Abundant and well-preserved remains of noncalcareous algae and soft-bodied metazoans were collected from Middle Cambrian Kaili biota in Taijiang county, Guizhou Province, China. These remains provide further evidence ...Abundant and well-preserved remains of noncalcareous algae and soft-bodied metazoans were collected from Middle Cambrian Kaili biota in Taijiang county, Guizhou Province, China. These remains provide further evidence for the wide geographic distribution of many Burgess Shale taxa. Among the algae, 5 genera (including two new genera) and 5 species are described. They are Marpolia spissa Walcott, Acinocricus stichus Conway Morris and Robison, Udotealga erecta Yang, Eosargassum sawata Yang, and Rhizophyton zhaoyuanlongii Yang. Contrasting the macroalgal fossil assemblage in the Kaili biota with one in the Burgess Shale biota, it is clear that similarity of the Kaili biota and the Burgess Shale biota is reflected by the same content of not only the soft-bodied metazoans, but also the noncalcareous algae.展开更多
This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province(southern China). The chemical ...This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province(southern China). The chemical weathering characteristics of the studied profile were investigated and the inheritance relationships between the terra rossa and overlying strata were discussed. The results show that there is no remarkable variation in the major elements and weathering indices from the rock–soil interface to the topsoil, indicating that the studied profile was not typical for in situ crustal chemical weathering. The terra rossa were mainly composed of Si O_2, Al_2O_3 and Fe_2O_3. Compared with the insoluble residues and overlying strata, the terra rossa are characterized by an enrichment of Y and Cs and depletion of Ba and Sr. The subsoil shows a notable Ce negative anomaly, characterized by heavy rare earth element enrichment(L/H = 1.55–3.74), whereas the topsoil shows a positive Ce anomaly with light rare earth element enrichment(L/H = 5.93–9.14). According to Laterite-forming capacity estimates, the terra rossa could not have only been formed from acid-insoluble residues from the bedrock; Al_2O_3 versus Fe_2O_3and Nb plotted against Ta show significant positive correlations between the terra rossa and overlying strata. The Eu/Eu* versusGd_N/Yb_Nand ternary diagrams for Sc, Th, Zr, and Ta suggest that the overlying strata could also provide parent materials for the genesis of terra rossa.展开更多
Karst rocky desertification is a geo-ecological problem in Southwest China. The rocky desertification risk zone delineation could be used as a guide for the regional and hierarchical rocky desertification management a...Karst rocky desertification is a geo-ecological problem in Southwest China. The rocky desertification risk zone delineation could be used as a guide for the regional and hierarchical rocky desertification management and prevention. We chose the middle and lower reaches of the Houzhai underground basin on the karst plateau in Puding County, Guizhou Province, China as the study area and selected land use type, elevation, slope, aspect, lithology and settlement buffer as the main driving factors of the rocky desertification. The potential risk of rocky desertification was quantifed with the factor-weights union method and statistical analysis method. Five grades of rocky desertification risk were delineated based on Geographic Information System. The extremely low, low, moderate, high and extremely high rocky desertification risk zones accounted for 5.01%, 44.17%, 33.92%, 15.59% and 1.30%, respectively. As a whole, the rocky desertification risk level was moderate because the area of low and moderate rocky desertification risk zones occupied 78.09% of the study area. However, more than half of the area (about 50.81%) was predicted to have moderate rocky desertification risk and above, indicating that the study area was subject to rocky desertification. Rocky desertification risk was higher in the southeast and lower in the northwest of the study area. Distinct differences in the distribution of rocky desertification risk zones corresponding to different factors have been found.展开更多
The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated...The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated in the rainy season (from April to June). Generaily, the leaching of soil nutrients from thesurface layer of red soils was in the order of Ca > Mg > K > NO3-N. In fertilization treatment, the totalamount of soil nutrients leached out of the surface layer in a red soil derived from granite was the highest inall soils. The uptake by grass decreased the leaching of fertilizer ions in surface layer, particularly for NO3-N.Soil total N and exchangeable K, Ca and Mg in the surface layer decreased with leaching and grass uptakeduring the 2 years without new fertilization of urea, Ca(H2PO4)2, KCl, CaCO3 and MgCO3. Ca movedfrom the application layer (0~5 cm) of fertilizer and accumulated in the 10~30 cm depth in the soils studiedexcept that derived from Quaternary red clay. The deficiency of soil exchangeable K will become a seriousdegradation process facing the Southeast China.展开更多
