合成了表面包覆 Si O2 的超细 Ca CO3 。通过 XPS,XRD对包覆表面层结构的分析 ,证实了 Si O2 以无定形包覆于 Ca CO3 表面 ,并在其表面形成了 Si- O- Ca键。对 Si O2 包覆超细 Ca CO3 的机理分析结果可知 :Na2 Si O3 的加入量是影响包...合成了表面包覆 Si O2 的超细 Ca CO3 。通过 XPS,XRD对包覆表面层结构的分析 ,证实了 Si O2 以无定形包覆于 Ca CO3 表面 ,并在其表面形成了 Si- O- Ca键。对 Si O2 包覆超细 Ca CO3 的机理分析结果可知 :Na2 Si O3 的加入量是影响包覆效率的重要因素 ,由于硅酸易自聚 ,控制 Si O2 与 Ca CO3 的重量比约为4 %～ 5 %时为包覆的最佳点 ;Ca CO3 晶粒度大小影响分散性能 ,进而影响包覆效率 ,分散性能好的包覆效率较高。展开更多
Ultrafine particles of CaCO3 were synthesized with micropore dispersion in gas-liquid （slurry） systems.Experiments was conducted on carbonation of Ca（OH）2/H2O system.Micropore plate was used for the dispersion of ...Ultrafine particles of CaCO3 were synthesized with micropore dispersion in gas-liquid （slurry） systems.Experiments was conducted on carbonation of Ca（OH）2/H2O system.Micropore plate was used for the dispersion of mixed gas containing CO2.Therefore,the processes of momentum transfer, mass transfer and reaction were enhanced.The results showed that ultrafine particles with diameter about 40nm and specific surface area more than 30 m2·g -1 were prepared successfully.The crystal structure of particles was characterized with BET, FTIR and TEM.展开更多
文摘合成了表面包覆 Si O2 的超细 Ca CO3 。通过 XPS,XRD对包覆表面层结构的分析 ,证实了 Si O2 以无定形包覆于 Ca CO3 表面 ,并在其表面形成了 Si- O- Ca键。对 Si O2 包覆超细 Ca CO3 的机理分析结果可知 :Na2 Si O3 的加入量是影响包覆效率的重要因素 ,由于硅酸易自聚 ,控制 Si O2 与 Ca CO3 的重量比约为4 %～ 5 %时为包覆的最佳点 ;Ca CO3 晶粒度大小影响分散性能 ,进而影响包覆效率 ,分散性能好的包覆效率较高。
文摘Ultrafine particles of CaCO3 were synthesized with micropore dispersion in gas-liquid （slurry） systems.Experiments was conducted on carbonation of Ca（OH）2/H2O system.Micropore plate was used for the dispersion of mixed gas containing CO2.Therefore,the processes of momentum transfer, mass transfer and reaction were enhanced.The results showed that ultrafine particles with diameter about 40nm and specific surface area more than 30 m2·g -1 were prepared successfully.The crystal structure of particles was characterized with BET, FTIR and TEM.
