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萃取技术在药物分析中的应用 被引量:3
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作者 屈颖 《天津药学》 2009年第1期59-62,共4页
简要介绍几种色谱分析样品处理技术中萃取技术的原理和特点,以及在天然药物有效成分的提取、鉴定、含量测定及生物样品中药物的检测和药物有机残留溶剂残留量测定等方面的应用。
关键词 谱分析样品处理 加速溶剂萃取 超临界流体萃取 微波辅助萃取 固相微萃取 液相微萃取
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高温热处理毛竹材诱发变色机理研究 被引量:10
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作者 沈钰程 王云芳 +1 位作者 汤颖 李延军 《竹子研究汇刊》 北大核心 2013年第4期42-45,共4页
采用4年生中部毛竹,对其进行160℃、180℃、200℃热处理2 h。定性观察高温热处理后毛竹颜色的直观变化,借助化学成分分析和红外光谱分析方法,研究高温热处理竹材的诱发变色机理。结果表明:高温热处理后,竹材木质素含量上升,增加了20.89... 采用4年生中部毛竹,对其进行160℃、180℃、200℃热处理2 h。定性观察高温热处理后毛竹颜色的直观变化,借助化学成分分析和红外光谱分析方法,研究高温热处理竹材的诱发变色机理。结果表明:高温热处理后,竹材木质素含量上升,增加了20.89%。木质素中发色基团增多,助色基团也发生了变化,从而导致了热处理竹材的诱发变色。特征官能团甲氧基峰值发生蓝移,波长减小,使得竹片外观颜色变深。 展开更多
关键词 采用4年生中部毛竹 对其进行160℃、180℃、200℃热处理2h 定性观察高温热处理后毛竹颜色的直观变化 借助化学成分分析和红外光谱分析方法 研究高温热处理竹材的诱发变色机理 结果表明 高温热处理 竹材木质素含量上升 增加了20 89% 木质素中发色基团增多 助色基团也发生了变化 从而导致了热处理竹材的诱发变色 特征官能团甲氧基峰值发生蓝移 波长减小 使得竹片外观颜色变深 高温热处理 毛竹 变色机理 木质素 FTIR
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聚束式SAR的宽场景成像算法 被引量:7
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作者 井伟 张磊 +1 位作者 邢孟道 保铮 《电子学报》 EI CAS CSCD 北大核心 2009年第3期470-475,共6页
提出了基于SPECAN处理的宽场景聚束式SAR成像算法.首先对距离Dechirp后的信号在方位上作谱分析(SPECAN)处理消除方位模糊并对信号支撑区进行伸缩与平移变换,二次相位补偿后选择合适的插值方法恢复信号理想支撑区,最后二维IFFT成像.讨论... 提出了基于SPECAN处理的宽场景聚束式SAR成像算法.首先对距离Dechirp后的信号在方位上作谱分析(SPECAN)处理消除方位模糊并对信号支撑区进行伸缩与平移变换,二次相位补偿后选择合适的插值方法恢复信号理想支撑区,最后二维IFFT成像.讨论并给出了算法对脉冲重复频率选择的限制.仿真实验验证了该方法的有效性. 展开更多
关键词 雷达成像 聚束SAR 谱分析处理 宽场景成像
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一种基于SPECAN卷积的聚束式SAR宽场景高分辨成像算法
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作者 张士明 计科峰 《现代电子技术》 2010年第19期35-38,共4页
针对聚束式SAR成像,提出了一种基于谱分析(SPECAN)卷积的宽场景高分辨成像算法。该算法主要利用SPECAN卷积对回波方位实现了多普勒去模糊,推导二次相位补偿项,可实现信号支撑区相干性恢复。利用SPECAN卷积和相位补偿实现了信号二维频谱... 针对聚束式SAR成像,提出了一种基于谱分析(SPECAN)卷积的宽场景高分辨成像算法。该算法主要利用SPECAN卷积对回波方位实现了多普勒去模糊,推导二次相位补偿项,可实现信号支撑区相干性恢复。利用SPECAN卷积和相位补偿实现了信号二维频谱解模糊,同时保持了相位规律,所以可利用高精度的距离徙动算法(RMA)实现高分辨聚焦。区别于传统的聚束式SAR成像算法,基于SPECAN卷积的算法不引入近似,可应用于大场景高分辨聚束成像。仿真试验验证了该方法的有效性和优越性。 展开更多
关键词 聚束SAR 谱分析处理 宽场景高分辨成像 二次相位补偿
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Spectral Analysis for HSS Preconditioners 被引量:3
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作者 Lung Chak Chan Michael K. Ng Nam Kiu Tsing 《Numerical Mathematics(Theory,Methods and Applications)》 SCIE 2008年第1期57-77,共21页
In this paper,we are interested in HSS preconditioners for saddle point lin- ear systems with a nonzero(2,2)-th block.We study an approximation of the spectra of HSS preconditioned matrices and use these results to il... In this paper,we are interested in HSS preconditioners for saddle point lin- ear systems with a nonzero(2,2)-th block.We study an approximation of the spectra of HSS preconditioned matrices and use these results to illustrate and explain the spectra obtained from numerical examples,where the previous spectral analysis of HSS precon- ditioned matrices does not cover. 展开更多
关键词 Saddle point problems iterative methods PRECONDITIONING EIGENVALUES
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Speed-up for N-FINDR algorithm 被引量:1
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作者 王立国 张晔 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2008年第1期141-144,共4页
N-FINDR is a very popular algorithm of endmember (EM) extraction for its automated property and high efficiency. Unfortunately, innumerable volume calculation, initial random selection of EMs and blind searching for E... N-FINDR is a very popular algorithm of endmember (EM) extraction for its automated property and high efficiency. Unfortunately, innumerable volume calculation, initial random selection of EMs and blind searching for EMs lead to low speed of the algorithm and limit the applications of the algorithm. So in this paper two measures are proposed to speed up the algorithm. One of the measures is substituting distance calculation for volume calculation. Thus the avoidance of volume calculation greatly decreases the computational cost. The other measure is resorting dataset in terms of pixel purity likelihood based on pixel purity index (PPI) concept. Then, initial EMs can be selected well-founded and a fast searching for EMs is achieved. Numerical experiments show that the two measures speed up the original algorithm hundreds of times as the number of EMs is more than ten. 展开更多
