We calculate the energy eigenvalues and the sate functions of one-electron Quantum Dot （QD） by using a combination of Quantum Genetic Algorithm （QGA） and Hartre-Fock-Roothaan （HFR） method. The linear and the thi...We calculate the energy eigenvalues and the sate functions of one-electron Quantum Dot （QD） by using a combination of Quantum Genetic Algorithm （QGA） and Hartre-Fock-Roothaan （HFR） method. The linear and the third-order nonlinear optical absorption coefficients for the 1s-1p, 1p-1d, and 1d-1f transitions are examined as a function of the incident photon energy for three different values of the stoichiometric ratio. The results show that the stoichiometric ratio, impurity, relaxation time, and dot size have great influence on the optical absorption coefficients of QDs.展开更多
The preparation of PT/PEK c films is reported as well as their dielectric and optical properties. The c axis orientation ratio of the films is 68%. Dielectric constant and loss factor at 10 kHz is about 4.023 F/m and ...The preparation of PT/PEK c films is reported as well as their dielectric and optical properties. The c axis orientation ratio of the films is 68%. Dielectric constant and loss factor at 10 kHz is about 4.023 F/m and 0.003, respectively. The refractive indices of the films, n e and n o, are 1.657 3 and 1.627 8 at 0.63 μm wavelength, respectively. The optical band gap of the film with a thickness of 2.33 μm is found to be 3.06 eV.展开更多
The use of nanostructured composites as catalyst supports is a promising route to prepare catalysts with high selectivity and productivity. In this work, reduced graphene oxide-TiO_2(rGP-x) composites with a variation...The use of nanostructured composites as catalyst supports is a promising route to prepare catalysts with high selectivity and productivity. In this work, reduced graphene oxide-TiO_2(rGP-x) composites with a variation of reduced graphene oxide(rGO) content were synthesized by hydrothermal method. Pd/rGP-x catalysts were prepared in incipient-wetness impregnation method for the direct synthesis of H_2O_2 from H2 and O_2. The morphology and electronic properties of catalysts were investigated by XPS, TEM, and Raman spectroscopy.The ratio of Pd^(2+)/Pd^0 and the hydrophobicity of the catalysts were increased with the rising content of rGO. As the amount of rGO in the catalysts varied in the range of 0.025 wt%–2 wt%, the selectivity of H_2O_2 exhibited a tendency of increasing firstly and then decreasing from 0.1 wt% to 2 wt%. It indicates that good catalytic performance for H_2O_2 synthesis can be achieved only when appropriate amount of rGO is introduced. The H_2O_2 selectivity and productivity of Pd/r GP-0.025 both improved remarkably compared with Pd/P25. This enhancement originated from the combined effects of the proper ratio of Pd^(2+)/Pd^0 and hydrophobicity of the catalyst.展开更多
Some famous local spices were selected to determine their potentials in terms of their aroma and utilization. They included Tea Bush （Ocimum basilicum）, Guinea Black Pepper （Piper guineense）, African Pepper （Xylo...Some famous local spices were selected to determine their potentials in terms of their aroma and utilization. They included Tea Bush （Ocimum basilicum）, Guinea Black Pepper （Piper guineense）, African Pepper （Xylopia aethiopica）, Alden Tree （Tetrapleura tetraptera） and the African Meg Nut or Onion Tree （Blighia unijugata）. Essential oils were extracted from the samples and used for aroma absorption test in a uv-visible spectrometer V2.03. The intensity of aroma was indicated at some peak values of absorption at particular wavelengths. The compounds responsible for the aroma at this peak values were identified by matching their wavelengths with those of known compounds at similar wavelengths of absorption. Thus, a compound such as Quinoline that has hot strong aroma and little bleaching effect was proved to be present in Guinea black pepper ;at the wavelength of 313.0 nm. Benzene with hot strong aroma and flammable effect was also indicated in this spice at the wavelength of 253.0 rim. Proximate analysis carried out showed that these spices have high nutritive values. Some of them such as Guinea black pepper, African Nutmeg and Ethiopian （African） pepper had high ether extract of 20.01, 25.97 and 31.25 respectively, and could be regarded as oil seeds, they contain much of essential oils.展开更多
