Study on the effects of sonolysis, ozonolysis and US/O3 system on the decomposition of p-chlorophenol in aqueous solutions indicated that in the cases of US/O3 system, individual ozonolysis and sonolysis, the decompos...Study on the effects of sonolysis, ozonolysis and US/O3 system on the decomposition of p-chlorophenol in aqueous solutions indicated that in the cases of US/O3 system, individual ozonolysis and sonolysis, the decomposition rate of p-chlorophenol reached 78.78%, 56.20%, 2.79% after a 16-min reaction while its CODcr (chemical oxygen demand) removal rate was 97.02%, 62.17%, 3.67% after a 120-min reaction. The decomposition reaction of p-chlorophenol follows pseudo-first-order kinetics. The enhancement factors of p-chlorophenol and its CODcr under US/O3 system reached 63% and 237% respectively. The main intermediates during the decomposition include catechol, hydroquinone, p-benzoquinone, phenol, fumaric acid, maleic acid, oxalic acid and formic acid. The decomposition mechanism of p-chlorophenol was also discussed.展开更多
The ultrasonic echo in liquid density measurement often suffers noise,which makes it difficult to obtain the useful echo waveform,resulting in low accuracy of density measurement.A denoising method based on improved v...The ultrasonic echo in liquid density measurement often suffers noise,which makes it difficult to obtain the useful echo waveform,resulting in low accuracy of density measurement.A denoising method based on improved variational mode decomposition(VMD)for noise echo signals is proposed.The number of decomposition layers of the traditional VMD is hard to determine,therefore,the center frequency similarity factor is firstly constructed and used as the judgment criterion to select the number of VMD decomposition layers adaptively;Secondly,VMD algorithm is used to decompose the echo signal into several modal components with a single modal component,and the useful echo components are extracted based on the features of the ultrasonic emission signal;Finally,the liquid density is calculated by extracting the amplitude and time of the echo from the modal components.The simulation results show that using the improved VMD to decompose the echo signal not only can improve the signal-to-noise ratio of the echo signal to 20.64 dB,but also can accurately obtain the echo information such as time and amplitude.Compared with the ensemble empirical mode decomposition(EEMD),this method effectively suppresses the modal aliasing,keeps the details of the signal to the maximum extent while suppressing noise,and improves the accuracy of the liquid density measurement.The density measurement accuracy can reach 0.21%of full scale.展开更多
文摘Study on the effects of sonolysis, ozonolysis and US/O3 system on the decomposition of p-chlorophenol in aqueous solutions indicated that in the cases of US/O3 system, individual ozonolysis and sonolysis, the decomposition rate of p-chlorophenol reached 78.78%, 56.20%, 2.79% after a 16-min reaction while its CODcr (chemical oxygen demand) removal rate was 97.02%, 62.17%, 3.67% after a 120-min reaction. The decomposition reaction of p-chlorophenol follows pseudo-first-order kinetics. The enhancement factors of p-chlorophenol and its CODcr under US/O3 system reached 63% and 237% respectively. The main intermediates during the decomposition include catechol, hydroquinone, p-benzoquinone, phenol, fumaric acid, maleic acid, oxalic acid and formic acid. The decomposition mechanism of p-chlorophenol was also discussed.
文摘The ultrasonic echo in liquid density measurement often suffers noise,which makes it difficult to obtain the useful echo waveform,resulting in low accuracy of density measurement.A denoising method based on improved variational mode decomposition(VMD)for noise echo signals is proposed.The number of decomposition layers of the traditional VMD is hard to determine,therefore,the center frequency similarity factor is firstly constructed and used as the judgment criterion to select the number of VMD decomposition layers adaptively;Secondly,VMD algorithm is used to decompose the echo signal into several modal components with a single modal component,and the useful echo components are extracted based on the features of the ultrasonic emission signal;Finally,the liquid density is calculated by extracting the amplitude and time of the echo from the modal components.The simulation results show that using the improved VMD to decompose the echo signal not only can improve the signal-to-noise ratio of the echo signal to 20.64 dB,but also can accurately obtain the echo information such as time and amplitude.Compared with the ensemble empirical mode decomposition(EEMD),this method effectively suppresses the modal aliasing,keeps the details of the signal to the maximum extent while suppressing noise,and improves the accuracy of the liquid density measurement.The density measurement accuracy can reach 0.21%of full scale.