关键词 endmember extraction N-FINDR algorithm PPI algorithm spectral unmixing
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Least Squares Spectral Analysis and Its Application to Superconducting Gravimeter Data Analysis 被引量:2
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作者 YINHui SpirosD.Pagiatakis 《Geo-Spatial Information Science》 2004年第4期279-283,共5页
Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inhere... Detection of a periodic signal hidden in noise is the goal of Superconducting Gravimeter (SG) data analysis. Due to spikes, gaps, datum shrifts (offsets) and other disturbances, the traditional FFT method shows inherent limitations. Instead, the least squares spectral analysis (LSSA) has showed itself more suitable than Fourier analysis of gappy, unequally spaced and unequally weighted data series in a variety of applications in geodesy and geophysics. This paper reviews the principle of LSSA and gives a possible strategy for the analysis of time series obtained from the Canadian Superconducting Gravimeter Installation (CGSI), with gaps, offsets, unequal sampling decimation of the data and unequally weighted data points. 展开更多
关键词 least squares spectrum superconducting gravimeter data analysis
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Feature extraction for target identification and image classification of OMIS hyperspectral image 被引量:7
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作者 DU Pei-jun TAN Kun SU Hong-jun 《Mining Science and Technology》 EI CAS 2009年第6期835-841,共7页
In order to combine feature extraction operations with specific hyperspectral remote sensing information processing objectives,two aspects of feature extraction were explored. Based on clustering and decision tree alg... In order to combine feature extraction operations with specific hyperspectral remote sensing information processing objectives,two aspects of feature extraction were explored. Based on clustering and decision tree algorithm,spectral absorption index (SAI),continuum-removal and derivative spectral analysis were employed to discover characterized spectral features of different targets,and decision trees for identifying a specific class and discriminating different classes were generated. By combining support vector machine (SVM) classifier with different feature extraction strategies including principal component analysis (PCA),minimum noise fraction (MNF),grouping PCA,and derivate spectral analysis,the performance of feature extraction approaches in classification was evaluated. The results show that feature extraction by PCA and derivate spectral analysis are effective to OMIS (operational modular imaging spectrometer) image classification using SVM,and SVM outperforms traditional SAM and MLC classifiers for OMIS data. 展开更多
关键词 hyperspectral remote sensing feature extraction decision tree SVM OMIS
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Municipal Landfill as a Source of Fulvic Acids Polluting Water
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作者 Tomasz Orliński Anna M. Anielak 《Journal of Civil Engineering and Architecture》 2018年第6期462-469,共8页