Continuous measurements of speciated atmo- spheric mercury (Hg), including gaseous elemental mer- cury (GEM), particulate mercury (PHg), and reactive gaseous mercury (RGM) were conducted in Guizhou Pro- vince,...Continuous measurements of speciated atmo- spheric mercury (Hg), including gaseous elemental mer- cury (GEM), particulate mercury (PHg), and reactive gaseous mercury (RGM) were conducted in Guizhou Pro- vince, southwestern China. Guiyang Power Plant (GPP), Guiyang Wujiang Cement Plant, Guizhou Aluminum Plant (GAP), and Guiyang Forest Park (GFP) in Guiyang were selected as study sites. Automatic Atmospheric Mercury Speciation Analyzers (Tekran 2537A) were used for GEM analysis. PHg and RGM were simultaneously collected by a manual sampling system, including elutriator, coupler/ impactor, KCl-coated annular denuder, and a filter holder. Results show that different emission sources dominate different species of Hg. The highest average GEM value was 22.2 ±28.3 ng·m-3 and the lowest 6.1 ± 3.9 ng·m-3, from samples collected at GPP and GAP, respectively. The maximum average PHg was 1984.9 pg·m-3 and the mini- mum average 55.9 pg·m-3, also from GPP and GAP, respectively. Similarly, the highest average RGM of 68.8 pg·m-3 was measured at GPP, and the lowest level of 20.5 pg·m-3 was found at GAP. We conclude that coal combustion sources are still playing a key role in GEM; traffic contributes significantly to PHg; and domestic pol- lution dominates RGM.展开更多
The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks...The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks.This age is identical to the eruption age of the Emeishan large igneous province, indicating a synchronous magmatic event. The rare-earth-element patterns of laterite samples were similar to those of the weathered basalt sample, and sub-parallel to those of the Emeishan high-Ti basalts,implying a genetic relationship between the laterite and the basalt. The Chemical Index of Alteration values of laterite ranged from 96 to 98, suggesting a high degree of weathering. SiO_2, MgO, and alkaline metal elements decreased with increasing degree of weathering, while Al_2O_3, Fe_2O_3,and TiO_2 increased. We found the highest TiO_2 in laterite and the lowest in pillow basalts, indicating that Ti migrated from basalt to laterite.Our U–Pb dating and whole-rock elemental geochemistry analyses suggest that the Emeishan basalt is the parent rock of the Shazi anatase ore deposit.Based on our analysis, we propose a metallogenic model to explain the ore-forming process, in which the karst terrain formed by the Emeishan mantle plume and the subsequent basaltic magma eruption were the key factors in the formation the Shazi anatase ore deposit.展开更多
Xianglushan-type iron deposits are one of the new types of iron deposits found in the Weining Area of Western Guizhou. The iron-bearing rock system is a paleo-weathered crustal sedimentary(or accumulating) stratum bet...Xianglushan-type iron deposits are one of the new types of iron deposits found in the Weining Area of Western Guizhou. The iron-bearing rock system is a paleo-weathered crustal sedimentary(or accumulating) stratum between the top of the Middle-Late Permian Emeishan basalt formation and the Late Permian Xuanwei formation. Iron ore is hosted in the Lower-Middle part of the rock system. In terms of the genesis of mineral deposit, this type of deposit should be a basalt paleo-weathering crustal redeposit type, very different from marine sedimentary iron deposits or continental weathering crust iron deposits. Based on field work and the analytical results of XRD Powder Diffraction, Electron Probe, Scanner Electron Microscope, etc., the geological setting of the ore-forming processes and the deposit features are illustrated in this paper. The ore-forming environment of the deposit and the Emeishan basalt weathering mineralization are also discussed in order to enhance the knowledge of the universality and diversity of mineralization of the Emeishan Large Igneous Province(ELIP), which may be a considerable reference to further research for ELIP metallogenic theories, and geological research for iron deposits in the paleo-weathering crust areas of the Emeishan basalt,Southwestern, China.展开更多
The use of high As-bearing coals has caused more than 3,000 cases of arsenosis patients in southwest Guizhou Province, China. The mode of occurrence of arsenic in coal is an important key role in understanding its beh...The use of high As-bearing coals has caused more than 3,000 cases of arsenosis patients in southwest Guizhou Province, China. The mode of occurrence of arsenic in coal is an important key role in understanding its behavior during usage and damage pathway to human health. Coal samples from endemic arsenosis areas were analyzed with INAA, EMPA, SEM-EDX, LTA, XRD, XAFS, and sequential leaching experiment. Arsenic in pyrite is from under the limit of EMPA to 1.75%, and in most cases, the content of arsenic is lower than 0.5%. Besides pyrite and arsenopyrite, SEM-EDX combined with LTA and XRD find that sulfates, clay and phosphates also contain arsenic. XAFS shows that arsenic mainly exists in the form of As^5+. More than 50% of arsenic stayes in residual solid and combined with organic matrix in two samples, but most arsenic is leached out in other samples. The occurrence of such exceptionally high As contents in coal and the fact that the arsenic is dominantly organically associated are unique observations.展开更多
Topography, especially altitude, will influence the way, process and characteristics of land cover changes in mountainous area, simultaneously, the vertical difference of land cover changes will affect soil quality an...Topography, especially altitude, will influence the way, process and characteristics of land cover changes in mountainous area, simultaneously, the vertical difference of land cover changes will affect soil quality and regional ecological environment. Therefore, the gradient relationship analysis between land cover changes and altitude is very important for regional sustainability. This study investigated land cover dynamics based on land cover data from a typical mountainous area in the Guizhou-Guangxi karst mountain area, China, in 2000 and 2010, then explored the relationship between altitude and land cover change and analyzed different drivers of land cover change at different altitudes. Our findings are as follows. 