In this article, we study the structures of the pseudoscalar mesons π, K and the scalar diquarks U^a, D^a, Sa in the framework of the coupled rainbow Schwinger-Dyson equation and ladder Bethe-Salpeter equation with t...In this article, we study the structures of the pseudoscalar mesons π, K and the scalar diquarks U^a, D^a, Sa in the framework of the coupled rainbow Schwinger-Dyson equation and ladder Bethe-Salpeter equation with the confining effective potential. The u, d, s quarks have small current masses, and the renormalization is very large, the mass poles in the timelike region are absent which implements confinement naturally. The Bethe-Salpeter wavefunctions of the pseudoscalar mesons π, K, and the scalar diquarks U^a, D^a, S^a have the same type （Gaussian type） momentum dependence, center around zero momentum and extend to the energy scale about q^2 = 1 GeV^2, which happens to be the energy scale for the chiral symmetry breaking, the strong interactions in the infrargd region result in bound （or quasl-bound） states. The numerical results for the masses and decay constants of the π and K mesons can reproduce the experimental values, and the ground state masses of the scalar diquarks U^a, D^a, S^a are consistent with the existing theoretical calculations. We suggest a new Lagrangian which may explain the uncertainty of the masses of the scalar diauarks.展开更多
The ground and three low-excited states of the hydrogen negative ion confined by a spherical harmonic oscillator potential are studied employing the adiabatic hyperspherical approach method. Total energies are obtaine...The ground and three low-excited states of the hydrogen negative ion confined by a spherical harmonic oscillator potential are studied employing the adiabatic hyperspherical approach method. Total energies are obtained as a function of the confined potential radii. We find that the confinement may cause accidental degeneracies between levels with different low-excited states and the inversion of the energy values.展开更多
We have measured the variation of photoluminescence(PL) in porous silicon with anodization(AO) time,HF soak time or natural oxidation time,and found that the peak value of PL spectrum will shift towards shorter value ...We have measured the variation of photoluminescence(PL) in porous silicon with anodization(AO) time,HF soak time or natural oxidation time,and found that the peak value of PL spectrum will shift towards shorter value as above time is increased.The analyses in experiment and theory show that the quantum confined structures produced by the AO process may be responsible for the blue shift.展开更多
The probe absorption-dispersion spectra of a radio-frequency （RF）-driven five-level atom embedded in a photonic crystal are investigated by considering the isotropic double-band photonic-bandogap （PBG） reservoir. ...The probe absorption-dispersion spectra of a radio-frequency （RF）-driven five-level atom embedded in a photonic crystal are investigated by considering the isotropic double-band photonic-bandogap （PBG） reservoir. In the model used, the two transitions are, respectively, coupled by leading to some curious phenomena. Numerical simulations the upper and lower bands in such a PBG material, thus are performed for the optical spectra. It is found that when one transition frequency is inside the band gap and the other is outside the gap, there emerge three peaks in the absorption spectra. However, for the case that two transition frequencies lie inside or outside the band gap, the spectra display four absorption profiles. Especially, there appear two sharp peaks in the spectra when both transition frequencies exist inside the band gap. The influences of the intensity and frequency of the RF-driven field on the absorptive and dispersive response are analyzed under different band-edge positions. It is found that a transparency window appears in the absorption spectra and is accompanied by a very steep variation of the dispersion profile by adjusting system parameters. These results show that the absorption-dispersion properties of the system depend strongly on the RF-induced quantum interference and the density of states （DOS） of the PBG reservoir.展开更多
