Cu2O@Cu2O core-shell nanoparticles (NPs) were prepared by using solution phase strategy. It was found that Cu2O@Cu2O NPs were easily converted to Cu2O@Cu NPs with the help of polyvinylpyrrolidine (PVP) and excessive a...Cu2O@Cu2O core-shell nanoparticles (NPs) were prepared by using solution phase strategy. It was found that Cu2O@Cu2O NPs were easily converted to Cu2O@Cu NPs with the help of polyvinylpyrrolidine (PVP) and excessive ascorbic acid (AA) in air at room temperature, which was an interesting phenomenon. The features of the two kinds of NPs were characterized by XRD, TEM and extinction spectra. Cu2O@Cu NPs with different shell thicknesses showed wide tunable optical properties for the localized surface plasmon (LSP) in metallic Cu. But Cu2O@Cu2O NPs did not indicate this feature. FTIR results reveal that Cu+ ions on the surface of Cu2O shell coordinate with N and O atoms in PVP and are further reduced to metallic Cu by excessive AA and then form a nucleation site on the surface of Cu2O nanocrystalline. PVP binds onto different sites to proceed with the reduction utill all the Cu sources in Cu2O shell are completely assumed.展开更多
Based on real-time digital simulations(RTDS),a laboratory environment similar to the real-time operation situation of the Three Gorges Hydropower Station is established.Then,the causes for the power fluctuation of the...Based on real-time digital simulations(RTDS),a laboratory environment similar to the real-time operation situation of the Three Gorges Hydropower Station is established.Then,the causes for the power fluctuation of the second generator by errors in the rotor rotating speed calculation are found,and the tuning method of the speed related parameters are given.The damping and reverse tuning characteristics of power system stabilizers(PSSs)in the digital automatic voltage regulator(AVR)are compared and investigated in the frequency range of 0.18-1.1 Hz.The efficiency of the proposed tuning method for ensuring power system stability is verified by RTDS.Finally,field tests show the validity of the laboratory test results.展开更多
Recently ionic liquids(ILs) are introduced as novel dual function gas hydrate inhibitors. However, no desired gas hydrate inhibition has been reported due to poor IL selection and/or tuning method. Trial & error a...Recently ionic liquids(ILs) are introduced as novel dual function gas hydrate inhibitors. However, no desired gas hydrate inhibition has been reported due to poor IL selection and/or tuning method. Trial & error as well as selection based on existing literature are the methods currently employed for selecting and/or tuning ILs. These methods are probabilistic, time consuming, expensive and may not result in selecting high performance ILs for gas hydrate mitigation. In this work, COSMO-RS is considered as a prescreening tool of ILs for gas hydrate mitigation by predicting the hydrogen bonding energies(E_(HB)) of studied IL inhibitors and comparing the predicted E_(HB) to the depression temperature(?) and induction time. Results show that, predicted EHBand chain length of ILs strongly relate and significantly affect the gas hydrate inhibition depression temperature but correlate moderately(R = 0.70) with average induction time in literature. It is deduced from the results that, ? increases with increasing IL EHBand/or decreases with increasing chain length. However, the cation–anion pairing of ILs also affects IL gas hydrate inhibition performance. Furthermore, a visual and better understanding of IL/water behavior for gas hydrate inhibition in terms of hydrogen bond donor and acceptor interaction analysis is also presented by determining the sigma profile and sigma potential of studied IL cations and anions used for gas hydrate mitigation for easy IL selection.展开更多
Gravitational contributions to the running of gauge couplings are calculated by using different regularizationschemes.As the β function concerns counter-terms of dimension four, only quadratic divergences from the gr...Gravitational contributions to the running of gauge couplings are calculated by using different regularizationschemes.As the β function concerns counter-terms of dimension four, only quadratic divergences from the gravitationalcontributions need to be investigated.A consistent result is obtained by using a symmetry-preserving loop regularizationwith string-mode regulators which can appropriately treat the quadratic divergences and preserve non-abelian gaugesymmetry.The harmonic gauge condition for gravity is used in both diagrammatical and background field calculations,the resulting gravitational corrections to the β function are found to be nonzero, which is different from previous resultspresented in the existing literatures.展开更多
The paper deals with analysis and synthesis of non-harmonic and non-linear sources and appliances, and their interaction with harmonic power supply network. Basic idea is based on knowledge of harmonic spectrum of the...The paper deals with analysis and synthesis of non-harmonic and non-linear sources and appliances, and their interaction with harmonic power supply network. Basic idea is based on knowledge of harmonic spectrum of the sources and/or appliances, respectively. Obviously, one need to know voltage harmonic components of voltage sources (renewable with inverters,...), and current harmonic components generated by non-linear appliances (rectifiers,...). Method of investigation lies on decomposition of real electric circuit into n-harmonic separated equivalent schemes for each harmonic component. Then transient analysis will be done for each scheme separately using "impedance harmonic matrices". The important fact is that each equivalent scheme is now linearized and therefore easily calculated. Finally, the effects of each investigated schemes arc summed into resulting quantities of real non-linear electric circuit.展开更多
基金Projects(41172110,61107090)supported by the National Natural Science Foundation of China
文摘Cu2O@Cu2O core-shell nanoparticles (NPs) were prepared by using solution phase strategy. It was found that Cu2O@Cu2O NPs were easily converted to Cu2O@Cu NPs with the help of polyvinylpyrrolidine (PVP) and excessive ascorbic acid (AA) in air at room temperature, which was an interesting phenomenon. The features of the two kinds of NPs were characterized by XRD, TEM and extinction spectra. Cu2O@Cu NPs with different shell thicknesses showed wide tunable optical properties for the localized surface plasmon (LSP) in metallic Cu. But Cu2O@Cu2O NPs did not indicate this feature. FTIR results reveal that Cu+ ions on the surface of Cu2O shell coordinate with N and O atoms in PVP and are further reduced to metallic Cu by excessive AA and then form a nucleation site on the surface of Cu2O nanocrystalline. PVP binds onto different sites to proceed with the reduction utill all the Cu sources in Cu2O shell are completely assumed.
