The major elements, trace elements and REEs were analyzed on the samples collected from the sandstone-type uranium deposits in the Ordos Basin to constrain the mechanism of uranium enrichment. The total REE amount ran...The major elements, trace elements and REEs were analyzed on the samples collected from the sandstone-type uranium deposits in the Ordos Basin to constrain the mechanism of uranium enrichment. The total REE amount ranges from 36.7 to 701.8 μg/g and the REE distribution patterns of the sandstone-type uranium samples are characterized by LREE enrichment and high REE depletion. The results also indicated a high Y abundance and Eu anomalies between 0.77-1.81. High-precision ICP-MS results showed that U abundances are within the range of 0.73-150 μg/g, showing some strong correlation between U enrichment and related elements such as Ti, V, Zr, Mo, and Au. In addition, Th abundance is correlated with ΣREE.展开更多
The Laochang polymetallic ore deposit at Lancang is one of the well known ancient ore deposits associated with volcanic rocks in the Sanjiang (Tri-river) region of Southwest China. Volcanic rocks are dominated by alka...The Laochang polymetallic ore deposit at Lancang is one of the well known ancient ore deposits associated with volcanic rocks in the Sanjiang (Tri-river) region of Southwest China. Volcanic rocks are dominated by alkali basalt and trachyte basalt. There has long been a controversy on the environment of formation of basalts. Some scholars hold that the basalts were formed in a continental environment, some thought they were formed in an oceanic environment and others considered that the basalts were emplaced in a back-arc basin. This study focuses on the geochemical characteristics of the basalts on the basis of their major elements, REEs and trace elements. At the same time, strongly incompatible elements such as Ta, Th and Hf and their ratios were used to differentiate the geotectonic settings of basalts. The results showed that the basalts in the region studied were formed in a continental rift environment.展开更多
Basaltic samples from different locations in Aershan area determined by instrumental neutron activation analysis (INAA) have the same distribution patterns of REE and trace elements. The similar REE contents of the sa...Basaltic samples from different locations in Aershan area determined by instrumental neutron activation analysis (INAA) have the same distribution patterns of REE and trace elements. The similar REE contents of the same minerals without inclusions from different xenolith suggest that the mantle source region under different active volcanoes have the same composition. The REE content differences between the same minerals with and without melt inclusions selected from the same mantle xenolith indicate that the melt inclusions are rich in REE. The same patterns of trace elements of inclusions and host minerals from different xenolith analyzed by SRXRF suggest that the mantle fluid has no notable heterogeneity in Aershan area.展开更多
We report an imaging method of zircon U-Pb dating with NanoSIMS 50 L, which overcomes the significant U-Pb fractionation as the pit was sputtered deeper during conventional spot mode analysis and can be applied to irr...We report an imaging method of zircon U-Pb dating with NanoSIMS 50 L, which overcomes the significant U-Pb fractionation as the pit was sputtered deeper during conventional spot mode analysis and can be applied to irregular small grains or heterogeneous areas of zircon. The U-Pb and Pb-Pb ages can be acquired simultaneously for 2 μm×2 μm(for small grains) or 1 μm×9 μm(for zoned grains), together with Zr, Y and other trace elements distributions. Using zircon M257 as standard, the U-Pb ages of other zircon standards, including Qinghu, Plesovice, Temora and 91500, were measured to(2σ) as158.8±0.8, 335.9±3.4, 412.0±12 and 1067±12 Ma, respectively, consistent with the recommended values within the analytical uncertainties. Tiny zircon grains in the impact melt breccia of the lunar meteorite SaU 169 were also measured in this study,with a Pb-Pb age of 3912±14 Ma and a U-Pb age of 3917±17 Ma, similar to previous results reported for the same meteorite.The imaging method was also applied to determine U-Pb age of the thin overgrowth rims of Longtan metamorphic zircon, with a Pb-Pb age of 1933±27 Ma and a U-Pb age of 1935±25 Ma, clearly distinct from the Pb-Pb age of 2098±61 Ma and the U-Pb age of 2054±40 Ma for detrital cores.展开更多