A Z-scheme is a promising approach to achieve broad-spectrum photocatalysis. Integration of TiO2 with another semiconductor with a band gap of -1.0 eV would be ideal to harvest both ultraviolet and visible-near infrar...A Z-scheme is a promising approach to achieve broad-spectrum photocatalysis. Integration of TiO2 with another semiconductor with a band gap of -1.0 eV would be ideal to harvest both ultraviolet and visible-near infrared light for photocatalysis; however, most narrow-bandgap semiconductors have straddling band structure alignments with TiO2, constituting an obstacle to forming the Z-scheme for photocatalytic hydrogen production. In this communication, we demonstrate Ag2S as a model system where the energy band upshift of the narrow-bandgap semiconductor that shares an interface with a metal can overcome this limitation. To fabricate the design, we developed a unique approach to synthesize Ag2S-Ag-TiO2 hybrid structures. The obtained ternary hybrid structures exhibited dramatically enhanced performance in photocatalytic hydrogen pro- duction under full-spectrum light illumination. The activities were significantly higher than the sum of those of Ag2S-Ag-TiO2 structures under λ〈 400 nm and λ 〉 400 nm irradiation as well as those of their counterparts under any light illumination conditions.展开更多
Lead-free double perovskite nanocrystals(NCs),such as Cs2AgInCl6,have attracted considerable attention as stable and non-toxic alternatives to lead-based perovskites.However,the low photoluminescence(PL)intensity of p...Lead-free double perovskite nanocrystals(NCs),such as Cs2AgInCl6,have attracted considerable attention as stable and non-toxic alternatives to lead-based perovskites.However,the low photoluminescence(PL)intensity of pristine Cs_(2)AgInCl_(6)limits its practical applications.In this study,a series of Cs_(2)AgIn_(1−γ−x)Bi_(x)La_(γ)Cl_(6)NCs were synthesized to break the parity-forbidden transition and modify the associated optical functionalities.A broadband bright warm-white emission in the visible region was achieved,with an excellent PL quantum yield of 60%.The dynamic mechanism,involving ultrafast transient absorption,suggests that high-efficiency PL is induced by triplet self-trapping exciton emission.The incorporation of La^(3+)-Bi^(3)+facilitated the singlet–triplet transition by increasing the lifetime and quickening the intersystem crossing process.This finding provides a reliable method for optimizing the optical properties of emerging lead-free halide perovskite NCs.展开更多
基金The project supported by National Natural Science Foundation of China under Grant No. 10405009 The authors are indebted to Dr： J. He （IHEP）, Dr. X.B. nuang （PKU） and Dr. L. Li （GSCAS） for numerous help. Without them, the work would not be finished. The authors would also like to thank Prof. C.D. Roberts for providing us some important literatures.
文摘In this article, we study the structures of the pseudoscalar mesons π, K and the scalar diquarks U^a, D^a, Sa in the framework of the coupled rainbow Schwinger-Dyson equation and ladder Bethe-Salpeter equation with the confining effective potential. The u, d, s quarks have small current masses, and the renormalization is very large, the mass poles in the timelike region are absent which implements confinement naturally. The Bethe-Salpeter wavefunctions of the pseudoscalar mesons π, K, and the scalar diquarks U^a, D^a, S^a have the same type （Gaussian type） momentum dependence, center around zero momentum and extend to the energy scale about q^2 = 1 GeV^2, which happens to be the energy scale for the chiral symmetry breaking, the strong interactions in the infrargd region result in bound （or quasl-bound） states. The numerical results for the masses and decay constants of the π and K mesons can reproduce the experimental values, and the ground state masses of the scalar diquarks U^a, D^a, S^a are consistent with the existing theoretical calculations. We suggest a new Lagrangian which may explain the uncertainty of the masses of the scalar diauarks.
基金The project supported by National Natural Science Foundation of China under Grant No. 10475021 and the Natural Science Foundation of Guangdong Province under Grant No. 04009519
文摘The ground and three low-excited states of the hydrogen negative ion confined by a spherical harmonic oscillator potential are studied employing the adiabatic hyperspherical approach method. Total energies are obtained as a function of the confined potential radii. We find that the confinement may cause accidental degeneracies between levels with different low-excited states and the inversion of the energy values.
文摘We have measured the variation of photoluminescence(PL) in porous silicon with anodization(AO) time,HF soak time or natural oxidation time,and found that the peak value of PL spectrum will shift towards shorter value as above time is increased.The analyses in experiment and theory show that the quantum confined structures produced by the AO process may be responsible for the blue shift.