The FAs (fulvic acids) belong to natural organic contaminants that are commonly found in different environments. In the process of oxidation and disinfection FAs are precursors of toxic substances, which cause a pro... The FAs (fulvic acids) belong to natural organic contaminants that are commonly found in different environments. In the process of oxidation and disinfection FAs are precursors of toxic substances, which cause a problem in many water treatment plants. In the sewage treatment plants, FAs are not biodegradable and together with purified wastewater and are discharged into surface waters. One of important source of the formation of FAs is the municipal landfill. In this thesis the authors test the amount of soluble fulvic acids present in the leachate of Barycz landfill in Krakow. The extracted FAs were subjected to a detailed analysis for the content of metals and IR spectrum analysis has also been done. Basing on elemental composition the C/O, C/H and C/N ratios have been determined. The obtained data were compared with the characteristics specified in the literature. 展开更多
关键词 Fulvic acids humic acids humic substances LANDFILL LEACHATE WASTE
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Designing of Acousto-optic Spectrum Analyzer
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作者 WANGDan-zhi SHAODing-rong LIShu-jian 《Semiconductor Photonics and Technology》 CAS 2004年第4期237-239,共3页
The structure of the acousto-optic spectrum analyzer was investigated including the RF amplifying circuit, the optical structures and the postprocessing circuit, and the design idea of the module was applied to design... The structure of the acousto-optic spectrum analyzer was investigated including the RF amplifying circuit, the optical structures and the postprocessing circuit, and the design idea of the module was applied to design the spectrum analyzer. The modularization spectrum analyzer takes on the performance stabilization and higher reliability, and according to different demands, the different modules can be used. The spectrum analyzer had such performances as the detecting frequency precision of 1 MHz, the detecting frequency error of 0.58 MHz, detecting responsivity of 90 dBm and bandwidth of 50 MHz. 展开更多
关键词 Acousto-optic signal processing Spectrum analyzer Structures designing
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Study on the removal of toxic substance from river water using O_3-GAC process
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作者 杨玉楠 孙志荣 +2 位作者 王宝贞 杨敏 李文兰 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2004年第4期447-451,共5页
This paper studied on the removal of toxic substance from river water using O3-GAC process. The result of GC/MS analysis indicated that the number of organic compound species was decreased by 55.1%. The species of tox... This paper studied on the removal of toxic substance from river water using O3-GAC process. The result of GC/MS analysis indicated that the number of organic compound species was decreased by 55.1%. The species of toxic substance of raw water also decreased from 16 to 5. The total removal rate of CODMn andUV254 were 45%~72% and 60%~80% following O3-GAC treatment. It reflected that this process had a good effective on removing unsaturation organic which absorb UV and toxic organic containing nitrogen. The results of Ames test indicated that raw water had a relatively strong mutagicity on TA 98. The O3-GAC process had a good ability in removing mutagen in water. The effluent water’s mutagicity is minus. The results of the study indicated that the effluent of the O3-GAC process was meet the demand of drinking water. 展开更多
关键词 removal of toxic substance O_3-GAC process GC/MS analysis
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Diethylstilbestrol in Fish Tissue Determined Through Subcritical Fluid Extraction and with GC-MS 被引量:1
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作者 QIAO Qinghui SHI Nianrong +3 位作者 FENG Xiaomei LU Jie HAN Yuqian XUE Changhu 《Journal of Ocean University of China》 SCIE CAS 2016年第3期489-494,共6页