The earth crust is believed to be made of a mass of minerals and is matched by their importance in human life. The human body, depend like other leaving organisms, on several minerals as essential constituents of its ...The earth crust is believed to be made of a mass of minerals and is matched by their importance in human life. The human body, depend like other leaving organisms, on several minerals as essential constituents of its existence. Metal ions in foodstuff are in different chemical forms, as inorganic salts or organic molecules or complexes with other compounds such as proteins, amino acids, enzymes and some vitamins, among others, that play an important role in human health. Entomophagy, insect consumption by several ethnic groups in Mexico as cultural tradition since prehispanic era represent an option for population to obtain the minerals needed by the body to keep a good health. Escamoles ant eggs of the Liometopumapiculatum M genus, much appreciated either at rural communities as well as in urban cities, contain minerals with a favorable effect in human health. The aim of this study was to investigate the mineral composition of Escamoles and the benefits which can provide to the human body. Sampling was at an arid region of the Hidalgo state on April 2012. Minerals in dry basis, determined by atomic absorption spectrophotometry, with the exception of phosphorus content, obtained from a triple acid digested extract and determined colorimetrically. Data of mineral analysis in dry basis of Escamoles were： total minerals 5.92%; Na 0.079%; K 0.075%; Ca 0.097%; P 0.701%; Fe 0.021%; Zn 0.035% Cu 0.009%; Mg 0.998%; Mn 0.002%. Minerals quantify are not equal to total ash contained because not all of them were assess determined. Elements concentration depends not only on the total mineral composition of foodstuff the inorganic or organic form or interaction among metal ions, but also on their availability and avail of them. Minerals in Escamoles ant eggs have a considerable influence in the condition of human health.展开更多
The effect of grid shape on the properties of transparent conductive films(TCFs) is theoretically analyzed and experimentally verified. The light transmittance by three types of grid shapes: triangle, square and hexag...The effect of grid shape on the properties of transparent conductive films(TCFs) is theoretically analyzed and experimentally verified. The light transmittance by three types of grid shapes: triangle, square and hexagon have been theoretically calculated and simulated. It was found that hexagonal grid unit has the highest light transmittance limit under the practical lattice parameters and its decrease in light transmittance caused by the increase of line width in printing process is the least. The grid of three different shapes with same theoretical transmittance is fabricated through flexographic printing. The result shows that the actual light transmittance of the printed TCFs is lower than its theoretical value because of the inevitable width increase of printed grid lines, with slight difference between the three shapes. However, it is greatly different in terms of conductivity, leading to variation in the quality factor Q(defined as the ratio of light transmittance to total resistance) which represents the performance of TCFs. The Q of hexagonal grid(6.04) is the highest, which is 21% higher than that of the square grid.展开更多
Effects of ions charge-mass ratio on energy and energy spread of accelerated ions in laser driven plasma are investigated in detail by proposing a simple double-layer model for a foil target driven by an ultrastrong l...Effects of ions charge-mass ratio on energy and energy spread of accelerated ions in laser driven plasma are investigated in detail by proposing a simple double-layer model for a foil target driven by an ultrastrong laser. The radiation pressure acceleration mechanism plays an important role on the studied problem. For the ions near the plasma mirror, i.e. electrons layer, the dependence of ions energy on their charge-mass ratio is derived theoretically. It is found that the larger the charge-mass ratio is, the higher the accelerated ions energy gets. For those ions far away from the layer, the dependence of energy and energy spread on ions charge-mass ratio are also obtained by numerical performance. It exhibits that, as ions charge-mass ratio increases, not only the accelerated ions energy but also the energy spread will become large.展开更多
A boradiazaindacenes (BODIPY)-phenol conjugate,1,can act as a colorimetric and fluorometric sensor for sensitive and se-lective measurement of F-over AcO-and H2PO-4 in CH3CN. Sensor 1 gives response to F-in a 1:1 rati...A boradiazaindacenes (BODIPY)-phenol conjugate,1,can act as a colorimetric and fluorometric sensor for sensitive and se-lective measurement of F-over AcO-and H2PO-4 in CH3CN. Sensor 1 gives response to F-in a 1:1 ratio via the deprotonation of the phenolic OH proton,which results in color change from pale yellow to light green and quenching of bright green fluo-rescence.展开更多
文摘We calculate the energy eigenvalues and the sate functions of one-electron Quantum Dot （QD） by using a combination of Quantum Genetic Algorithm （QGA） and Hartre-Fock-Roothaan （HFR） method. The linear and the third-order nonlinear optical absorption coefficients for the 1s-1p, 1p-1d, and 1d-1f transitions are examined as a function of the incident photon energy for three different values of the stoichiometric ratio. The results show that the stoichiometric ratio, impurity, relaxation time, and dot size have great influence on the optical absorption coefficients of QDs.
