Al_3Ni_2的一个超结构相

Ａｌ３Ｎｉ２的一个超结构相郝朝斌王蓉（北京科技大学材料物理系，１０００８３）Ａｌ３Ｎｉ２（τ３）相是一种空位有序相，实验上已观察到由十次准晶向Ａｌ３Ｎｉ２的五重畴结构的转变［１］，然而，Ａｌ３Ｎｉ２结构并不满足准晶近似相的大单胞特征［２］。已有工作［...

用透射和扫描电镜观察Ni-Cr-Al合金γ'和Cr(α)析出相

Ni-Cr-3％Al-0.2％Ce合金0.3mm细丝经500～600℃时效处理,用透射和扫描电镜观察组织形貌,用化学定量提取法和测定微区成分的方法确定相Ni、Cr、Al的含量,用程控图像仪测定富Cr(α)相析出颗粒大小和分布,查明γ’相沿基体{100}面共格析出并呈细小颗粒状,在γ’相周围析出的过饱和富Cr(α)相弥散分布在合金基体中。据此认为该合金是由γ’相和富Cr(α)相复合析出强化合金基体的。

Vegetative Storage Proteins in Meliaceae

采用光学和电子显微镜技术及SDS_PAGE研究了营养贮藏蛋白质 (VSPs)在楝科树木中的分布和超微结构 ;并采用免疫印迹技术 ,以大叶桃花心木 (SwieteniamacrophyllaKing)的 2 1kDVSP的抗血清检测楝科树木VSPs的免疫相关性。结果表明 ,在桃花心木亚科 (Swietenioideae)的树木中普遍存在VSPs ,但楝亚科 (Melioidae)仅部分属的树木有VSPs而椿亚科 (Cedreloideae)树木没有VSPs。VSPs在同一属树木中的分布是一致的。桃花心木亚科和楝亚科树木之间的VSPs几乎没有免疫相关性 ,但是在桃花心木亚科中 ,VSPs具有相对高的同源性。楝科树木VSPs的超微结构存在一定程度的差异 ,这可能与VSPs的种类不同有关。VSPs的分布。

Performance of Inner-core Supersonic Gas Separation Device with Droplet Enlargement Method

To improve the separation performance of a supersonic gas separation device for the treatment of gas mixture with a single heavy component, a novel structure with shorter settlement distance was constructed and a method of droplet enlargement was applied. A series of experiments were carried out in the improved separation device under various conditions, using air-ethanol vapor as the medium and micro water droplets as nucleation cen- ters. The effects of the inlet pressure, temperature and relative humidity, the swirling intensity, and mass flow rate of water on the separation performance were investigated. The separation was improved by increasing the inlet pressure and relative humidity. With the decrease of swirling intensity and mass flow rate of water, the separation efficiency increased first and then decreased. The inlet temperature had a slight effect on the separation. The results showed that the separation performance was effectively improved using the proposed structure and method, and the best separation in this study was obtained with the ethanol removal rate about 55% and dew point depression 27 K. The addition of water had little pollution to the air-ethanol vapor system since the water carry-over rate was within the range of -2 %-0 in most cases.

Analysis of phospholipids in microalga Nitzschia closterium by UPLC-Q-TOF-MS

Precise structural identification of phospholipids in the microalga Nitzschia closterium has been established using ultra performance liquid chromatography-electrospray ionization-quadrupole-time of flight-mass spectrometry (UPLC-ESI-Q-TOF-MS) for direct analysis of total lipid extracts.Mass spectrometry was performed in reflective time-of-flight using electron spraying ionization in negative mode.Phospholipid molecular species identification was based on the characteristic product ions and neutral loss yielded by different phospholipids under ESI-MS/MS mode.The molecular species were confirmed by the carboxylate anions produced by phospholipids in negative mode;the regiospecificity of the two acyl chains was determined from the ratio of sn-1 to sn-2 carboxylate anion abundances.As a result,18 lipid molecular species were identified for the first time in this microalga,comprising seven phosphatidylcholines (PC),two phosphatidylethanolamines (PE),two phosphatidylinositols (PI),and seven phosphatidylglycerols (PG).Lipid standards of PC,PE,PI,and PG were added to the total lipids as internal standards for semiquantitative analysis,revealing concentrations of phospholipids in this species between 0.09 and 3.37 nmol/mg.This method can produce a full structural profile of intact phospholipid molecular species and can be used for study of the physiological and ecological functions of lipids by monitoring their individual changes over time.