1) From 2000 to 2010, the total area of land cover transition was 7167.04 km^2 or 2.8% of the region. The increasing area of build-up land(926.23 km^2) was larger than that of forest(859.38 km^2), suggesting that the urban construction speed was higher than that of reforestation. 2) Intensity of land cover transition in northwestern Guizhou-Guangxi karst mountain area was much larger than that of southeast part and their transition trend was also significantly different, which was consistent with regional population and economy. 3) Human activity was the most dramatic at altitudes between 0–500 m. For 500–1000 m, grassland mainly converted to forest and build-up land. Area of land cover transition was the greatest between 1000–1500 m, while above 1500 m, the transition of grassland was the most obvious. 4) The drivers of land cover change varied. Land cover change was positively correlated with gross domestic product and population density but was inversely related to relief amplitude. There were correlations between land cover change and distance to roads and rivers, and their correlations varied with altitude. By revealing patterns and causes of land cover changes in different altitudes, we hope to understand the vertical dependence of land cover changes, so as to improve land productivity and protect land ecological environment scientifically.展开更多
The black shale series that formed in the Edi- acaran-Cambrian transition are important stratigraphic records of the co-evolution of the paleo-ocean, -climate, and -biology. In this study, we measured Re-Os isotopic c...The black shale series that formed in the Edi- acaran-Cambrian transition are important stratigraphic records of the co-evolution of the paleo-ocean, -climate, and -biology. In this study, we measured Re-Os isotopic compositions of the black shale in the Niutitang Formation from the Gezhongwu section in Zhijin, Guizhou Province. The samples had high Re and Os contents, with Re ranging from 21.27 to 312.78 ng/g and Os ranging from 0.455 to 7.789 ng/g. The Re-Os isotope isochron age of 522.9 ± 8.6 Ma implies deposition of the Niutitang black shale predated the Chengjiang Fauna, providing an age constraint for the expansion of oceanic anoxia in the study area. The initial ^187Os/^188Os ratio of 0.826 ± 0.026 indi- cates that enhanced continental weathering might have triggered the expansion of the oceanic anoxia.展开更多
Chinese giant salamander(CGS, Andrias davidianus) is experiencing the threat of extinction. It is disappearing gradually, because of overharvesting, environmental pollution, specially river pollution, activity of huma...Chinese giant salamander(CGS, Andrias davidianus) is experiencing the threat of extinction. It is disappearing gradually, because of overharvesting, environmental pollution, specially river pollution, activity of human exploitation, and so on. We conducted community interview fieldworks to collect respondent data from Xieba Country(not reserve) situated in Zhengan County of Guizhou Province, where one of the places known by historical giant salamander records in Guizhou. Through the analysis of the collected data, we created quantitative data of use for conservation management on the local status of salamander populations, and we compared our data with those available data of Y. Pan et al., who investigated the status of CGS in 3 reserves in Guizhou Province in 2015.The conclusions have a similar trend, which proved that the collected data were creditable. Through statistical analysis of the comparison data, the number of wild CGS decreased actually followed the increase of artificial framing.Because of the source of breeding to catch wild CGS, overharvesting was likely the most reason to make wild CGS decline.展开更多
Karst rocky desertification is one of the major ecological and environmental problems that threaten the sustainable development of southwestern China. It is caused by irrational and intensive land-use patterns in kars...Karst rocky desertification is one of the major ecological and environmental problems that threaten the sustainable development of southwestern China. It is caused by irrational and intensive land-use patterns in karst geo-ecological environment. Therefore, it is vital to identify how human forces work on this degraded environment. Based on the soil erosion information in 2000 and remote sensing images of Guanling County collected in 2000 and 2007, four grades of karst rocky desertification data in 14 villages of Guanling County were extracted. Impacts of population, affluence, and other human forces on karst rocky desertification were analyzed using STIRPAT model. The results show that:1) Factors of population and affluence had strong influence on karst rocky desertification. In the STIRPAT model analysis, the population and affluence coefficients were positive, indicating that the increase in population and affluence would lead to more serious desertification. 2) Factors of farmer correlated with karst rocky desertification negatively, especially the way of viewing the relationship between people and nature, and the level of knowledge about rocky desertification. Government behavior was not a significant factor in this analysis. 3) The findings provide evidence that STIRPAT model can be used to analyze the relationship between human driving forces and rocky desertification.展开更多
HUNAN’S“king of mask changing” is the 70-year-old Zeng Jingui. He spent most of his working life in Chinese opera,and has brought this passion into his retirement. The 70-year-old operates an opera mask workshop fr...HUNAN’S“king of mask changing” is the 70-year-old Zeng Jingui. He spent most of his working life in Chinese opera,and has brought this passion into his retirement. The 70-year-old operates an opera mask workshop from his two-room apartment. It is crammed with thousands of different-sized facemasks seen in traditional Chinese operas.展开更多