As the key point in sex hormone analysis, sample pre-treatment technology has attracted scientists' attention all over the world, and the development trend of sample preparation forwarded to faster and more effici... As the key point in sex hormone analysis, sample pre-treatment technology has attracted scientists' attention all over the world, and the development trend of sample preparation forwarded to faster and more efficient technologies. Taking economic and environmental concerns into account, subcritical fluid extraction as a faster and more efficient method has stood out as a sample pre-treatment technology. This new extraction technology can overcome the shortcomings of supercritical fluid and achieve higher extraction efficiency at relatively low pressures and temperatures. In this experiment, a simple, sensitive and efficient method has been developed for the determination of diethylstilbestrol(DES) in fish tissue using subcritical 1,1,1,2-tetrafluoroethane(R134a) extraction in combination with gas chromatography-mass spectrometry(GC-MS). After extraction, freezing-lipid filtration was utilized to remove fatty co-extract. Further purification steps were performed with C_(18) and NH_2 solid phase extraction(SPE). Finally, the analyte was derived by heptafluorobutyric anhydride(HFBA), followed by GC-MS analysis. Response surface methodology(RSM) was employed to optimizing the extraction condition, and the optimized was as follows: extraction pressure, 4.3 MPa; extraction temperature, 26℃; amount of co-solvent volume, 4.7 m L. Under this condition, at a spiked level of 1, 5, 10 μg kg^(-1), the mean recovery of DES was more than 90% with relative standard deviations(RSDs) less than 10%. Finally, the developed method has been successfully used to analyzing the real samples. 展开更多
关键词 subcritical R134a extraction DIETHYLSTILBESTROL GC-MS determination fish tissue
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Acousto-optic Devices: Theory and Applications
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作者 SHIJianjun SHIYongji 《Semiconductor Photonics and Technology》 CAS 1998年第3期135-145,共11页
The basics and applications of acousto-optic devices are described.The applications include acousto-optic spectrum analyzer,acousto-optic deflector,acousto-optic processors and acousto-optic digital matrix computer.
关键词 Acousto-optic Deflector Acousto-optic Digital Matrix Computer Acousto-optic Modulator Acousto-optic Processor Acousto-optic Spectrum Analyzer
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Characterization of Rapeseed Oil Using FTIR-ATR Spectroscopy
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作者 Lu Yuzhen Du Changwen Shao Yanqiu Zhou Jianmin 《Journal of Food Science and Engineering》 2014年第5期244-249,共6页
Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was employed to characterize rapeseed oils. The spectral features of rapeseed oils were first investigated. Spectral data was processed... Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was employed to characterize rapeseed oils. The spectral features of rapeseed oils were first investigated. Spectral data was processed using principal component analysis (PCA) and linear discriminant analysis (LDA) to discriminate the oils from three cultivars of rapeseeds. As a result, 100% discrimination accuracy was obtained by LDA. Furthermore, the applicability of FTIR-ATR spectroscopy to characterize the changes of rapeseed oils caused by thermal treatment was studied. The rapeseed oil at 60 ℃ was regularly subjected to spectral measurement, and the spectral changes induced by thermal treatment were analyzed and discussed. This study had demonstrated the good performance of FTIR-ATR spectroscopy in characterizing rapeseed oils. 展开更多
关键词 Rapeseed oil FTIR-ATR characterization.
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