Sodium-treated sepiolite(Na Sep)-supported transition metal catalysts(TM/Na Sep;TM = Cu, Fe, Ni, Mn, and Co) were synthesized via a rotary evaporation method. Physicochemical properties of the as-synthesized samples w...Sodium-treated sepiolite(Na Sep)-supported transition metal catalysts(TM/Na Sep;TM = Cu, Fe, Ni, Mn, and Co) were synthesized via a rotary evaporation method. Physicochemical properties of the as-synthesized samples were characterized by means of various techniques, and their catalytic activities for HCHO(0.2%) oxidation were evaluated. Among the samples, Cu/Na Sep exhibited superior performance, and complete HCHO conversion was achieved at 100 ℃(GHSV = 240000 m L/(g·h)). Additionally, the sample retained good catalytic activity during a 42 h stability test. A number of factors, including elevated acidity, the abundance of oxygen species, and favorable low-temperature reducibility, were responsible for the excellent catalytic activity of Cu/Na Sep. According to the results of the in-situ DRIFTS characterization, the HCHO oxidation mechanism was as follows:(i) HCHO was rapidly decomposed into dioxymethylene(DOM) species on the Cu/Na Sep surface;(ii) DOM was then immediately converted to formate species;(iii) the resultant formate species were further oxidized to carbonates;(iv) the carbonate species were eventually converted to CO2 and H2O.展开更多
Present mobile communication system suffers from the exponentially increased mobile traffic and research on the fifth generation(5G) mobile network architectures is ongoing to solve this problem. We investigate the fe...Present mobile communication system suffers from the exponentially increased mobile traffic and research on the fifth generation(5G) mobile network architectures is ongoing to solve this problem. We investigate the feasibility of the proposals used for the network architecture evolution from 4G to 5G and first propose a compatible network architecture, which decouples the management plane, the control plane and the user plane based on NO Stack framework proposed in our previous study. We mainly design detail procedures including UE attachment, service request and dedicated bearer activation/deactivation for our proposal network architecture. Finally, we establish a clear analytical mode of the application and system states to evaluate the signaling loads of new architecture. Simulation results show that our proposal network architecture with elaborated signaling procedures has much impact on the total signaling loads of system and could obviously decrease the signaling overhead compared with LTE.展开更多
In this study, MWNT and alumina nanopowder were used as a ruthenium catalyst support for the conversion of carbon monoxide to methane. Metal foam structures were employed to support such catalytic systems, offering in...In this study, MWNT and alumina nanopowder were used as a ruthenium catalyst support for the conversion of carbon monoxide to methane. Metal foam structures were employed to support such catalytic systems, offering interesting possibilities for commercial applications due to low-pressure drop; excellent flow characteristic and heat transfer properties. Prior to the ruthenium impregnation, the MWNT surface was initially modified by means of metal cation activation and surface adsorption of anionic surfactant. The decoration processes using both surface modifications promoted the deposition of ruthenium with a mean 2 nm diameter. The use of nickel as a nucleating center enhanced the Ru nanoparticle density on the CNT surface compared to the Ru/CNT catalyst prepared by excess solution impregnation. As a reducing agent, ethylene glycol completely converted Ru2＋ to Ru0as confirmed by an EDS/TEM analysis. Among the prepared catalysts, Ru/AI203-CNTs prepared by Ni2＋ activation showed the best performance for the hydrogenation reaction. This is interpreted in terms of the higher ruthenium nanoparticle exposure on the nanostructured catalyst, as a result of the better MWNT dispersion in the MWNT/Al2O3 mixture.展开更多
This research was performed in order to allow the study of the chemical composition influence of the coking process load on the efficiency and the quality of coke. For this reason, the coking of the following loads wa...This research was performed in order to allow the study of the chemical composition influence of the coking process load on the efficiency and the quality of coke. For this reason, the coking of the following loads was realized： Atmospheric residue （RAT）, vacuum Residue （RSV） and catalytic Residue of cracking （RCC）. （The residues are obtained from an Algerian crude oil）. As the oil residues are rich for their strongly polar composition, such as the asphaltene resins, and complex structures units （SCU）, which has a role in the formation of coke, and as the dispersion of these latter improves the quality of coke, a study on the stability of aggregation was carried out by the addition of one stabilizer （oil Extract） in the coking process load, The Compounding （Extracted from/RCC oil） has been drived to the best efficiency of coke. The study consists of the influence this is characterized by the analyses Infra-red （IR） and x-ray diffraction （XRD）.展开更多
CO oxidation was investigated on various powder oxide supported Pd catalysts by temperature-programined reaction. The pre-reduced catalysts show significantly higher activities than the pre-oxidized ones. Model studie...CO oxidation was investigated on various powder oxide supported Pd catalysts by temperature-programined reaction. The pre-reduced catalysts show significantly higher activities than the pre-oxidized ones. Model studies were performed to better understand the oxidation state, reactivities and stabilities of partially oxidized Pd surfaces under CO oxidation reaction condi tions using an in situ infrared reflection absorption spectrometer （IRAS）. Three O/Pd（100） model surfaces, chemisorbed oxygen covered surface, surface oxide and bulk-like surface oxide, were prepared and characterized by low-energy electron diffraction （LEED） and Auger electron spectroscopy （AES）. The present work demonstrates that the oxidized palladium surface is less active for CO oxidation than the metallic surface, and is unstable under the reaction conditions with sufficient CO.展开更多
文摘Sodium-treated sepiolite(Na Sep)-supported transition metal catalysts(TM/Na Sep;TM = Cu, Fe, Ni, Mn, and Co) were synthesized via a rotary evaporation method. Physicochemical properties of the as-synthesized samples were characterized by means of various techniques, and their catalytic activities for HCHO(0.2%) oxidation were evaluated. Among the samples, Cu/Na Sep exhibited superior performance, and complete HCHO conversion was achieved at 100 ℃(GHSV = 240000 m L/(g·h)). Additionally, the sample retained good catalytic activity during a 42 h stability test. A number of factors, including elevated acidity, the abundance of oxygen species, and favorable low-temperature reducibility, were responsible for the excellent catalytic activity of Cu/Na Sep. According to the results of the in-situ DRIFTS characterization, the HCHO oxidation mechanism was as follows:(i) HCHO was rapidly decomposed into dioxymethylene(DOM) species on the Cu/Na Sep surface;(ii) DOM was then immediately converted to formate species;(iii) the resultant formate species were further oxidized to carbonates;(iv) the carbonate species were eventually converted to CO2 and H2O.