Based on the results of multipurpose regional geochemical surveys of the Guizhou Province, geochemical characteristics of soil Se and Se-rich land resources in the central area of Guiyang City were studied and evaluat...Based on the results of multipurpose regional geochemical surveys of the Guizhou Province, geochemical characteristics of soil Se and Se-rich land resources in the central area of Guiyang City were studied and evaluated.Major conclusions are as follows:(1) the Se content in surface soil of the central area of Guiyang City was 0.17–2.89 mg kg^(-1), and the average was 0.78 mg kg^(-1), which were respectively 2.6 and 3.9 times of the national background value of soil and the world background value of soil.The Se content in deep soil was 0.11–1.48 mg kg^(-1), and the average was 0.44 mg kg^(-1), which were respectively 1.5 and2.2 times of the national background value of soil and the world background value of soil. The soil Se content decreased with the increase in the soil depth on the vertical profile, and the surface soil had a higher Se content.(2)Distribution of Se content was mainly affected by parent material, physicochemical properties of soil and other components, soil type, and land use type. Parent material played a key role, as the soil Se content was mainly originated from parent rock and increased with the background value of Se in parent rock, physicochemical properties of soil and other components had certain influences upon the Se content. Se was shown to have a significant linear positive correlation with S and organic carbon but no significant correlation with p H value. Se content varied with different types of soil as follows: skeleton soil > yellow soil > paddy soil > limestone soil > purple soil. Land use type also hadcertain influences upon the soil Se content as follows: dry land > construction land > garden plot > grassland =garden plot > forest land.(3) Taking 0.4 mg kg^(-1)B x(Se) <3.0 mg kg^(-1) as the standard for Se-rich soil, Se-rich soil of the study area covered an area of 2224 km^2 and 92.5% of the total area; the remaining is general soil. The study area had no Se-excess soil. Therefore, the central area of Guiyang City has a high proportion of Se-rich land, a large area of Serich land resources, and a moderate selenium enrichment strength, which have been rarely seen anywhere and provide advantageous resources for the development of Se-rich featured agriculture.展开更多
The effects of acid deposition on pine forest ecosystems in Longli of Guizhou Province, southwestern China are studied using indoor experiments and model simulations. Indoor experiments are designed to explore the alu...The effects of acid deposition on pine forest ecosystems in Longli of Guizhou Province, southwestern China are studied using indoor experiments and model simulations. Indoor experiments are designed to explore the aluminum toxicity on pine seedlings, and the long-term soil acidification model (LTSAM) and a terrestrial biogeochemistry model (CENTURY) are used to simulate the influences of acid deposition on pine forest ecosystems. The indoor experiment results of aluminum toxicishow that aluminum ions in solution limit plant growth and acid deposition enhances this effect by facilitating the release of aluminum ions from the soil. Pine seedling bio- mass and root elongation decrease as the aluminum concentration increases. The results of model simulations show that the soil chemis- try varies significantly with different changes in acid deposition. When the acid deposition increases, the pH value in the soil solution decreases and the soil A13+ concentration increases. The increased acid deposition also has negative impacts on the forest ecosystem, i.e., decreases plant biomass, net primary productivity (NPP) and net C02 uptake. As a result, the soil organic carbon (SOC) decreases be- cause of the limited supply of decomposition material. Thus acid deposition need be reduced to help protect the forest ecosystems.展开更多
13 water quality parameters were tested from 38 reaches of 34 counties in Guizhou where Chinese giant salamander(Andrias davidianus) distributed over the past 30 years. Dissolved oxygen and p H were found to be signif...13 water quality parameters were tested from 38 reaches of 34 counties in Guizhou where Chinese giant salamander(Andrias davidianus) distributed over the past 30 years. Dissolved oxygen and p H were found to be significant determinants of the species distribution in recent years(P<0.05). There was no Chinese giant salamander distribution in the recent five years in rivers with dissolved solids of greater than 415 mg/L, conductivity of greater than 639 us/cm, salinity of greater than 0.31 ppt and total hardness of greater than 150 mg/L. Sensitive to environment, the Chinese giant salamander is an important indicator for environmental quality, so it could be used as one of the environmental indicator. Eutrophication, chemical fertilizer, pesticides and inorganic pollutants may be one of reasons driving wild CGS into extinction.展开更多
文摘Abundant and well-preserved remains of noncalcareous algae and soft-bodied metazoans were collected from Middle Cambrian Kaili biota in Taijiang county, Guizhou Province, China. These remains provide further evidence for the wide geographic distribution of many Burgess Shale taxa. Among the algae, 5 genera (including two new genera) and 5 species are described. They are Marpolia spissa Walcott, Acinocricus stichus Conway Morris and Robison, Udotealga erecta Yang, Eosargassum sawata Yang, and Rhizophyton zhaoyuanlongii Yang. Contrasting the macroalgal fossil assemblage in the Kaili biota with one in the Burgess Shale biota, it is clear that similarity of the Kaili biota and the Burgess Shale biota is reflected by the same content of not only the soft-bodied metazoans, but also the noncalcareous algae.
