正交异性钢-混凝土组合板负弯矩区抗弯性能分析

为探究正交异性钢-混凝土组合板负弯矩区的抗弯性能,对3块正交异性钢-混凝土组合板进行了抗弯静载试验和非线性数值分析,研究了不同因素对混凝土负弯矩开裂荷载和组合板整体抗弯极限承载力的影响.结果表明:正交异性钢-混凝土组合板呈现典型的弯曲破坏形态;当钢纤维体积分数为1%时,钢-混凝土组合板开裂弯矩的提升率最大,但钢纤维体积分数的改变对整体抗弯极限承载力影响较小;正交异性钢-混凝土组合板的开裂弯矩与正交异性钢板强度无关,极限弯矩则随钢板强度的增加而增大;增加混凝土板厚能提高组合板开裂弯矩和极限弯矩,当混凝土板厚度与正交异性钢板高度比值为0.8时,开裂弯矩的提升率最大.

论中药的“负”性能

中药临床作用具有两重性,主要探讨中药“负”性能。其发生的方法有:加强药品管理、辨证用药、组方配伍、炮制、用量、制备工艺、不良反应的监测。目的:在临床中合理应用中药。

助剂对聚乙烯醇缩甲醛机械性能及负压渗水性能的影响

为了提高新型负压渗水材料聚乙烯醇缩甲醛(polyvinyl formal,PVFM)的机械性能,该试验在先前制备聚乙烯醇缩甲醛泡沫塑料的基础上添加Si O2粉末、高岭土、硅油、硅油+Si O2粉末、硅油+高岭土5种助剂,运用机械发泡法制得5种聚乙烯醇缩甲醛泡沫塑料管,与不添加助剂的聚乙烯醇缩甲醛泡沫塑料管(CK)比较,检测了其基本物理性能、机械性能、负压渗水性能、孔隙结构等指标。结果表明,除Si O2粉末外,其余4种助剂均能改善PVFM的外观质量,使之表面光滑细腻;这5种助剂会降低PVFM负压渗水材料的吸水倍率,提高表观密度、真密度、孔隙率,其中加入高岭土能够在保证较高吸水倍率的同时显著(P<0.05)增大孔隙率;硅油+Si O2粉末、硅油+高岭土2种混合助剂能够显著(P<0.05)提高PVFM负压渗水材料的机械性能,其中硅油+Si O2粉末对其硬度的提高幅度高达62.5%,对拉伸强度的增幅高达51.9%,硅油+高岭土对其断裂伸长率的增幅高达33.5%;加入助剂能显著(P<0.05)提高PVFM的发泡点值,硅油+高岭土使增幅达70.7%;但几种助剂的加入并未提高PVFM的累积入渗量及渗水速率,仅在较低负压(?10 k Pa)下加入Si O2粉末能使PVFM的累积入渗量增加;5种助剂的加入均能使PVFM孔隙结构变得更加均匀致密,其中加入硅油+高岭土后孔隙最为均匀细小,气泡极少。总体而言,混合助剂的两个处理均能提高PVFM的外观质量、发泡点值和机械性能,其提高幅度不同程度地高于单一助剂,而Si O2粉末可以较好地提高?10 k Pa下PVFM的累积入渗量和渗水速率,此研究为高分子型负压渗水材料的改良提供方向。

Si掺杂对Mn_3Zn_(0.6)Ge_(0.4)N的负热膨胀和磁性能的影响

为了探究Si元素对反钙钛矿材料Mn3Zn0.6Ge0.4N的负热膨胀和磁性能的影响,利用放电等离子体烧结法制备了一系列Si掺杂的Mn3Zn0.6SixGe0.4-xN(x=0,0.1,0.15,0.2)材料。材料的结构通过多晶粉末X射线衍射进行了表征,测试结果表明实验成功的制备了Mn3Zn0.6SixGe0.4-xN化合物(空间群Pm-3 m)。接着,对Mn3Zn0.6SixGe0.4-xN进行了热膨胀性能测试,发现随着Si掺杂量的增加,样品的负热膨胀温区的起始温度向低温移动,而负热膨胀温区的宽度不变。Mn3Zn0.6SixGe0.4-xN的磁性能由物理性能测试系统(PPMS)进行了测试,结果表明,掺杂Si元素之后,在370 K附近的顺磁-反铁磁转变完全消失,这与掺杂Si元素之后,负热膨胀起始温度迅速向低温移动的现象一致,证明负热膨胀现象与磁转变的紧密联系。另外,Si掺杂使Mn3Zn0.6Ge0.4N在低温阶段出现自旋玻璃态现象,同时激发了样品的低温铁磁性。

