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UPy修饰纳米纤维素基复合纤维膜的构筑
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作者 王汉琛 吴嘉茵 +1 位作者 黄彪 卢麒麟 《纺织科技进展》 CAS 2022年第8期25-32,共8页
为解决纳米纤维素(CNC)用于复合材料的增强过程中易于形成自团聚现象,提高其在基质中的分散性,利用端基含有—NCO基团的脲基嘧啶酮类化合物UPy-NCO对CNC进行表面化学修饰,在CNC表面成功接枝—UPy基团。将其作为分子桥与PVA有机结合,通... 为解决纳米纤维素(CNC)用于复合材料的增强过程中易于形成自团聚现象,提高其在基质中的分散性,利用端基含有—NCO基团的脲基嘧啶酮类化合物UPy-NCO对CNC进行表面化学修饰,在CNC表面成功接枝—UPy基团。将其作为分子桥与PVA有机结合,通过多重氢键作用构筑了具有良好机械性能的超分子复合膜。对超分子复合膜的微观形貌、特征结构、热稳定性和力学性能等性质进行分析表征。测试结果表明CNC-UPy在水介质中定向排列并能均匀分散在PVA介质中,利用UPy-CNO对纳米纤维素进行修饰并未改变纳米纤维素的晶体结构,仍为纤维素Ⅰ型;力学性能测试的结果显示当CNC-UPy的含量增加到5%时,超分子复合膜的拉伸强度由34.97MPa增加到65.35MPa,增加了86.87%;热性能分析结果表明随着CNC-UPy含量的增加,超分子复合膜的初始热分解温度由231℃提高到242℃,同时最大失重速率温度由288℃提升到332℃。 展开更多
关键词 超分子复合膜 纳米纤维素 UPy 分子 多重氢键
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Preparation and Fluorescence Properties of Co-doped Nanocomposite Film Based on Supra Molecular Structure 被引量:3
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作者 李贵安 李貅 +4 位作者 宋建平 李发荣 马少华 张玉荣 方晓玲 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第2期183-186,共4页
A novel materials design procedure based on the co-doping of metal nanoparticle and azo dye compound (MNPADC) is developed to improve the properties of functional molecules. The synthesized materials were characteri... A novel materials design procedure based on the co-doping of metal nanoparticle and azo dye compound (MNPADC) is developed to improve the properties of functional molecules. The synthesized materials were characterized by transmission electron micrograph (TEM), ultraviolet-visible absorption spectra (UV-Vis) and fluorescence spectra (FS). It was found that the fluorescence intensity of methyl orange (MO) was enhanced by 5 times in the aqueous composite system doped with silver nanoparticles whereas it was reduced by 15% and 20% in composite films with co-mixing and coating structures, respectively. The results indicate that the properties of functional molecules can be greatly improved in composite film with supra molecular structure and that the procedure presented here is effective. 展开更多
关键词 Supra molecular structure Nanocomposite film Silver nanoparticles Methyl orange Fluorescence properties
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