The sluggish reaction kinetics and poor structure stability of transition metal dichalcogenides(TMDs)-based anodes in potassium-ion batteries(KIBs)usually cause limited rate performance and rapid capacity decay,which ...The sluggish reaction kinetics and poor structure stability of transition metal dichalcogenides(TMDs)-based anodes in potassium-ion batteries(KIBs)usually cause limited rate performance and rapid capacity decay,which seriously impede their application.Herein,we report a vacancy engineering strategy for preparing a class of Te-doped 1T'-ReSe_(2)anchored onto MXene(Te-ReSe_(2)/MXene)as an advanced anode for KIBs with high performance.By taking advantage of the synergistic effects of the defective Te-ReSe_(2)arrays with expanded interlayers and the elastic MXene nanosheets with self-autoadjustable function,the Te-ReSe_(2)/MXene superstructure exhibits boosted K^(+)ion storage performance,in terms of high reversible capacity(361.1 mA h g^(−1)at 0.1 A g^(−1)over 200 cycles),excellent rate capability(179.3 mA h g^(−1)at 20 A g^(−1)),ultra-long cycle life(202.8 mA h g^(−1)at 5 A g^(−1)over 2000 cycles),and steady operation in flexible full battery,presenting one of the best performances among the TMDs-based anodes reported thus far.The kinetics analysis and theoretical calculations further indicate that satisfactory pseudocapacitive property,high electronic conductivity and outstanding K^(+)ion adsorption/diffusion capability corroborate the accelerated reaction kinetics.Especially,structural characterizations clearly elaborate that the Te-ReSe_(2)/MXene undergoes reversible evolutions of an initial insertion process followed by a conversion reaction.展开更多
基金the National Natural Science Foundation of China(22005223 and 21975187)Guangdong Basic and Applied Basic Research Foundation(2019A1515012161)+7 种基金the Special Innovational Project of Department of Education of Guangdong Province(2019KTSCX186 and 2017KCXTD031)the Science Foundation for Young Teachers of Wuyi University(2019td01)the Science Foundation for High-Level Talents of Wuyi University(2018RC50 and 2017RC23)Wuyi University-Hong Kong-Macao Joint Research Project(2019WGALH10)the Innovative Leading Talents of Jiangmen(Jiangren(2019)7)the Science and Technology Projects of Jiangmen((2017)307,(2017)149,(2018)352)the Research Fund of the State Key Laboratory of Solidification Processing(NPU),China(SKLSP202004)Guangdong Key Building Discipline Research Capability Enhancement Funds(2021ZDJS093).
文摘The sluggish reaction kinetics and poor structure stability of transition metal dichalcogenides(TMDs)-based anodes in potassium-ion batteries(KIBs)usually cause limited rate performance and rapid capacity decay,which seriously impede their application.Herein,we report a vacancy engineering strategy for preparing a class of Te-doped 1T'-ReSe_(2)anchored onto MXene(Te-ReSe_(2)/MXene)as an advanced anode for KIBs with high performance.By taking advantage of the synergistic effects of the defective Te-ReSe_(2)arrays with expanded interlayers and the elastic MXene nanosheets with self-autoadjustable function,the Te-ReSe_(2)/MXene superstructure exhibits boosted K^(+)ion storage performance,in terms of high reversible capacity(361.1 mA h g^(−1)at 0.1 A g^(−1)over 200 cycles),excellent rate capability(179.3 mA h g^(−1)at 20 A g^(−1)),ultra-long cycle life(202.8 mA h g^(−1)at 5 A g^(−1)over 2000 cycles),and steady operation in flexible full battery,presenting one of the best performances among the TMDs-based anodes reported thus far.The kinetics analysis and theoretical calculations further indicate that satisfactory pseudocapacitive property,high electronic conductivity and outstanding K^(+)ion adsorption/diffusion capability corroborate the accelerated reaction kinetics.Especially,structural characterizations clearly elaborate that the Te-ReSe_(2)/MXene undergoes reversible evolutions of an initial insertion process followed by a conversion reaction.