防冻外加剂对磷酸盐水泥负温力学性能的影响

为了提高磷酸盐水泥(MPC)的负温可施工性,拓宽MPC的施工范围,本文通过负温胶砂强度试验研究乙二醇和氨水两种防冻外加剂在不同浓度下对MPC砂浆负温力学性能的影响,探讨其作用机理,确定最佳浓度和掺量。结果表明,两种防冻剂能降低水泥中水的冰点,提高水化活性,显著提升MPC砂浆在-15℃下的抗折、抗压强度,其中乙二醇最佳浓度为15%(拌合用水),25%氨水的最佳掺量为6mL。

负温高性能混凝土配制与实现途径探讨

浅述了负温高性能混凝土 (HPCMT)配制时所采取的方法及其配制原则 ,并探讨了实现这一原则的途径 ,提出了与负温与普通混凝土相比较 ,在应用HPC时应考虑需明快的问题。

软质PVC的电负性研究及其火灾感温报警电缆的研制

研究了增塑剂用量、类型以及其他添加剂对火灾感温报警电缆电负性能的影响,并进行了热老化试验。试验结果表明:①添加DOP的体系要比添加TOTM的体系敏感温度低,感温性能好;②随着增塑剂用量的增加,电缆电阻值对温度的敏感系数减小,敏感温度范围降低;③添加硬脂酸和抗静电剂类添加剂可以调节电缆对温度的敏感性能和敏感温度范围;④TOTM、DMP、DOP、DOS 4种增塑剂热老化性能试验结果表明,TOTM的耐热性能最好。

掺铜氧化铁陶瓷负阻特性的研究

研究了掺铜氧化铁陶瓷的负阻特性，并从相结构入手，探讨了负阻机理，分析了该类材料在一定温区内呈现负阻性能的原因。

天然树脂对混凝土抗冻性能的影响与机理

研究了分别掺质量分数为0％，0．1％，0．5％，1％，2％的天然树脂（NR）对混凝土抗冻性影响，探讨了天然树脂（NR）改善混凝土抗冻性的作用机理，并建立了相应的理论模型．结果表明：不同掺量的天然树脂（NR）可提高冻融后混凝土的抗压强度20％～50％左右，而且使冻融后混凝土的弹模显著提高，一般为空白混凝土的3．76～5．64倍．同时表面微观结构、MIP及NR溶液负温性能研究表明：NR改善混凝土抗冻性的机理在于有效廷缓混凝土孔溶液的热质交换与传递过程，使混凝土孔隙溶液达到冰点的时间后移，提高混凝土冻融循环后的结构稳定性．

Graphene-loaded nickel−vanadium bimetal oxides as hydrogen pumps to boost solid-state hydrogen storage kinetic performance of magnesium hydride

To modify the thermodynamics and kinetic performance of magnesium hydride(MgH_(2))for solid-state hydrogen storage,Ni_(3)V_(2)O_(8)-rGO(rGO represents reduced graphene oxide)and Ni_(3)V_(2)O_(8)nanocomposites were prepared by hydrothermal and subsequent heat treatment.The beginning hydrogen desorption temperature of 7 wt.%Ni_(3)V_(2)O_(8)-rGO modified MgH_(2)was reduced to 208℃,while the additive-free MgH_(2)and 7 wt.%Ni_(3)V_(2)O_(8)doped MgH_(2)appeared to discharge hydrogen at 340 and 226℃,respectively.A charging capacity of about 4.7 wt.%H_(2)for MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO was achieved at 125℃ in 10 min,while the dehydrogenated MgH_(2)took 60 min to absorb only 4.6 wt.%H_(2)at 215℃.The microstructure analysis confirmed that the in-situ generated Mg_(2)Ni/Mg_(2)N_(i)H_(4) and metallic V contributed significantly to the enhanced performance of MgH_(2).In addition,the presence of rGO in the MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO composite reduced particle aggregation tendency of Mg/MgH_(2),leading to improving the cyclic stability of MgH_(2)during 20 cycles.

