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新型螯合配体BPMPHD的质谱特性研究 被引量:1
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作者 董学畅 戴云 《陕西师范大学学报(自然科学版)》 CAS CSCD 北大核心 2001年第S1期54-58,共5页
通过质谱分析法、理论计算等首次对新型螯合配体BPMPHD的质谱特性进行了较系统的研究 ,并对其基峰。
关键词 螯合配体 BPMPHD 质谱特性 裂解规律
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新型螯合试剂4-取代甲氧苯甲酰PMP的质谱特性
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作者 戴云 董学畅 《质谱学报》 EI CAS CSCD 2000年第3期57-58,共2页
关键词 4-取代甲氧苯甲酰PMP 裂解 质谱特性
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新螯合萃取剂NDBPMP的质谱特性研究
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作者 董学畅 《云南化工》 CAS 2001年第1期1-3,47,共4页
通过质谱法和理论分析首次对新螯合萃取剂NDBPMP的质谱特性进行了较系统的研究与报道 ,并对其基峰稳定性。
关键词 螯合萃取剂 NDBPMP 质谱特性 裂解规律 双(苯基甲基氧代吡唑基)壬二酮
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新螯合萃取剂DDBPMP的质谱特性研究
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作者 董学畅 戴云 《云南民族学院学报(自然科学版)》 2001年第4期473-476,共4页
通过质谱分析法和理论计算首次对新螯合萃取剂DDBPMP的质谱特性进行了较系统的研究与报道 ,并对其基峰。
关键词 螯合萃取剂 DDBPMP 质谱特性 裂解规律 4 4-癸二酰基双PMP 基峰 碎片离子
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4-肉桂酰基PMP质谱特性研究
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作者 董学畅 《云南民族学院学报(自然科学版)》 1999年第2期17-19,22,共4页
通过质谱分析法和理论计算,首次对4-向桂酰基PMP的质谱特性进行了较系统的研究与报道.
关键词 肉桂酰基 PMP 质谱特性 螯合萃取剂 吡唑啉酮
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4,4’—十二烷二酰基双PMP的质谱特性研究
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作者 董学畅 《云南民族学院学报(自然科学版)》 2001年第1期276-278,共3页
通过质谱分析法和理论计算首次对新螯合萃取剂 4,4’ -十二烷二酰基双PMP的质谱特性进行了较系统的研究与报道 ,并对其基峰、主要碎片离子形成的机制和规律进行了研讨 .
关键词 螯合萃取剂 4 4'-十二烷二酰基双PMP 质谱特性 裂解规律
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弹性体交联网分子结构的质谱特性
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作者 王红梅 《橡塑资源利用》 2005年第4期43-43,共1页
关键词 分子结构 弹性体 质谱特性 联网 硫化胶 化学交联 聚合物链 有效方法 NMR
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质谱技术研究儿茶素及儿茶素-锗多聚体特性 被引量:13
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作者 黄河宁 胡晓慧 +4 位作者 黄河清 颜利 陈东仕 欧阳高亮 卓惠钦 《分析化学》 SCIE EI CAS CSCD 北大核心 2006年第1期52-56,共5页
采用HPLC-ESI-Q-TOF和MALD I-TOF质谱技术分析儿茶素组成与结构,发现儿茶素中的表没食子儿茶素没食子酸酯(EGCG)具有多聚体特性。有机化学法合成EGCG-Ge4+化合物,并经HPLC进一步分离纯化。红外光谱和质谱技术分析并证实EGCG不仅能形成... 采用HPLC-ESI-Q-TOF和MALD I-TOF质谱技术分析儿茶素组成与结构,发现儿茶素中的表没食子儿茶素没食子酸酯(EGCG)具有多聚体特性。有机化学法合成EGCG-Ge4+化合物,并经HPLC进一步分离纯化。红外光谱和质谱技术分析并证实EGCG不仅能形成多聚体,而且还能络合金属锗(包括其他金属离子),成为EGCG-Ge4+和EGCG-Ge4+多聚体。EGCG-Ge4+抑制肺癌细胞生长速率明显高于EGCG,其提高幅度约为30%~40%左右。 展开更多
关键词 儿茶素 多聚体 表没食子儿茶景-锗 质谱特性 抗癌药物
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Analysis of a Class of Logical Functions over Galois and Z_m Rings 被引量:1
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作者 陈卫红 曾洪杰 《Chinese Quarterly Journal of Mathematics》 CSCD 2002年第4期105-110,共6页
In this paper, the author analyzed some cryptographic properties of a class of logical functions, f(x,y)=(q(x),...,q(x))·y+h(x),over Galois rings and residue rings, presented the relationship between the characte... In this paper, the author analyzed some cryptographic properties of a class of logical functions, f(x,y)=(q(x),...,q(x))·y+h(x),over Galois rings and residue rings, presented the relationship between the character spectrum of f(x,y) and the character speetrum of q(x),h(x) and the relationship between the cryptographic properties of f(x,y) and the cryptographic properties of h(x). 展开更多
关键词 logical function character spectrum cryptographic properties
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Spectral Response of Different Eroded Soils in Subtropical China: A Case Study in Changting County, China 被引量:1
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作者 LIN Chen ZHOU Sheng-lu +2 位作者 WU Shao-hua ZHU Qing DANG Qi 《Journal of Mountain Science》 SCIE CSCD 2014年第3期697-707,共11页
Hyper-spectral data is widely used to determine soil properties. However, few studies have explored the soil spectral characteristics as response to soil erosion. This study analysed the spectral response of different... Hyper-spectral data is widely used to determine soil properties. However, few studies have explored the soil spectral characteristics as response to soil erosion. This study analysed the spectral response of different eroded soils in subtropical China, and then identify the spectral characteristics and soil properties that better discriminate softs with different erosion degrees. Two methods were compared: direct identification by inherent spectral characteristics and indirect identification by predictions of critical soft properties. Results showed that the spectral curves for different degrees of erosion were similar in morphology, while overall reflectance and characteristics of specific absorption peaks were different. When the