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索氏提取-气相色谱质谱法测定纸质包装材料中五种多溴联苯 被引量:2
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作者 陈琼 兰丽丽 +1 位作者 张海娟 蒋小良 《中华纸业》 CAS 2018年第8期12-15,共4页
建立了测试纸质包装材料中5种多溴联苯含量的气相色谱-质谱法(GC-MS)。以甲苯为提取剂,采用索氏提取方式提取纸质包装材料中多溴联苯,考察了提取溶剂和提取时间对提取效果的影响。提取液经浓缩、净化后用气相色谱-质谱法测定,外标法定... 建立了测试纸质包装材料中5种多溴联苯含量的气相色谱-质谱法(GC-MS)。以甲苯为提取剂,采用索氏提取方式提取纸质包装材料中多溴联苯,考察了提取溶剂和提取时间对提取效果的影响。提取液经浓缩、净化后用气相色谱-质谱法测定,外标法定量分析。结果表明,在0.2~10mg/l浓度范围内,5种多溴联苯均具有较好线性关系,其相关系数(r^2)均大于0.992,5种多溴联苯的检出限在0.35~0.50mg/l之间。样品平均加标回收率在86.4%~94.2%之间,相对标准偏差小于7.4%。 展开更多
关键词 纸质包装材料 多溴联苯 超索氏提取 气相色谱-质谱法
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Extraction of the Residual Polycyclic Aromatic Hydrocarbons in the Long-term Contaminated Soil in the Field 被引量:1
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作者 张铁军 李晓军 +2 位作者 杨辉 王善仙 图影 《Agricultural Science & Technology》 CAS 2010年第9期153-156,共4页
[Objective] The aim of this study was to find a better method to exactly quantify the residual polycyclic aromatic hydrocarbons(PAHs)in the long-term contaminated soil in the field so as to provide basis for the rem... [Objective] The aim of this study was to find a better method to exactly quantify the residual polycyclic aromatic hydrocarbons(PAHs)in the long-term contaminated soil in the field so as to provide basis for the remediation for PAHs contaminated soil.[Method]The comparisons of soxhlet extraction,ultrasonic extraction and shaking extraction were studied in the agricultural soil irrigated with oil sewage over a long period of time.[Result]The total PAHs extracted by soxhlet extraction were the highest(6 873.7 μg/kg),followed by shaking extraction(6 698.8 μg/kg)and ultrasonic extraction(5 737.6 μg/kg).Among these methods,the highest extracted 4 and 6 rings PAHs were in the soxhlet extraction,the highest extracted 2 and 5 rings PAHs were in the shaking extraction,and the highest extracted 3 rings PAHs were in the ultrasonic extraction.[Conclusion]This study had provided basis for the selection of the assessment method of residual PAHs in the field soil. 展开更多
关键词 Polycyclic aromatic hydrocarbons Soil Soxhlet extraction Ultrasonic extraction Shaking extraction
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