To deal with a sharp increase in transmission energy consumption due to the presence of a large number of secondary users( SUs),an energy-efficient cooperative spectrum sensing results transmission scheme is proposed ...To deal with a sharp increase in transmission energy consumption due to the presence of a large number of secondary users( SUs),an energy-efficient cooperative spectrum sensing results transmission scheme is proposed for cognitive radio systems. First,a cluster-based structure is introduced into the sensing results transmission scheme to reduce the transmission power. Then,the centralized sensing results transmission model is employed,and the non-fixed code rate Luby transform( LT)code is selected as the channel coding since its code rate can dynamically adapt to channel conditions and therefore avoid unnecessary redundancy in the transmission power.Furthermore,an improved optimal degree distribution( ODD)is designed for the LT code. The simulation results show that the choice of the appropriate parameters in degree distribution is very helpful for the LT code to achieve a promising performance. The ODD with optimized parameters can achieve more than 2 d B performance gain than other typical degree distributions when the bit error rate( BER) is 10-3. The energy consumption of the proposed scheme is not only at least71. 4% lower than that of the non-coding system,but also lower than that of the convolutional coding system with different code rates. Meanwhile, the energy consumption can be further reduced in the case that a suitable clustering method is selected.展开更多
In this article, we present a facile, direct, synthetic approach of preparing monodisperse [Au2s（SePh）ls]- nanoclusters in high yield. In this synthetic approach, two-phase Brust-Schiffrin method is used. Both PhSeH...In this article, we present a facile, direct, synthetic approach of preparing monodisperse [Au2s（SePh）ls]- nanoclusters in high yield. In this synthetic approach, two-phase Brust-Schiffrin method is used. Both PhSeH and NaBH4 should be added drop-wise to the solution of Au （III） at the same time. The formula and molecular purity of [Au25（SePh）ls] TOA＋ clusters are characterized by MALDI-TOF mass spectrometry, NMR and TGA analysis. Furthermore, some critical parameters to obtain pure [Au25（SePh）18]-TOA＋ are identified, including the NaBH4-to-Au ratio, the selenolate-to-Au ratio and the temperature. The facile, direct, high yield synthetic method can be widely applied in the theoretical research of Au clusters protected by selenol.展开更多
基金The National Natural Science Foundation of China(No.61771126)the Foundation of Graduate Innovation Center in NUAA(No.kfjj20170402)
文摘To deal with a sharp increase in transmission energy consumption due to the presence of a large number of secondary users( SUs),an energy-efficient cooperative spectrum sensing results transmission scheme is proposed for cognitive radio systems. First,a cluster-based structure is introduced into the sensing results transmission scheme to reduce the transmission power. Then,the centralized sensing results transmission model is employed,and the non-fixed code rate Luby transform( LT)code is selected as the channel coding since its code rate can dynamically adapt to channel conditions and therefore avoid unnecessary redundancy in the transmission power.Furthermore,an improved optimal degree distribution( ODD)is designed for the LT code. The simulation results show that the choice of the appropriate parameters in degree distribution is very helpful for the LT code to achieve a promising performance. The ODD with optimized parameters can achieve more than 2 d B performance gain than other typical degree distributions when the bit error rate( BER) is 10-3. The energy consumption of the proposed scheme is not only at least71. 4% lower than that of the non-coding system,but also lower than that of the convolutional coding system with different code rates. Meanwhile, the energy consumption can be further reduced in the case that a suitable clustering method is selected.
基金the financial support by the National Natural Science Foundation of China (20871112, 21072001, 21372006)Changjiang Scholars Program+1 种基金the Scientific Research Foundation for Returning Overseas Chinese Scholars, State Education Ministry, Ministry of Human Resources and Social Security, Anhui Province International Scientific and Technological Cooperation Project211 Project of Anhui University
文摘In this article, we present a facile, direct, synthetic approach of preparing monodisperse [Au2s（SePh）ls]- nanoclusters in high yield. In this synthetic approach, two-phase Brust-Schiffrin method is used. Both PhSeH and NaBH4 should be added drop-wise to the solution of Au （III） at the same time. The formula and molecular purity of [Au25（SePh）ls] TOA＋ clusters are characterized by MALDI-TOF mass spectrometry, NMR and TGA analysis. Furthermore, some critical parameters to obtain pure [Au25（SePh）18]-TOA＋ are identified, including the NaBH4-to-Au ratio, the selenolate-to-Au ratio and the temperature. The facile, direct, high yield synthetic method can be widely applied in the theoretical research of Au clusters protected by selenol.