first method is applied, some differences among different eroded groups were found by integration of associated indicators. However, the index of such indicators showed apparent mixing and crossover among different groups, which reduced the accuracy of identification. For the second method, the correlation between critical soil properties, such as soil organic matter (SOM), iron and aluminium oxides and reflectance spectra, was analysed. The correlation coefficients for the moderate eroded group were primarily between -0.3 to -0.5, which were worse than the other twogroups. However, the maximum value of R2 was obtained as 0.86 and 0.94 for the non-apparent eroded and the severe group. Furthermore, these two groups also showed some differences in the spectral response of iron complex state (Fep), Aluminium amorphous state (Alo) and the modelling results for soil organic matter (SOM). The study proved that it is feasible to identify different degrees of soil erosion by hyperspectral data, and that indirect identification by modelling critical soil properties and reflectance spectra is much better than direct identification. These results indicate that hyper-spectral data may represent a promising tool in monitoring and modelling soil erosion. 展开更多
关键词 Soil erosion Erosion degree HYPER-SPECTRAL Aluminium oxides Iron oxide SOM
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Chemical and spectroscopic characterization of dissolved humic substances in a mangrove-fringed estuary in the eastern coast of Hainan Island,China 被引量:7
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作者 张耀玲 杜金洲 +3 位作者 彭浡 张芬芬 赵欣 张经 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2013年第2期454-463,共10页
Mangrove-derived dissolved organic matter (DOM) has an important effect on estuarine and coastal area on a large scale. In order to improve the understanding of origin, composition, and fate of DOM in mangrove-fring... Mangrove-derived dissolved organic matter (DOM) has an important effect on estuarine and coastal area on a large scale. In order to improve the understanding of origin, composition, and fate of DOM in mangrove-fringed estuarine and coastal areas, dissolved humic substances (DHS) were isolated from one mangrove pore-water sample and one near-shore seawater sample downstream the mangrove pore-water site in the eastern coast of Hainan Island, South China. Fulvic acids, humic acids and XAD-4 fractions were obtained from the two water samples by using a two-column array of XAD-g and XAD-4 resins. Chemica~ and spectroscopic methods were used to analyze the features of these DHS. Compared to the mangrove pore-water DHS, the near-shore seawater DHS were found rich in 13C with lower C/N ratios and more aliphatic compounds and carbohydrates, but less aromatic structures and carboxyl groups. As for the three fractions of the two DHS, XAD-4 fractions contain more aliphatics, carbohydrates, carboxyl groups, and enrich in 13C with respect to both fulvic and humic acids. Photo-oxidation transformation and contribution from marine-derived DOM were considered as the main reasons resulted in the difference in compositional features for these DHS in this study. 展开更多
关键词 MANGROVE fulvic acid humic acid XAD-4 fraction FTIR NMR
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INFRARED THERMAL IMAGE STUDY ON THE FOREWARNING OF COAL AND SANDSTONE FAILURE UNDER LOAD 被引量:2
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作者 吴立新 王金庄 《Journal of Coal Science & Engineering(China)》 1997年第2期15-23,共9页
In the experimental study, AGE-782 thermal instrument was used to detect the infrared radiation variation of coal and sandstone (wave-length range 3.6~5.5 μm was used). It's discovered that coal and sandstone fa... In the experimental study, AGE-782 thermal instrument was used to detect the infrared radiation variation of coal and sandstone (wave-length range 3.6~5.5 μm was used). It's discovered that coal and sandstone failure under load have three kinds of infrared thermal features as well as infrared forewarning messages. That are: (1) temperature rises gradually but drops before failure ; (2) temperature rises gradually but quickly rises before failure; (3) first rises,then drops and lower temperature emerges before failure. The further researches and the prospect of micro-wave remote sensing detection .on ground pressure is also discussed. 展开更多
关键词 forewarning message of Coal and sandstone failure infrared detection infrared thermal image underground pressure microwave remote sensing
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