This paper investigates the effect of carried-envelope phase on transient process in a cascade-type atomic system, which is driven by two ultrashort laser pulses （probe and signal laser）. It is found that the one- a...This paper investigates the effect of carried-envelope phase on transient process in a cascade-type atomic system, which is driven by two ultrashort laser pulses （probe and signal laser）. It is found that the one- and two-photon processes corresponding to pathway ｜0〉→｜1〉and ｜0〉→｜1〉→｜2〉 can be enhanced or ,suppressed by modulating the carried-envelope phases of probe laser pulse. Our numerical results also show that the transient populations of two excited states can be periodically affected by the carried-envelope phase of probe laser pulse. With certain time, the partial population transfer between two exited states can be realized just by adjusting the carried-envelope phase of probe laser pulse.展开更多
The nonradiative decay of a n-stacked pair of adenine molecules, one of which was excited by an ultrafast laser pulse, is studied by semiclassical dynamics simulations. This simulation investigation is focused on the ...The nonradiative decay of a n-stacked pair of adenine molecules, one of which was excited by an ultrafast laser pulse, is studied by semiclassical dynamics simulations. This simulation investigation is focused on the effect of the formation of bonded excimer in stacked adenines on the mechanism of ultrafast decay. The simulation finds that the formation of the bond- ed excimer significantly lowers the energy gap between the LUMO and HOMO and consequently facilitates the deactivation of the electronically excited molecule. On the other hand, the formation of the chemical bond between two stacked adenines re- stricts the deformation vibration of the pyrimidine of the excited molecule due to the steric effect. This slows down the formation of the coupling between the HOMO and LUMO energy levels and therefore delays the deactivation process of the excited adenine molecule to the electronic ground state.展开更多
文摘This paper investigates the effect of carried-envelope phase on transient process in a cascade-type atomic system, which is driven by two ultrashort laser pulses （probe and signal laser）. It is found that the one- and two-photon processes corresponding to pathway ｜0〉→｜1〉and ｜0〉→｜1〉→｜2〉 can be enhanced or ,suppressed by modulating the carried-envelope phases of probe laser pulse. Our numerical results also show that the transient populations of two excited states can be periodically affected by the carried-envelope phase of probe laser pulse. With certain time, the partial population transfer between two exited states can be realized just by adjusting the carried-envelope phase of probe laser pulse.
基金supported by the National Natural Science Foundation of China (21073242)the Natural Science Foundation of Chongqing (cstc2011jjA00009)+1 种基金the Project of Science Technology Foundation of Chongqing Education Committee (KJ100507)the Research Fund of Chongqing University of Posts and Telecommunications (A2009-63,A2010-17)
文摘The nonradiative decay of a n-stacked pair of adenine molecules, one of which was excited by an ultrafast laser pulse, is studied by semiclassical dynamics simulations. This simulation investigation is focused on the effect of the formation of bonded excimer in stacked adenines on the mechanism of ultrafast decay. The simulation finds that the formation of the bond- ed excimer significantly lowers the energy gap between the LUMO and HOMO and consequently facilitates the deactivation of the electronically excited molecule. On the other hand, the formation of the chemical bond between two stacked adenines re- stricts the deformation vibration of the pyrimidine of the excited molecule due to the steric effect. This slows down the formation of the coupling between the HOMO and LUMO energy levels and therefore delays the deactivation process of the excited adenine molecule to the electronic ground state.