Effect of germanium on electrochemical performance of chain-like Co-P anode material for Ni/Co rechargeable batteries

Co-P （4.9% P） powders with a chain-like morphology were prepared by a novel chemical reduction method. The Co-P and germanium powders were mixed at various mass ratios to form Co-P composite electrodes. Charge and discharge test and electrochemical impedance spectroscopy （EIS） were carried out to investigate the electrochemical performance, which can be significantly improved by the addition of germanium. For instance, when the mass ratio of Co-P powders to germanium is 5：1, the sample electrode shows a reversible discharge capacity of 350.3 mA·h/g and a high capacity retention rate of 95.9% after 50 cycles. The results of cyclic voltammmetry （CV） show the reaction mechanism of Co/Co（OH）2 within Co-P composite electrodes and EIS indicates that this electrode shows a low charge-transfer resistance, facilitating the oxidation of Co to Co（OH）2.

Enhanced Photoelectrochemical Property of Zn Loaded TiO2 Nanotube Arrays Electrode

TiO2 nanotube arrays （TNTs） electrode loaded with Zn nanoparticles was prepared by anodization and the size of Zn nanoparticle loaded on TNTs electrode was controlled by chronoamperometry deposition time. Results of SEM and XRD analysis show that Zn nanoparticles had a diameter of about 15-25 nm when the deposition time was 3-5 s. The UV-Vis diffuse reflectance spectra show the Zn loaded harvest light with 480-780 nm more effectively than the unloaded sample. The photocurrent response of Zn loaded TNTs electrodes were studied, the results showed that TNTs electrodes loaded with Zn nanoparti-cles has 50% increased photocurrent response under high-pressure mercury lamp irradiation compared with unloaded TNTs electrode.

Calculation model of edge carbon atoms in graphite particles for anode of lithium-ion batteries

Based on the hexagonal crystallite model of graphite,the electrochemical characteristics of carbon atoms on the edge and basal plane were proposed by analyzing graphite crystal structure and bonds of carbon atoms in different sites.A spherical close-packed model for graphite particle was developed.The fractions of surface carbon atoms（SCA） and edge carbon atoms（ECA） were derived in the expression of crystallographic parameters and particle size,and the effects of ECA on the initial irreversible capacity and the mechanisms of action were analyzed and verified.The results show that the atoms on the edge are more active for electrochemical reactions,such as electrolyte decomposition and tendency to form stable bond with other atoms and groups.For the practical graphite particle,corresponding modifying factors were introduced to revise the difference in calculating results.The revised expression is suitable for the calculation of the fractions of SCA and ECA for carbon materials such as graphite,disordered carbon and modified graphite.

Interference analysis and improvement of capacity reduction for FHSS networks in WPAN application environment

The coexistence between Bluetooth system and IEEE 802.11 frequency hoppingspread spectrum (FHSS) equipment is analyzed. Based on the capacity formulae and system simulation,the inter-affection between these networks is compared. A fragment adaptive solution of packetpayload length is presented, which can be used to improve the capacity reduction of IEEE 802.11 FHSSnetwork. Analysis results show that the IEEE 802.11 WLAN standard with its inherent mechanismsupports this fragment length adaptive algorithm. With the increasing of Bluetooth interferingnetworks, this adaptive solution can effectively relieve capacity decreasing of IEEE 802.11 FHSSnetwork. The capacity analysis method and adaptive algorithm adopted in this paper can also begeneralized into other FHSS networks.

Seismic Behavior of Frame with Specially Shaped Columns Subjected to Cyclic Load

In order to study the seismic behavior of frame with specially shaped columns,the hysteretic curve was analyzed based on a quasi-static test of a two-span,three-story frame with specially shaped columns.The top layer framework curve and the corresponding resilience model were obtained from the hysteretic curve.And the stiffness and strength degeneration were also investigated.The results indicated that the stiffness degeneration is not obvious,thus the frame with specially shaped columns has high earthquake-resistant behavior.The resilience model calculated from the test can provide reference for design and nonlinear finite element analysis.

Effect of exhaust gas recirculation and intake pre-heating on performance and emission characteristics of dual fuel engines at part loads

Achieving simultaneous reduction of NOx,CO and unburned hydrocarbon(UHC) emissions without compromising engine performance at part loads is the current focus of dual fuel engine research.The present work focuses on an experimental investigation conducted on a dual fuel(diesel-natural gas) engine to examine the simultaneous effect of inlet air pre-heating and exhaust gas recirculation(EGR) ratio on performance and emission characteristics at part loads.The use of EGR at high levels seems to be unable to improve the engine performance at part loads.However,it is shown that EGR combined with pre-heating of inlet air can slightly increase thermal efficiency,resulting in reduced levels of both unburned hydrocarbon and NOx emissions.CO and UHC emissions are reduced by 24% and 31%,respectively,The NOx emissions decrease by 21% because of the lower combustion temperature due to the much inert gas brought by EGR and decreased oxygen concentration in the cylinder.