基金Supported by the National Natural Science Foundation of China under Grant Nos.91021011,10975054,11004069,and 10874050the Doctoral Foundation of the Ministry of Education of China under Grant Nos.200804870051,20100142120081the Innovation Foundation from Huazhong University of Science and Technology under Grant No.2010MS074
文摘The probe absorption-dispersion spectra of a radio-frequency （RF）-driven five-level atom embedded in a photonic crystal are investigated by considering the isotropic double-band photonic-bandogap （PBG） reservoir. In the model used, the two transitions are, respectively, coupled by leading to some curious phenomena. Numerical simulations the upper and lower bands in such a PBG material, thus are performed for the optical spectra. It is found that when one transition frequency is inside the band gap and the other is outside the gap, there emerge three peaks in the absorption spectra. However, for the case that two transition frequencies lie inside or outside the band gap, the spectra display four absorption profiles. Especially, there appear two sharp peaks in the spectra when both transition frequencies exist inside the band gap. The influences of the intensity and frequency of the RF-driven field on the absorptive and dispersive response are analyzed under different band-edge positions. It is found that a transparency window appears in the absorption spectra and is accompanied by a very steep variation of the dispersion profile by adjusting system parameters. These results show that the absorption-dispersion properties of the system depend strongly on the RF-induced quantum interference and the density of states （DOS） of the PBG reservoir.
基金Acknowledgements This work was financially supported by the National Basic Research Program of China （973 Program） （No. 2014CB848900）, National Natural Science Foundation of China （NSFC） （Nos. 21471141 and 21473166）, Recruitment Program of Global Experts, Hundred Talent Program of CAS, and the Fundamental Research Funds for the Central Universities （Nos. WK2060190025, WK2310000035, and WK2090050027）. Photoemission spectroscopy experiments were performed at the Catalysis and Surface Physics Endstation at the BL11U beamline in the National Synchrotron Radiation Laboratory （NSRL） in Hefei, China.
文摘A Z-scheme is a promising approach to achieve broad-spectrum photocatalysis. Integration of TiO2 with another semiconductor with a band gap of -1.0 eV would be ideal to harvest both ultraviolet and visible-near infrared light for photocatalysis; however, most narrow-bandgap semiconductors have straddling band structure alignments with TiO2, constituting an obstacle to forming the Z-scheme for photocatalytic hydrogen production. In this communication, we demonstrate Ag2S as a model system where the energy band upshift of the narrow-bandgap semiconductor that shares an interface with a metal can overcome this limitation. To fabricate the design, we developed a unique approach to synthesize Ag2S-Ag-TiO2 hybrid structures. The obtained ternary hybrid structures exhibited dramatically enhanced performance in photocatalytic hydrogen pro- duction under full-spectrum light illumination. The activities were significantly higher than the sum of those of Ag2S-Ag-TiO2 structures under λ〈 400 nm and λ 〉 400 nm irradiation as well as those of their counterparts under any light illumination conditions.
基金the National Key Research and Development Program of China(2017YFA0204800)the National Natural Science Foundation of China(21833009,21533010,and 21525315)+2 种基金the Scientific Instrument Developing Project of the Chinese Academy of Sciences(YJKYYQ20190003)Liaoning Revitalization Talents Program(XLYC1802126)Dalian City Foundation for Science and Technology Innovation(2019J12GX031).
文摘Lead-free double perovskite nanocrystals(NCs),such as Cs2AgInCl6,have attracted considerable attention as stable and non-toxic alternatives to lead-based perovskites.However,the low photoluminescence(PL)intensity of pristine Cs_(2)AgInCl_(6)limits its practical applications.In this study,a series of Cs_(2)AgIn_(1−γ−x)Bi_(x)La_(γ)Cl_(6)NCs were synthesized to break the parity-forbidden transition and modify the associated optical functionalities.A broadband bright warm-white emission in the visible region was achieved,with an excellent PL quantum yield of 60%.The dynamic mechanism,involving ultrafast transient absorption,suggests that high-efficiency PL is induced by triplet self-trapping exciton emission.The incorporation of La^(3+)-Bi^(3)+facilitated the singlet–triplet transition by increasing the lifetime and quickening the intersystem crossing process.This finding provides a reliable method for optimizing the optical properties of emerging lead-free halide perovskite NCs.