文摘The preparation of PT/PEK c films is reported as well as their dielectric and optical properties. The c axis orientation ratio of the films is 68%. Dielectric constant and loss factor at 10 kHz is about 4.023 F/m and 0.003, respectively. The refractive indices of the films, n e and n o, are 1.657 3 and 1.627 8 at 0.63 μm wavelength, respectively. The optical band gap of the film with a thickness of 2.33 μm is found to be 3.06 eV.
基金Supported by the National Key Basic Research Program of China(2013CB733505,2013CB733501)the National Natural Science Foundation of China(91334202)+2 种基金the Natural Science Foundation of Jiangsu Province of China(BK2012421,BK20130062)the Research Fund for the Doctoral Program of Higher Education of China(20123221120015)the Project for Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘The use of nanostructured composites as catalyst supports is a promising route to prepare catalysts with high selectivity and productivity. In this work, reduced graphene oxide-TiO_2(rGP-x) composites with a variation of reduced graphene oxide(rGO) content were synthesized by hydrothermal method. Pd/rGP-x catalysts were prepared in incipient-wetness impregnation method for the direct synthesis of H_2O_2 from H2 and O_2. The morphology and electronic properties of catalysts were investigated by XPS, TEM, and Raman spectroscopy.The ratio of Pd^(2+)/Pd^0 and the hydrophobicity of the catalysts were increased with the rising content of rGO. As the amount of rGO in the catalysts varied in the range of 0.025 wt%–2 wt%, the selectivity of H_2O_2 exhibited a tendency of increasing firstly and then decreasing from 0.1 wt% to 2 wt%. It indicates that good catalytic performance for H_2O_2 synthesis can be achieved only when appropriate amount of rGO is introduced. The H_2O_2 selectivity and productivity of Pd/r GP-0.025 both improved remarkably compared with Pd/P25. This enhancement originated from the combined effects of the proper ratio of Pd^(2+)/Pd^0 and hydrophobicity of the catalyst.
文摘Some famous local spices were selected to determine their potentials in terms of their aroma and utilization. They included Tea Bush （Ocimum basilicum）, Guinea Black Pepper （Piper guineense）, African Pepper （Xylopia aethiopica）, Alden Tree （Tetrapleura tetraptera） and the African Meg Nut or Onion Tree （Blighia unijugata）. Essential oils were extracted from the samples and used for aroma absorption test in a uv-visible spectrometer V2.03. The intensity of aroma was indicated at some peak values of absorption at particular wavelengths. The compounds responsible for the aroma at this peak values were identified by matching their wavelengths with those of known compounds at similar wavelengths of absorption. Thus, a compound such as Quinoline that has hot strong aroma and little bleaching effect was proved to be present in Guinea black pepper ;at the wavelength of 313.0 nm. Benzene with hot strong aroma and flammable effect was also indicated in this spice at the wavelength of 253.0 rim. Proximate analysis carried out showed that these spices have high nutritive values. Some of them such as Guinea black pepper, African Nutmeg and Ethiopian （African） pepper had high ether extract of 20.01, 25.97 and 31.25 respectively, and could be regarded as oil seeds, they contain much of essential oils.