基金financially supported by the National Basic Research Program of China(Grants No.2006CB403202)
文摘This study presents bulk chemical compositions of the Tongmuling soil profile, which developed on dolostone, and the overlying strata covering the bedrock in the central Guizhou province(southern China). The chemical weathering characteristics of the studied profile were investigated and the inheritance relationships between the terra rossa and overlying strata were discussed. The results show that there is no remarkable variation in the major elements and weathering indices from the rock–soil interface to the topsoil, indicating that the studied profile was not typical for in situ crustal chemical weathering. The terra rossa were mainly composed of Si O_2, Al_2O_3 and Fe_2O_3. Compared with the insoluble residues and overlying strata, the terra rossa are characterized by an enrichment of Y and Cs and depletion of Ba and Sr. The subsoil shows a notable Ce negative anomaly, characterized by heavy rare earth element enrichment(L/H = 1.55–3.74), whereas the topsoil shows a positive Ce anomaly with light rare earth element enrichment(L/H = 5.93–9.14). According to Laterite-forming capacity estimates, the terra rossa could not have only been formed from acid-insoluble residues from the bedrock; Al_2O_3 versus Fe_2O_3and Nb plotted against Ta show significant positive correlations between the terra rossa and overlying strata. The Eu/Eu* versusGd_N/Yb_Nand ternary diagrams for Sc, Th, Zr, and Ta suggest that the overlying strata could also provide parent materials for the genesis of terra rossa.
基金Under the auspices of Major Basic Reseach Development Program of China (973 Program) (No. 2006CB403201)
文摘Karst rocky desertification is a geo-ecological problem in Southwest China. The rocky desertification risk zone delineation could be used as a guide for the regional and hierarchical rocky desertification management and prevention. We chose the middle and lower reaches of the Houzhai underground basin on the karst plateau in Puding County, Guizhou Province, China as the study area and selected land use type, elevation, slope, aspect, lithology and settlement buffer as the main driving factors of the rocky desertification. The potential risk of rocky desertification was quantifed with the factor-weights union method and statistical analysis method. Five grades of rocky desertification risk were delineated based on Geographic Information System. The extremely low, low, moderate, high and extremely high rocky desertification risk zones accounted for 5.01%, 44.17%, 33.92%, 15.59% and 1.30%, respectively. As a whole, the rocky desertification risk level was moderate because the area of low and moderate rocky desertification risk zones occupied 78.09% of the study area. However, more than half of the area (about 50.81%) was predicted to have moderate rocky desertification risk and above, indicating that the study area was subject to rocky desertification. Rocky desertification risk was higher in the southeast and lower in the northwest of the study area. Distinct differences in the distribution of rocky desertification risk zones corresponding to different factors have been found.
文摘The leaching and redistribution of nutrients in the surface layer of 4 types of red soils in SoutheastChina were studied with a lysimeter experiment under field conditions. Results showed that the leachingconcentrated in the rainy season (from April to June). Generaily, the leaching of soil nutrients from thesurface layer of red soils was in the order of Ca > Mg > K > NO3-N. In fertilization treatment, the totalamount of soil nutrients leached out of the surface layer in a red soil derived from granite was the highest inall soils. The uptake by grass decreased the leaching of fertilizer ions in surface layer, particularly for NO3-N.Soil total N and exchangeable K, Ca and Mg in the surface layer decreased with leaching and grass uptakeduring the 2 years without new fertilization of urea, Ca(H2PO4)2, KCl, CaCO3 and MgCO3. Ca movedfrom the application layer (0~5 cm) of fertilizer and accumulated in the 10~30 cm depth in the soils studiedexcept that derived from Quaternary red clay. The deficiency of soil exchangeable K will become a seriousdegradation process facing the Southeast China.