文摘Based on real-time digital simulations(RTDS),a laboratory environment similar to the real-time operation situation of the Three Gorges Hydropower Station is established.Then,the causes for the power fluctuation of the second generator by errors in the rotor rotating speed calculation are found,and the tuning method of the speed related parameters are given.The damping and reverse tuning characteristics of power system stabilizers(PSSs)in the digital automatic voltage regulator(AVR)are compared and investigated in the frequency range of 0.18-1.1 Hz.The efficiency of the proposed tuning method for ensuring power system stability is verified by RTDS.Finally,field tests show the validity of the laboratory test results.
文摘Recently ionic liquids(ILs) are introduced as novel dual function gas hydrate inhibitors. However, no desired gas hydrate inhibition has been reported due to poor IL selection and/or tuning method. Trial & error as well as selection based on existing literature are the methods currently employed for selecting and/or tuning ILs. These methods are probabilistic, time consuming, expensive and may not result in selecting high performance ILs for gas hydrate mitigation. In this work, COSMO-RS is considered as a prescreening tool of ILs for gas hydrate mitigation by predicting the hydrogen bonding energies(E_(HB)) of studied IL inhibitors and comparing the predicted E_(HB) to the depression temperature(?) and induction time. Results show that, predicted EHBand chain length of ILs strongly relate and significantly affect the gas hydrate inhibition depression temperature but correlate moderately(R = 0.70) with average induction time in literature. It is deduced from the results that, ? increases with increasing IL EHBand/or decreases with increasing chain length. However, the cation–anion pairing of ILs also affects IL gas hydrate inhibition performance. Furthermore, a visual and better understanding of IL/water behavior for gas hydrate inhibition in terms of hydrogen bond donor and acceptor interaction analysis is also presented by determining the sigma profile and sigma potential of studied IL cations and anions used for gas hydrate mitigation for easy IL selection.
基金Supported by the National Natural Science Foundation of China under Grant Nos.10821504,10491306,10975170 the Project of Knowledge Innovation Program of Chinese Academy of Science
文摘Gravitational contributions to the running of gauge couplings are calculated by using different regularizationschemes.As the β function concerns counter-terms of dimension four, only quadratic divergences from the gravitationalcontributions need to be investigated.A consistent result is obtained by using a symmetry-preserving loop regularizationwith string-mode regulators which can appropriately treat the quadratic divergences and preserve non-abelian gaugesymmetry.The harmonic gauge condition for gravity is used in both diagrammatical and background field calculations,the resulting gravitational corrections to the β function are found to be nonzero, which is different from previous resultspresented in the existing literatures.
文摘The paper deals with analysis and synthesis of non-harmonic and non-linear sources and appliances, and their interaction with harmonic power supply network. Basic idea is based on knowledge of harmonic spectrum of the sources and/or appliances, respectively. Obviously, one need to know voltage harmonic components of voltage sources (renewable with inverters,...), and current harmonic components generated by non-linear appliances (rectifiers,...). Method of investigation lies on decomposition of real electric circuit into n-harmonic separated equivalent schemes for each harmonic component. Then transient analysis will be done for each scheme separately using "impedance harmonic matrices". The important fact is that each equivalent scheme is now linearized and therefore easily calculated. Finally, the effects of each investigated schemes arc summed into resulting quantities of real non-linear electric circuit.