文摘The earth crust is believed to be made of a mass of minerals and is matched by their importance in human life. The human body, depend like other leaving organisms, on several minerals as essential constituents of its existence. Metal ions in foodstuff are in different chemical forms, as inorganic salts or organic molecules or complexes with other compounds such as proteins, amino acids, enzymes and some vitamins, among others, that play an important role in human health. Entomophagy, insect consumption by several ethnic groups in Mexico as cultural tradition since prehispanic era represent an option for population to obtain the minerals needed by the body to keep a good health. Escamoles ant eggs of the Liometopumapiculatum M genus, much appreciated either at rural communities as well as in urban cities, contain minerals with a favorable effect in human health. The aim of this study was to investigate the mineral composition of Escamoles and the benefits which can provide to the human body. Sampling was at an arid region of the Hidalgo state on April 2012. Minerals in dry basis, determined by atomic absorption spectrophotometry, with the exception of phosphorus content, obtained from a triple acid digested extract and determined colorimetrically. Data of mineral analysis in dry basis of Escamoles were： total minerals 5.92%; Na 0.079%; K 0.075%; Ca 0.097%; P 0.701%; Fe 0.021%; Zn 0.035% Cu 0.009%; Mg 0.998%; Mn 0.002%. Minerals quantify are not equal to total ash contained because not all of them were assess determined. Elements concentration depends not only on the total mineral composition of foodstuff the inorganic or organic form or interaction among metal ions, but also on their availability and avail of them. Minerals in Escamoles ant eggs have a considerable influence in the condition of human health.
基金supported by the Beijing Municipal Commission of Education Foundation for School Innovation Ability Promotion Plan(Grant No.TJSHG201310015016)the Key Project of Beijing Institute of Graphic Communication(Grant No.Ea201501)the Creative Groups of Materials and Technology of Printed Electronics(Grant No.23190113100)
文摘The effect of grid shape on the properties of transparent conductive films(TCFs) is theoretically analyzed and experimentally verified. The light transmittance by three types of grid shapes: triangle, square and hexagon have been theoretically calculated and simulated. It was found that hexagonal grid unit has the highest light transmittance limit under the practical lattice parameters and its decrease in light transmittance caused by the increase of line width in printing process is the least. The grid of three different shapes with same theoretical transmittance is fabricated through flexographic printing. The result shows that the actual light transmittance of the printed TCFs is lower than its theoretical value because of the inevitable width increase of printed grid lines, with slight difference between the three shapes. However, it is greatly different in terms of conductivity, leading to variation in the quality factor Q(defined as the ratio of light transmittance to total resistance) which represents the performance of TCFs. The Q of hexagonal grid(6.04) is the highest, which is 21% higher than that of the square grid.
基金Supported by the National Natural Science Foundation of China (NNSFC) under Grant Nos. 11175023 and 10834008partially by the Fundamental Research Funds for the Central Universities (FRFCU)
文摘Effects of ions charge-mass ratio on energy and energy spread of accelerated ions in laser driven plasma are investigated in detail by proposing a simple double-layer model for a foil target driven by an ultrastrong laser. The radiation pressure acceleration mechanism plays an important role on the studied problem. For the ions near the plasma mirror, i.e. electrons layer, the dependence of ions energy on their charge-mass ratio is derived theoretically. It is found that the larger the charge-mass ratio is, the higher the accelerated ions energy gets. For those ions far away from the layer, the dependence of energy and energy spread on ions charge-mass ratio are also obtained by numerical performance. It exhibits that, as ions charge-mass ratio increases, not only the accelerated ions energy but also the energy spread will become large.
基金supported by the National Natural Science Foundation of China (20972170 to S-J. Shao)the open fund of State Key Laboratory of Oxo Synthesis & Selective Oxidation (OSSO2008kjk6 to S-J. Shao)the Natural Science Foundation of Gansu Province (096RJ2A033 to Y. Guo)
文摘A boradiazaindacenes (BODIPY)-phenol conjugate,1,can act as a colorimetric and fluorometric sensor for sensitive and se-lective measurement of F-over AcO-and H2PO-4 in CH3CN. Sensor 1 gives response to F-in a 1:1 ratio via the deprotonation of the phenolic OH proton,which results in color change from pale yellow to light green and quenching of bright green fluo-rescence.