The Supramolecular Arrangement of Methane Halides in Liquid Phase

The IR spectroscopic data indicate the tautomeric transformations of typical aprotonic organic fluids such as methane halides with gross formulas CHX3 （X = Cl, Br）, CH2X2 （X = CI, Br, I） and CCl4 at normal conditions. These transformations lead to the appearance in molecules of activated hydrogen atoms similar in the spectral behaviour to the bounded proton. The classical analysis of IR bands in 5000-600 cm^-1 region, for studied samples and their deuterated derivatives, proves the existence in the presented organic fluids of hydrogen and dihydrogen bonds. This bonding promotes the formation of supramolecular structure in methane halides. The mechanism of unusual binding in liquid phase in terms of common knowledge for the basic chemical properties of the examined compounds is discussed.

Hydroelastic Analysis of a Very Large Floating Structure Edged with a Pair of Submerged Horizontal Plates

This paper is concerned with the hydroelastic problem of a very large pontoon-type floating structure(VLFS) edged with a pair of submerged horizontal plates, which is a combination of perforated and non-perforated plates attached to the for-end and back-end of the VLFS. For the hydroelastic analysis, the fluid is assumed to be ideal and its motion is irrotational so that a velocity potential exists. The VLFS is modeled as an elastic plate according to the classical thin plate theory. The fluid-structure interaction problem is separated into conventional hydrodynamics and structure dynamics by using modal expansion method in the frequency-domain. It involves, firstly, the deflection of the VLFS, which is expressed by a superposition of modal functions and corresponding modal amplitudes. Then the boundary element method is used to solve the integral equations of diffraction and radiation on the body surface for the velocity potential, whereas the vibration equation is solved by the Galerkin's method for modal amplitudes, and then the deflection is obtained by the sum of multiplying modal functions with modal amplitudes. This study examines the effects of the width and location of the non-perforated horizontal plates on the hydroelastic response of the VLFS, then the performance of perforated plates is investigated to reduce the motion near the fore-end of the VLFS. Considering the advantages and disadvantages of submerged plates without and with cylindrical holes, we propose a simple anti-motion device, which is a combination of a pair of perforated and non-perforated plates attached to the for-end and back-end of the VLFS. The effectiveness of this device in reducing the deformation and bending moment of the VLFS has been confirmed, and is compared with the results in cases without and with the submerged horizontal plates by the analysis in this paper.

Crystal structure and superconductivity at about 30 K in ACa_2Fe_4As_4F_2(A = Rb,Cs)

We have synthesized two iron fluo-arsenides ACa2Fe4As4Fz with A = Rb and Cs, analogous to the newly discovered superconductor KCazFe4As4F2. The quinary inor- ganic compounds crystallize in a body-centered tetragonal lattice with space group I4/mmm, which contain double Fe2As2 layers that are separated by insulating Ca2F2 layers. The electrical and magnetic measurements on the polycrys- talline samples demonstrate that the new materials undergo superconducting transitions at Tc = 30.5 and 28.2 K, respec- tively, without extrinsic doping. The correlations between Tc and structural parameters are discussed.

