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数值微分零交点法分辨重叠谱的研究与应用
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作者 张礼知 张江华 陆晓华 《华中理工大学学报》 CSCD 北大核心 1998年第A02期68-70,共3页
在简述数值微分零交点法分辨重叠谱的原理基础上,研究了该方法对不同分离度的两组分重叠谱图的分辨效果.结果表明,对于两条高斯型重叠谱线,当分离度R≥0.07时,可有效地分辨两组分的谱图.对于前舌和拖尾的重叠谱体系,实现有... 在简述数值微分零交点法分辨重叠谱的原理基础上,研究了该方法对不同分离度的两组分重叠谱图的分辨效果.结果表明,对于两条高斯型重叠谱线,当分离度R≥0.07时,可有效地分辨两组分的谱图.对于前舌和拖尾的重叠谱体系,实现有效分辨的分离度的最低限也随峰变形程度的增加而增大.以L-色氨酸和DL-酪氨酸两组分重叠紫外光谱图的分辨为例,讨论了方法在两组分同时测定中的应用. 展开更多
关键词 谱图分辨 数值微分零交点 分析化学 重叠
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利用曲线补偿,变时溶出示差技术测定铜、铅、锌、镉初步探讨
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作者 刘汝娥 《新疆环境保护》 1998年第2期44-46,共3页
利用曲线补偿,变时溶出示差技术提高了测定铜、铅、锌、镉的灵敏度、精密度和准确度,进一步改变了谱图的分辨率,避免了O2波的干扰。
关键词 曲线补偿 变时溶出 谱图分辨
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Multi-scale MSDT inversion based on LAI spatial knowledge 被引量:6
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作者 ZHU XiaoHua FENG XiaoMing ZHAO YingShi 《Science China Earth Sciences》 SCIE EI CAS 2012年第8期1297-1305,共9页
Quantitative remote sensing inversion is ill-posed. The Moderate Resolution Imaging Spectroradiometer at 250 m resolution (MODIS_250m) contains two bands. To deal with this ill-posed inversion of MODIS_250m data, we... Quantitative remote sensing inversion is ill-posed. The Moderate Resolution Imaging Spectroradiometer at 250 m resolution (MODIS_250m) contains two bands. To deal with this ill-posed inversion of MODIS_250m data, we propose a framework, the Multi-scale, Multi-stage, Sample-direction Dependent, Target-decisions (Multi-scale MSDT) inversion method, based on spa- tial knowledge. First, MODIS images (1 km, 500 m, 250 m) are used to extract multi-scale spatial knowledge. The inversion accuracy of MODIS_lkm data is improved by reducing the impact of spatial heterogeneity. Then, coarse-scale inversion is taken as prior knowledge for the fine scale, again by inversion. The prior knowledge is updated after each inversion step. At each scale, MODIS_lkm to MODIS_250m, the inversion is directed by the Uncertainty and Sensitivity Matrix (USM), and the most uncertain parameters are inversed by the most sensitive data. All remote sensing data are involved in the inversion, during which multi-scale spatial knowledge is introduced, to reduce the impact of spatial heterogeneity. The USM analysis is used to implement a reasonable allocation of limited remote sensing data in the model space. In the entire multi-scale inversion process field data, spatial knowledge and multi-scale remote sensing data are all involved. As the multi-scale, multi-stage inversion is gradually refined, initial expectations of parameters become more reasonable and their uncertainty range is effectively reduced, so that the inversion becomes increasingly targeted. Finally, the method is tested by retrieving the Leaf Area Index (LAI) of the crop canopy in the Heihe River Basin. The results show that the proposed method is reliable. 展开更多
关键词 ill-posed inversion prior knowledge MSDT MULTI-SCALE
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