to analyze the dynamic characteristics of arch bridges. In this model, the effects of adjustment to the length of a suspender on its geometry stiffness matrix are stressed. The FEM equations of mechanics characteristics, natural frequency and main mode are set up based on the first order matrix perturbation theory. Applicantion of the proposed model to analyze a real arch bridge proved the improvement in the simulation precision of dynamical characteristics of the arch bridge by considering the effects of suspender length variation.
文摘A type of two qubits Josephson charge system is constructed, and properties of the quantum discord （QD） as well as the differences between thermal QD and thermal entanglement are investigated. A detailed calculation shows that the magnetic flux is more efficient than the voltage in tuning QD. By choosing proper system parameter the maximum QD can be realized in our two qubits Josephson charge system.
基金supported by the National Natural Science Foundation of China(Grant Nos.11465020,11264042,61465013,and 11564041)the Project of Jilin Science and Technology Development for Leading Talent of Science and Technology Innovation in Middle and Young and Team Project(Grant No.20160519022JH)
文摘Here, we propose a simple scheme to realize a one-dimensional （1D） modulated Rice-Mele model （RMM） and investigate its topological properties with a 1D circuit quantum electrodynamics （QED） lattice. The system can be mapped into a Chern insulator model by introducing a period parameter. Interestingly and surprisingly, we found that the circuit-QED lattice system always exhibits topologically nonttrvial phases if both the nearest-neighbor hopping strength between two resonators and the qubitassisted on-site potentials are alternately changed in the direction of the lattice. The numerical results show that the topological phases can be obtained by introducing an additional modulation parameter and both the edge state and topological invariant can be unambiguously seen with the existence of decay and disorders, even with few resonators in the lattice.