A robust self-healing polyurethane elastomer: From H-bonds and stacking interactions to well-defined microphase morphology

Self-healing materials have attracted considerable attention because of their improved safety, lifetime, energy efficiency and environmental impact. Supramolecular interactions have been extensively considered in the field of self-healing materials due to their excellent reversibility and sensitive responsiveness to environmental stimuli. However,development of a polymeric material with good mechanical performance as well as self-healing capacity is very challenging. In this study, we report a robust self-healing polyurethane(PU) elastomer polypropylene glycol-2-amino-5-(2-hydroxyethyl)-6-methylpyrimidin-4-ol(PPG-mUPy) by integrating ureidopyrimidone(UPy) motifs with a PPG segment with a well-defined architecture and microphase morphology.To balance the self-healing capacity and mechanical performance, a thermal-triggered switch of H-bonding is introduced. The quadruple H-bonded UPy dimeric moieties in the backbone induce phase separation to form a hard domain as well as enable further aggregation into microcrystals by virtue of the stacking interactions, which are stable in ambient temperature. This feature endows the PU with high mechanical strength. Meanwhile, a high healing efficiency can be realized, when the reversibility of the H-bond was unlocked from the stacking at higher temperature. An optimized sample PPG1000-mUPy50%with a good balance of mechanical performance(20.62 MPa of tensile strength) and healing efficiency(93% in tensile strength) was achieved. This strategy will provide a new idea for developing robust self-healing polymers.

Experimental investigation on transverse jet penetration into a supersonic turbulent crossflow

The paper evaluates the evolvement of coherent structures and penetration height of gaseous transverse jet penetration into a supersonic turbulent flow.The high spatiotemporal resolution coherent structures of the jet plume are obtained by utilizing the nanoparticle-based planar laser scattering technique(NPLS).The evolving pattern of the coherent structures generated on the upwind surface of the transverse jet is analyzed based on the NPLS images.The shedding eddies from the jet near-field have lower convection velocity along freestream direction,while vortex growth rate is apparently higher than the far-field.Farther downstream,the large-scale eddies have less deformation and translate at velocities near the freestream velocity.Thus the near-field determines the scale of eddies in the far-field and affects the whole mixing process.The effect of injection stagnation pressure on the coherent structures is discussed and a modified penetration correlation is proposed based on an edge approximation definition and least square method with various injection pressures.

Identifying the genes of unconventional high temperature superconductors

We elucidate a recently emergent framework in unifying the two families of high temperature （high To） superconductors, cuprates and iron-based superconductors. The unification suggests that the latter is simply the counterpart of the former to realize robust extended s-wave pairing symmetries in a square lattice. The unification identifies that the key ingredients （gene） of high Tc superconductors is a quasi two dimensional electronic environment in which the d-orbitals of cations that partic- ipate in strong in-plane couplings to the p-orbitals of anions are isolated near Fermi energy. With this gene, the superexchange magnetic interactions mediated by anions could maximize their contributions to superconductivity. Creating the gene requires special arrangements between local electronic structures and crystal lattice structures. The speciality explains why high Tc superconductors are so rare. An explicit prediction is made to realize high Tc superconductivity in Co/Ni-based materials with a quasi two dimensional hexagonal lattice structure formed by trigonal bipyramidal complexes.

Superconductivity in two-dimensionalη-Mo3C2 films

Two-dimensional(2D)superconductors have intriguing physical properties and abundant potential applications.Recently,2D superconductingα-Mo2C and facecentered cubic Mo2C have been controllably prepared and they bring new viewpoints to carbon-based superconductivity.Although molybdenum carbides(Mo-Cs)have multiple crystalline stacking orders,there are still few structures reported for the lack of higher energy supply during growth.In this study,we report a two-step vapor deposition method to grow superconducting η-Mo3C2 films with different thicknesses,with the assistance of controllable plasma power.The grownη-Mo3C2 films show polycrystalline characteristics,but they still present superior superconductivity.The 3.0-nm-thick film has the superconducting transition temperature of 5.38 K,and its electrical performances follow truly 2D superconducting transitions.This study will not only exhibit a robust superconductingη-Mo3C2 ultrathin film,but also provides a convenient growth way to realize more carbide-based heterostructures for future device applications.