基金supported by the Chinas 863 Project (No.2015AA01A706)the National Science and Technology Major Project (No. 2016ZX03001017)+1 种基金the Science and Technology Program of Beijing (No. D161100001016002)the Science and Technology Cooperation Projects (No. 2015DFT10160B)
文摘Present mobile communication system suffers from the exponentially increased mobile traffic and research on the fifth generation(5G) mobile network architectures is ongoing to solve this problem. We investigate the feasibility of the proposals used for the network architecture evolution from 4G to 5G and first propose a compatible network architecture, which decouples the management plane, the control plane and the user plane based on NO Stack framework proposed in our previous study. We mainly design detail procedures including UE attachment, service request and dedicated bearer activation/deactivation for our proposal network architecture. Finally, we establish a clear analytical mode of the application and system states to evaluate the signaling loads of new architecture. Simulation results show that our proposal network architecture with elaborated signaling procedures has much impact on the total signaling loads of system and could obviously decrease the signaling overhead compared with LTE.
文摘In this study, MWNT and alumina nanopowder were used as a ruthenium catalyst support for the conversion of carbon monoxide to methane. Metal foam structures were employed to support such catalytic systems, offering interesting possibilities for commercial applications due to low-pressure drop; excellent flow characteristic and heat transfer properties. Prior to the ruthenium impregnation, the MWNT surface was initially modified by means of metal cation activation and surface adsorption of anionic surfactant. The decoration processes using both surface modifications promoted the deposition of ruthenium with a mean 2 nm diameter. The use of nickel as a nucleating center enhanced the Ru nanoparticle density on the CNT surface compared to the Ru/CNT catalyst prepared by excess solution impregnation. As a reducing agent, ethylene glycol completely converted Ru2＋ to Ru0as confirmed by an EDS/TEM analysis. Among the prepared catalysts, Ru/AI203-CNTs prepared by Ni2＋ activation showed the best performance for the hydrogenation reaction. This is interpreted in terms of the higher ruthenium nanoparticle exposure on the nanostructured catalyst, as a result of the better MWNT dispersion in the MWNT/Al2O3 mixture.
文摘This research was performed in order to allow the study of the chemical composition influence of the coking process load on the efficiency and the quality of coke. For this reason, the coking of the following loads was realized： Atmospheric residue （RAT）, vacuum Residue （RSV） and catalytic Residue of cracking （RCC）. （The residues are obtained from an Algerian crude oil）. As the oil residues are rich for their strongly polar composition, such as the asphaltene resins, and complex structures units （SCU）, which has a role in the formation of coke, and as the dispersion of these latter improves the quality of coke, a study on the stability of aggregation was carried out by the addition of one stabilizer （oil Extract） in the coking process load, The Compounding （Extracted from/RCC oil） has been drived to the best efficiency of coke. The study consists of the influence this is characterized by the analyses Infra-red （IR） and x-ray diffraction （XRD）.
基金supported by the National Basic Research Program of China(2010CB732303,2013CB933102)the Major Project of Chinese Ministry of Education(309019)+2 种基金the National Natural Science Foundation of China(21033006,21073149,21273178)the Program for Changjiang Scholars and Innovative Research Team in University(IRT1036)the Ph.D Programs foundation of Chinese Ministry of Education(20110121110010)
文摘CO oxidation was investigated on various powder oxide supported Pd catalysts by temperature-programined reaction. The pre-reduced catalysts show significantly higher activities than the pre-oxidized ones. Model studies were performed to better understand the oxidation state, reactivities and stabilities of partially oxidized Pd surfaces under CO oxidation reaction condi tions using an in situ infrared reflection absorption spectrometer （IRAS）. Three O/Pd（100） model surfaces, chemisorbed oxygen covered surface, surface oxide and bulk-like surface oxide, were prepared and characterized by low-energy electron diffraction （LEED） and Auger electron spectroscopy （AES）. The present work demonstrates that the oxidized palladium surface is less active for CO oxidation than the metallic surface, and is unstable under the reaction conditions with sufficient CO.