基金support was provided by the National Natural Science Foundation of China(No.40773067)
文摘Continuous measurements of speciated atmo- spheric mercury (Hg), including gaseous elemental mer- cury (GEM), particulate mercury (PHg), and reactive gaseous mercury (RGM) were conducted in Guizhou Pro- vince, southwestern China. Guiyang Power Plant (GPP), Guiyang Wujiang Cement Plant, Guizhou Aluminum Plant (GAP), and Guiyang Forest Park (GFP) in Guiyang were selected as study sites. Automatic Atmospheric Mercury Speciation Analyzers (Tekran 2537A) were used for GEM analysis. PHg and RGM were simultaneously collected by a manual sampling system, including elutriator, coupler/ impactor, KCl-coated annular denuder, and a filter holder. Results show that different emission sources dominate different species of Hg. The highest average GEM value was 22.2 ±28.3 ng·m-3 and the lowest 6.1 ± 3.9 ng·m-3, from samples collected at GPP and GAP, respectively. The maximum average PHg was 1984.9 pg·m-3 and the mini- mum average 55.9 pg·m-3, also from GPP and GAP, respectively. Similarly, the highest average RGM of 68.8 pg·m-3 was measured at GPP, and the lowest level of 20.5 pg·m-3 was found at GAP. We conclude that coal combustion sources are still playing a key role in GEM; traffic contributes significantly to PHg; and domestic pol- lution dominates RGM.
基金supported by the Natural Science Foundation of China (Grant No.41262005)
文摘The Shazi deposit is a large-scale anatase deposit in Qinglong, Guizhou Province. Zircon grains from this deposit yielded a zircon U–Pb age of *259 Ma, representing the formation age of the deposit's parent rocks.This age is identical to the eruption age of the Emeishan large igneous province, indicating a synchronous magmatic event. The rare-earth-element patterns of laterite samples were similar to those of the weathered basalt sample, and sub-parallel to those of the Emeishan high-Ti basalts,implying a genetic relationship between the laterite and the basalt. The Chemical Index of Alteration values of laterite ranged from 96 to 98, suggesting a high degree of weathering. SiO_2, MgO, and alkaline metal elements decreased with increasing degree of weathering, while Al_2O_3, Fe_2O_3,and TiO_2 increased. We found the highest TiO_2 in laterite and the lowest in pillow basalts, indicating that Ti migrated from basalt to laterite.Our U–Pb dating and whole-rock elemental geochemistry analyses suggest that the Emeishan basalt is the parent rock of the Shazi anatase ore deposit.Based on our analysis, we propose a metallogenic model to explain the ore-forming process, in which the karst terrain formed by the Emeishan mantle plume and the subsequent basaltic magma eruption were the key factors in the formation the Shazi anatase ore deposit.
基金supported by PMO of Guizhou Institute of Technology for the Study of Iron Deposit Oreforming Rule,Ore-controlling Factors and Ore-forming Predication in the Western Region of Guizhou Province(No.406,2015)PMO of Innovation Team of Guizhou General Institutes of Higher Education for Survey of Underlying Ore Deposit(No.56,2015)+1 种基金the Education Reform of the Guizhou Institute of Technology(No.2015JGY18)the Study for Existing State of Rare Earth Elements in Low Grade Iron Ore from Associated Multi-metal Deposits in Northwest Guizhou(Ref.No.05,2014)
文摘Xianglushan-type iron deposits are one of the new types of iron deposits found in the Weining Area of Western Guizhou. The iron-bearing rock system is a paleo-weathered crustal sedimentary(or accumulating) stratum between the top of the Middle-Late Permian Emeishan basalt formation and the Late Permian Xuanwei formation. Iron ore is hosted in the Lower-Middle part of the rock system. In terms of the genesis of mineral deposit, this type of deposit should be a basalt paleo-weathering crustal redeposit type, very different from marine sedimentary iron deposits or continental weathering crust iron deposits. Based on field work and the analytical results of XRD Powder Diffraction, Electron Probe, Scanner Electron Microscope, etc., the geological setting of the ore-forming processes and the deposit features are illustrated in this paper. The ore-forming environment of the deposit and the Emeishan basalt weathering mineralization are also discussed in order to enhance the knowledge of the universality and diversity of mineralization of the Emeishan Large Igneous Province(ELIP), which may be a considerable reference to further research for ELIP metallogenic theories, and geological research for iron deposits in the paleo-weathering crust areas of the Emeishan basalt,Southwestern, China.
文摘The use of high As-bearing coals has caused more than 3,000 cases of arsenosis patients in southwest Guizhou Province, China. The mode of occurrence of arsenic in coal is an important key role in understanding its behavior during usage and damage pathway to human health. Coal samples from endemic arsenosis areas were analyzed with INAA, EMPA, SEM-EDX, LTA, XRD, XAFS, and sequential leaching experiment. Arsenic in pyrite is from under the limit of EMPA to 1.75%, and in most cases, the content of arsenic is lower than 0.5%. Besides pyrite and arsenopyrite, SEM-EDX combined with LTA and XRD find that sulfates, clay and phosphates also contain arsenic. XAFS shows that arsenic mainly exists in the form of As^5+. More than 50% of arsenic stayes in residual solid and combined with organic matrix in two samples, but most arsenic is leached out in other samples. The occurrence of such exceptionally high As contents in coal and the fact that the arsenic is dominantly organically associated are unique observations.