Simulation of CO_2 Brayton Cycle for Engine Exhaust Heat Recovery under Various Operating Loads

A bottoming cycle system based on CO2 Brayton cycle is proposed to recover the engine exhaust heat. Its performance is compared with the conventional air Brayton cycle under five typical engine conditions. The results show that CO2 Brayton cycle proves to be superior to the air Brayton cycle in terms of the system net output power, thermal efficiency and recovery efficiency. In most cases, the recovery efficiency of CO2 Brayton cycle can be higher than 9% and the system has a better performance at the engine＇s high operating load, The thermal efficiency can be as large as 24.83% under 100% olaerating load, accordingly, the net outnut nower of 14.86 kW in nhtnined

A three-level mobility management scheme for hierarchical mobile IPv6 networks

Performance evaluation shows that Hierarchical Mobile IPv6 (HMIPv6) cannot outperform standard Mobile IPv6 (MIPv6) in all scenarios. Thus, adaptive protocol selection under certain circumstances is desired. Moreover, it is necessary to balance the load among different Mobility Anchor Points (MAPs). This paper proposes an efficient three-level hierarchical ar- chitecture for mobility management in HMIPv6 networks, in which a mobile node (MN) may register with either a higher/lower MAP or its home agent according to its speed and the number of connecting correspondent nodes (CNs). An admission control algorithm and a replacement algorithm are introduced to achieve load balancing between two MAP levels and among different MAPs within the same MAP level. Admission control is based on the number of CNs but not MNs that an MAP serves. In case there is no capacity for an MN, the MAP chooses an existing MN to be replaced. The replaced MN uses the MAP selection al- gorithm again to choose another mobility agent. Simulation results showed that the proposed scheme achieves better performance not only in reducing the signaling overhead, but also in load balancing among different MAPs.

Preparation and Photocatalytic Properties of Magnetically Separable TiO_2 Supported on Nickel Ferrite

A magnetically separable photocatalyst TiO2/SiO2/NiFe2O4 （TSN） with a typical ferromagnetic hysteresis was prepared by a liquid catalytic phase transfer method. When the intensity of applied magnetic field weakened to zero, the remnant magnetism of the prepared photocatalyst faded to zero. The photocatalytst can be separated from water when an external magnetic field is added and redispersed into aqueous solution after the external magnetic field is eliminated, that makes the photocatalysts promising for wastewater treatment. Transmission electron microscope （TEM） and X-ray diffractometer （XRD） were used to characterize the structure of the photocatalyst indicating that the magnetic SiOffNiFe204 （SN） particle was compactly enveloped by P-25 titania and Tit2 shell was formed. The magnetic composite showed high photocatalytic activity for the degradation of methyl orange in water. A thin SiO2 layer between NiFe2O4 and TiO2 shell prevented effectively the leakage of charges from TiO2 particles to NiFe2O4, which gave rise to the increase in photocatalytic activity. Moreover, the experiment on recycled use of TSN demonstrated a good repeatability of the photocatalytic activity.

Preparation and effects of W-doping on electrochemical properties of spinel Li_4Ti_5O_(12) as anode material for lithium ion battery

W-doped Li4TisO12 in the form of Li4Ti4.95W0.osO12 was firstly synthesized via solid state reaction. X-ray diffraction （XRD） and scanning electron microscope （gEM） were employed to characterize the structure and morphology of Li4Ti4.psW0.05Ol2. W-doping does not change the phase composition and particle morphology, while remarkably improves its cycling stability at high charge/discharge rate. Li4Ti4.95W0.05O12 exhibits an excellent rate capability with a reversible capacity of 131.2 mA.h/g at 10C and even 118.6 mA.h/g at 20C. The substitution of W for Ti site can enhance the electronic conductivity of Li4TisO12 via the generation of mixing Ti4＋/Ti3＋, which indicates that Li4Ti4.psW0.05O12 is promising as a high rate anode for the lithium-ion batteries.