工业固体废弃物资源综合利用技术现状

工业固废的综合利用已经成为建设资源节约型、环境友好型社会的重要措施。详细介绍了近几年来我国工业固废产生和处理的总体情况;概括与总结了粉煤灰、炉渣、尾矿、副产石膏、赤泥以及煤矸石等几种总产生量较大、品种较为集中的大宗工业固废的利用现状;同时以煤矸石为例详细介绍了其综合利用概况以及产业化情况,特别是利用其制备高性能混凝土、新型耐火材料、新型功能材料等高值产品将是未来的重要发展方向;最后,展望了我国大宗工业固废资源化利用技术的发展趋势。

The safety mining theory studying for coal resource in China

The coal resource has an important role in the energy development strategy in China. Because the coal resources are a kind of non-renewable resources, a Kind of ex-hausting resource, which is limited in quantity, and the exploitation of the recourses are not economized now, so how to realize the sustainable development for coal resource in China is very important. In this paper, two parts were researched to optimize the coal mining. In order to optimize the mining order of different mining areas, the fuzzy logic evaluation was used to build the evaluation system. The economic control theory model was built to realize the proper period to explore the coal recourses for the same mining areas.

SEMI-INDUSTRIAL UCG TRIAL AT XUZHOU XINGHE NO.2 MINE

This paper introduces the results of a semi-industrial UCG trial carried out at Xuzhou Xinghe No. 2 mine. A new underground gasifier, long tunnel. large section underground gasifier, is designed. It is an important way to make LCG cornmercialization because the new gasifier can steadily produce gas with higher heat value by changing the flow state of air and gas in the tunnel.

Open cut resource optimisation as applied to coal

Pit optimisation is the earliest and most established application of its kind in the minerals industry, but this has been primarily driven by metal, not coal. Coal has the same financial drivers for resource optimisation as does the metalliferous industry, yet pit optimisation is not common practice. Why？ The following discussion presents the basics of pit optimisation as they relate to coal and illustrates how a technology developed for massive deposits is not suitable for thin, multi-seam deposits where mine planning is often driven more by product quality than by value drivers such as Net Present Value. An alternative methodology is presented that takes advantage of the data structure of bedded deposits to optimise resource recovery in terms of a production schedule that meets constraints on coal quality.

Thermo-chemical conversion of coal samples under high temperature

Exhaustion of profitable coal resources makes for need of innovation including underground coal gasification(UCG).One of the most important problems of UCG is evaluation of the combustion area in underground coal seams.Physicochemical parameters of coal,in a whole,and coal mineral substance are changed under heating and combusting.Thermo-chemical conversion of coal mineral components has an effect on magnetic characteristics of coal seam and can be used for real-time control of combusting area.To this guessing check laboratory experiments have been made as an activity of the Far Eastern Federal University.Our investigation based on a theoretical analysis and laboratory simulation tests.Typical results of the laboratory experiments are presented below.Under heating coal thermo-chemical magnetization is forming.Coal's magnetic parameters varieties from anti-ferromagnetiсto ferromagnetic.Anti-ferromagnetic pyrite and siderite presented into coal mass is transformed into magnetic hematite and magnetite under heating.Therefore,geomagnetic is expected to be a useful geophysical tool to for evaluation of combustion volume and its migration for underground coal gasification.

Circulating Fluidized Bed Gasification of Low Rank Coal：Influence of O2/C Molar Ratio on Gasification Performance and Sulphur Transformation

To promote the utilization efficiency of coal resources,and to assist with the control of sulphur during gasification and/or downstream processes,it is essential to gain basic knowledge of sulphur transformation associated with gasification performance.In this research we investigated the influence of O_2/C molar ratio both on gasification performance and sulphur transformation of a low rank coal,and the sulphur transformation mechanism was also discussed.Experiments were performed in a circulating fluidized bed gasifier with O_2/C molar ratio ranging from 0.39 to 0.78 mol/mol.The results showed that increasing the O_2/C molar ratio from 0.39 to 0.78 mol/mol can increase carbon conversion from 57.65%to 91.92%,and increase sulphur release ratio from 29.66%to63.11%.The increase of O_2/C molar ratio favors the formation of H_2S,and also favors the retained sulphur transforming to more stable forms.Due to the reducing conditions of coal gasification,H_2S is the main form of the released sulphur,which could be formed by decomposition of pyrite and by secondary reactions.Bottom char shows lower sulphur content than fly ash,and mainly exist as sulphates.X-ray photoelectron spectroscopy(XPS)measurements also show that the intensity of pyrite declines and the intensity of sulphates increases for fly ash and bottom char,and the change is more obvious for bottom char.During CFB gasification process,bigger char particles circulate in the system and have longer residence time for further reaction,which favors the release of sulphur species and can enhance the retained sulphur transforming to more stable forms.