基金supported by the National Key Basic Research Program of China (973Program, 2015CB452706)the youth talent team program of the Institute of Mountain Hazards and Environment, CAS (SDSQB-2015-01)+1 种基金the National Natural Science Foundation of China (41401198 and 41571527)the Youth Innovation Promotion Association, CAS(No. 2016332)
文摘Topography, especially altitude, will influence the way, process and characteristics of land cover changes in mountainous area, simultaneously, the vertical difference of land cover changes will affect soil quality and regional ecological environment. Therefore, the gradient relationship analysis between land cover changes and altitude is very important for regional sustainability. This study investigated land cover dynamics based on land cover data from a typical mountainous area in the Guizhou-Guangxi karst mountain area, China, in 2000 and 2010, then explored the relationship between altitude and land cover change and analyzed different drivers of land cover change at different altitudes. Our findings are as follows. 1) From 2000 to 2010, the total area of land cover transition was 7167.04 km^2 or 2.8% of the region. The increasing area of build-up land(926.23 km^2) was larger than that of forest(859.38 km^2), suggesting that the urban construction speed was higher than that of reforestation. 2) Intensity of land cover transition in northwestern Guizhou-Guangxi karst mountain area was much larger than that of southeast part and their transition trend was also significantly different, which was consistent with regional population and economy. 3) Human activity was the most dramatic at altitudes between 0–500 m. For 500–1000 m, grassland mainly converted to forest and build-up land. Area of land cover transition was the greatest between 1000–1500 m, while above 1500 m, the transition of grassland was the most obvious. 4) The drivers of land cover change varied. Land cover change was positively correlated with gross domestic product and population density but was inversely related to relief amplitude. There were correlations between land cover change and distance to roads and rivers, and their correlations varied with altitude. By revealing patterns and causes of land cover changes in different altitudes, we hope to understand the vertical dependence of land cover changes, so as to improve land productivity and protect land ecological environment scientifically.
基金supported by the China Geological Survey (DD20160346)the National Natural Science Foundation of China (41472089)the Guizhou Geological Prospecting Fund (2016091)
文摘The black shale series that formed in the Edi- acaran-Cambrian transition are important stratigraphic records of the co-evolution of the paleo-ocean, -climate, and -biology. In this study, we measured Re-Os isotopic compositions of the black shale in the Niutitang Formation from the Gezhongwu section in Zhijin, Guizhou Province. The samples had high Re and Os contents, with Re ranging from 21.27 to 312.78 ng/g and Os ranging from 0.455 to 7.789 ng/g. The Re-Os isotope isochron age of 522.9 ± 8.6 Ma implies deposition of the Niutitang black shale predated the Chengjiang Fauna, providing an age constraint for the expansion of oceanic anoxia in the study area. The initial ^187Os/^188Os ratio of 0.826 ± 0.026 indi- cates that enhanced continental weathering might have triggered the expansion of the oceanic anoxia.
基金Supported by National Natural Science Foundation of China(31360144)the Key Laboratory of Biodiversity Preservation,Guiyang University
文摘Chinese giant salamander(CGS, Andrias davidianus) is experiencing the threat of extinction. It is disappearing gradually, because of overharvesting, environmental pollution, specially river pollution, activity of human exploitation, and so on. We conducted community interview fieldworks to collect respondent data from Xieba Country(not reserve) situated in Zhengan County of Guizhou Province, where one of the places known by historical giant salamander records in Guizhou. Through the analysis of the collected data, we created quantitative data of use for conservation management on the local status of salamander populations, and we compared our data with those available data of Y. Pan et al., who investigated the status of CGS in 3 reserves in Guizhou Province in 2015.The conclusions have a similar trend, which proved that the collected data were creditable. Through statistical analysis of the comparison data, the number of wild CGS decreased actually followed the increase of artificial framing.Because of the source of breeding to catch wild CGS, overharvesting was likely the most reason to make wild CGS decline.
基金Under the auspices of National Natural Science Foundation of China(No.40801039,40801066,41001183)
文摘Karst rocky desertification is one of the major ecological and environmental problems that threaten the sustainable development of southwestern China. It is caused by irrational and intensive land-use patterns in karst geo-ecological environment. Therefore, it is vital to identify how human forces work on this degraded environment. Based on the soil erosion information in 2000 and remote sensing images of Guanling County collected in 2000 and 2007, four grades of karst rocky desertification data in 14 villages of Guanling County were extracted. Impacts of population, affluence, and other human forces on karst rocky desertification were analyzed using STIRPAT model. The results show that:1) Factors of population and affluence had strong influence on karst rocky desertification. In the STIRPAT model analysis, the population and affluence coefficients were positive, indicating that the increase in population and affluence would lead to more serious desertification. 2) Factors of farmer correlated with karst rocky desertification negatively, especially the way of viewing the relationship between people and nature, and the level of knowledge about rocky desertification. Government behavior was not a significant factor in this analysis. 3) The findings provide evidence that STIRPAT model can be used to analyze the relationship between human driving forces and rocky desertification.