Twenty-two peat samples collected at different depths of a core including the layer affected by the 1908 explosion in Tunguska area of Central Siberia, Russia, and three basalt sampies collected near the site, are ana...Twenty-two peat samples collected at different depths of a core including the layer affected by the 1908 explosion in Tunguska area of Central Siberia, Russia, and three basalt sampies collected near the site, are analyzed by ICP-MS. The concentrations of Pd, Ni, Co, ∑ REE,Ti and Sr in the event layers are 4-35 times higher than the background values in the normal layers. The variation of Pd is closely related to Ni, Co and ∑ REE in the event layers, but not to these elements in the normal layers. It indicates that these excess elements came from the same source,i.e. the Tunguska explosion body. In addition, the patterns of Cl-chondrite-normalized REE in the event layers ((La/Yb)N≈2-3) are much flatter than those in the normal layers ((La/Yb)N≈7-143),and differ from those in the three basalt samples. The concentrations of REE in the three basalt samples are tens times higher than those in the event layers. It may be inferred that these excess elements could not be produced by the contamination of the terrestrial material, but probably by the Tunguska explosion body, Additionally, the ratios of Ti/Ni and Sr/Co in the event layers are close to those in comet. It implies that the solid part of the explosion body was compositionally similar to carbonaceous chondrites (CI) and more probably a small comet. In terms of the Pd excess fluxes in the explosion area, it can be estimated that the celestial body that exploded over Tunguska in 1908 weighed more than 107 tons, corresponding to a radius of >126 m.展开更多
Wind erosion is one of the major factors of land degradation in the typical steppe region, northern Mongolian Plateau. Using 137Cs tracing technique, we estimated the wind erosion rates of different pastures and aband...Wind erosion is one of the major factors of land degradation in the typical steppe region, northern Mongolian Plateau. Using 137Cs tracing technique, we estimated the wind erosion rates of different pastures and abandoned farmland at Bayannur and Karakorum in Mongolia. The pastures and cutting grassland at Bayannur were slightly eroded by wind, with the rates of 64.58-169.07 t·km?2·a?1. The abandoned farmland in Karakorum, however, was strongly eroded by wind, with annual surface soil loss of 4.05 mm·a?1, and wind erosion rates up to 6723.06 t·km?2·a?1. The total loss of surface soil due to wind erosion has been 17.4 cm since the cultivation of the steppe land in the 1960s. The wind ero- sion rate at the abandoned farmland was much higher than that at the typical steppe sites, showing that the cultivation led to serious wind erosion in the typical steppe region, northern Mongolian Plateau. By contrast, traditional livestock grazing resulted in less disturbance to the surface soil, and did not in- duce to devastating wind erosion, which plays an important role in maintaining the stability of the steppe ecosystem in the northern Mongolian Plateau.展开更多
基金This study is supported by the Chinese 973 National Key Research and Development Program (2003CB214606) on Accumulation and Formation of Multi-Energy Mineral Deposits Coexisting in the same Basin and Open Foundation of the State Laboratory of Geological Processes and Mineral Resources.
文摘The major elements, trace elements and REEs were analyzed on the samples collected from the sandstone-type uranium deposits in the Ordos Basin to constrain the mechanism of uranium enrichment. The total REE amount ranges from 36.7 to 701.8 μg/g and the REE distribution patterns of the sandstone-type uranium samples are characterized by LREE enrichment and high REE depletion. The results also indicated a high Y abundance and Eu anomalies between 0.77-1.81. High-precision ICP-MS results showed that U abundances are within the range of 0.73-150 μg/g, showing some strong correlation between U enrichment and related elements such as Ti, V, Zr, Mo, and Au. In addition, Th abundance is correlated with ΣREE.
基金Cooperative project between provincial academy and provincial universities of Yunnan Province (2003ADBEA34A025).
文摘The Laochang polymetallic ore deposit at Lancang is one of the well known ancient ore deposits associated with volcanic rocks in the Sanjiang (Tri-river) region of Southwest China. Volcanic rocks are dominated by alkali basalt and trachyte basalt. There has long been a controversy on the environment of formation of basalts. Some scholars hold that the basalts were formed in a continental environment, some thought they were formed in an oceanic environment and others considered that the basalts were emplaced in a back-arc basin. This study focuses on the geochemical characteristics of the basalts on the basis of their major elements, REEs and trace elements. At the same time, strongly incompatible elements such as Ta, Th and Hf and their ratios were used to differentiate the geotectonic settings of basalts. The results showed that the basalts in the region studied were formed in a continental rift environment.
基金Supported by the Chinese Academy of Sciences(No.KJCXN-01).