文摘HUNAN’S“king of mask changing” is the 70-year-old Zeng Jingui. He spent most of his working life in Chinese opera,and has brought this passion into his retirement. The 70-year-old operates an opera mask workshop from his two-room apartment. It is crammed with thousands of different-sized facemasks seen in traditional Chinese operas.
基金supported by outstanding science and technology education personnel special funds of Guizhou Province (Specific words in Guizhou Province (2012)No.27)National multipurpose regional geochemical survey Project (GZTR20070110)
文摘Based on the results of multipurpose regional geochemical surveys of the Guizhou Province, geochemical characteristics of soil Se and Se-rich land resources in the central area of Guiyang City were studied and evaluated.Major conclusions are as follows:(1) the Se content in surface soil of the central area of Guiyang City was 0.17–2.89 mg kg^(-1), and the average was 0.78 mg kg^(-1), which were respectively 2.6 and 3.9 times of the national background value of soil and the world background value of soil.The Se content in deep soil was 0.11–1.48 mg kg^(-1), and the average was 0.44 mg kg^(-1), which were respectively 1.5 and2.2 times of the national background value of soil and the world background value of soil. The soil Se content decreased with the increase in the soil depth on the vertical profile, and the surface soil had a higher Se content.(2)Distribution of Se content was mainly affected by parent material, physicochemical properties of soil and other components, soil type, and land use type. Parent material played a key role, as the soil Se content was mainly originated from parent rock and increased with the background value of Se in parent rock, physicochemical properties of soil and other components had certain influences upon the Se content. Se was shown to have a significant linear positive correlation with S and organic carbon but no significant correlation with p H value. Se content varied with different types of soil as follows: skeleton soil > yellow soil > paddy soil > limestone soil > purple soil. Land use type also hadcertain influences upon the soil Se content as follows: dry land > construction land > garden plot > grassland =garden plot > forest land.(3) Taking 0.4 mg kg^(-1)B x(Se) <3.0 mg kg^(-1) as the standard for Se-rich soil, Se-rich soil of the study area covered an area of 2224 km^2 and 92.5% of the total area; the remaining is general soil. The study area had no Se-excess soil. Therefore, the central area of Guiyang City has a high proportion of Se-rich land, a large area of Serich land resources, and a moderate selenium enrichment strength, which have been rarely seen anywhere and provide advantageous resources for the development of Se-rich featured agriculture.
基金Under the auspices of National Basic Research Program of China(No.2010CB951802,2005CB422207)Knowledge Innovation Program of Chinese Academy of Sciences(No.KZCX2-YW-219)National High Technology Research and Development Program of China(No.2009AA122104)
文摘The effects of acid deposition on pine forest ecosystems in Longli of Guizhou Province, southwestern China are studied using indoor experiments and model simulations. Indoor experiments are designed to explore the aluminum toxicity on pine seedlings, and the long-term soil acidification model (LTSAM) and a terrestrial biogeochemistry model (CENTURY) are used to simulate the influences of acid deposition on pine forest ecosystems. The indoor experiment results of aluminum toxicishow that aluminum ions in solution limit plant growth and acid deposition enhances this effect by facilitating the release of aluminum ions from the soil. Pine seedling bio- mass and root elongation decrease as the aluminum concentration increases. The results of model simulations show that the soil chemis- try varies significantly with different changes in acid deposition. When the acid deposition increases, the pH value in the soil solution decreases and the soil A13+ concentration increases. The increased acid deposition also has negative impacts on the forest ecosystem, i.e., decreases plant biomass, net primary productivity (NPP) and net C02 uptake. As a result, the soil organic carbon (SOC) decreases be- cause of the limited supply of decomposition material. Thus acid deposition need be reduced to help protect the forest ecosystems.
基金Supported by the National Natural Science Foundation of China(31360144)the Fund of the Key Laboratory of Biodiversity Preservation,Guiyang University
文摘13 water quality parameters were tested from 38 reaches of 34 counties in Guizhou where Chinese giant salamander(Andrias davidianus) distributed over the past 30 years. Dissolved oxygen and p H were found to be significant determinants of the species distribution in recent years(P<0.05). There was no Chinese giant salamander distribution in the recent five years in rivers with dissolved solids of greater than 415 mg/L, conductivity of greater than 639 us/cm, salinity of greater than 0.31 ppt and total hardness of greater than 150 mg/L. Sensitive to environment, the Chinese giant salamander is an important indicator for environmental quality, so it could be used as one of the environmental indicator. Eutrophication, chemical fertilizer, pesticides and inorganic pollutants may be one of reasons driving wild CGS into extinction.