文摘Basaltic samples from different locations in Aershan area determined by instrumental neutron activation analysis (INAA) have the same distribution patterns of REE and trace elements. The similar REE contents of the same minerals without inclusions from different xenolith suggest that the mantle source region under different active volcanoes have the same composition. The REE content differences between the same minerals with and without melt inclusions selected from the same mantle xenolith indicate that the melt inclusions are rich in REE. The same patterns of trace elements of inclusions and host minerals from different xenolith analyzed by SRXRF suggest that the mantle fluid has no notable heterogeneity in Aershan area.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 41430105, 41490631, 41573057 & 41521062)
文摘We report an imaging method of zircon U-Pb dating with NanoSIMS 50 L, which overcomes the significant U-Pb fractionation as the pit was sputtered deeper during conventional spot mode analysis and can be applied to irregular small grains or heterogeneous areas of zircon. The U-Pb and Pb-Pb ages can be acquired simultaneously for 2 μm×2 μm(for small grains) or 1 μm×9 μm(for zoned grains), together with Zr, Y and other trace elements distributions. Using zircon M257 as standard, the U-Pb ages of other zircon standards, including Qinghu, Plesovice, Temora and 91500, were measured to(2σ) as158.8±0.8, 335.9±3.4, 412.0±12 and 1067±12 Ma, respectively, consistent with the recommended values within the analytical uncertainties. Tiny zircon grains in the impact melt breccia of the lunar meteorite SaU 169 were also measured in this study,with a Pb-Pb age of 3912±14 Ma and a U-Pb age of 3917±17 Ma, similar to previous results reported for the same meteorite.The imaging method was also applied to determine U-Pb age of the thin overgrowth rims of Longtan metamorphic zircon, with a Pb-Pb age of 1933±27 Ma and a U-Pb age of 1935±25 Ma, clearly distinct from the Pb-Pb age of 2098±61 Ma and the U-Pb age of 2054±40 Ma for detrital cores.
基金the National Natural ScienceFoundation of China (Grant No. 40072046), Russian Foundation of Fundamental Investigations (Grant No. 99-05-39082), and Laboratory of Lithosphere Tectonic Evolution, Chinese Academy of Sciences (Grant No. 0104).
文摘Twenty-two peat samples collected at different depths of a core including the layer affected by the 1908 explosion in Tunguska area of Central Siberia, Russia, and three basalt sampies collected near the site, are analyzed by ICP-MS. The concentrations of Pd, Ni, Co, ∑ REE,Ti and Sr in the event layers are 4-35 times higher than the background values in the normal layers. The variation of Pd is closely related to Ni, Co and ∑ REE in the event layers, but not to these elements in the normal layers. It indicates that these excess elements came from the same source,i.e. the Tunguska explosion body. In addition, the patterns of Cl-chondrite-normalized REE in the event layers ((La/Yb)N≈2-3) are much flatter than those in the normal layers ((La/Yb)N≈7-143),and differ from those in the three basalt samples. The concentrations of REE in the three basalt samples are tens times higher than those in the event layers. It may be inferred that these excess elements could not be produced by the contamination of the terrestrial material, but probably by the Tunguska explosion body, Additionally, the ratios of Ti/Ni and Sr/Co in the event layers are close to those in comet. It implies that the solid part of the explosion body was compositionally similar to carbonaceous chondrites (CI) and more probably a small comet. In terms of the Pd excess fluxes in the explosion area, it can be estimated that the celestial body that exploded over Tunguska in 1908 weighed more than 107 tons, corresponding to a radius of >126 m.
基金Supported by the National Natural Science Foundation of China (Grant Nos. 40571130 and 40701150)the Key Project of International Cooperation, CAS (Grant No. GJHZ06)+3 种基金the Scientific Database of CAS (Grant No. INF105-SDB-A3)the Director Foundation of Institute of Geographic Sciences and Resources Research, CAS (Grant Nos. 06W60000SZ and 06W60001SZ)the Open Foundation of Key Laboratory of Water Cycle & Related Land Surface Processes, CAS (Grant No. WL2005001)the Key Project of Natural Science Foundation of Inner Mongolia of China (Grant Nos. 200608010602)
文摘Wind erosion is one of the major factors of land degradation in the typical steppe region, northern Mongolian Plateau. Using 137Cs tracing technique, we estimated the wind erosion rates of different pastures and abandoned farmland at Bayannur and Karakorum in Mongolia. The pastures and cutting grassland at Bayannur were slightly eroded by wind, with the rates of 64.58-169.07 t·km?2·a?1. The abandoned farmland in Karakorum, however, was strongly eroded by wind, with annual surface soil loss of 4.05 mm·a?1, and wind erosion rates up to 6723.06 t·km?2·a?1. The total loss of surface soil due to wind erosion has been 17.4 cm since the cultivation of the steppe land in the 1960s. The wind ero- sion rate at the abandoned farmland was much higher than that at the typical steppe sites, showing that the cultivation led to serious wind erosion in the typical steppe region, northern Mongolian Plateau. By contrast, traditional livestock grazing resulted in less disturbance to the surface soil, and did not in- duce to devastating wind erosion, which plays an important role in maintaining the stability of the steppe ecosystem in the northern Mongolian Plateau.