A new fluorescence silver nanosensor assisted by surfactant has been synthesized and applied to ultra trace nickel determination. Operational variables which influence nanomaterial synthesis have been studied and opti...A new fluorescence silver nanosensor assisted by surfactant has been synthesized and applied to ultra trace nickel determination. Operational variables which influence nanomaterial synthesis have been studied and optimized. Synthesis was very fast and simple using non polluting solvents; silver chemical reduction was carried out at room temperature. Spectroscopic studies were carried out in order to assure the uniformed of nanomaterial obtained. Fluorescent signal of silver nanoparticles resulted enhanced in presence of Ni（II）. At optimal experimental conditions, a detection limit of 0.036 pg＇L1 and quantification limit 0.12 pg＇L~ were obtained. The calibration sensitivity was 2 x 1014 L.pg-l.cm1 for the new methodology, with a range of linearity of six orders of magnitude between 0.12 and 2.93 × 10^5 pg L^-1. The tolerance levels for potential interferent ions were studied with good results. The proposed methodology represents a promising approach for Ni（II） traces quantification due to its low operation cost, simplicity of instrumentation, high sampling speed and non-polluting solvents.展开更多
To improve the efficiency of CNC machining, assumptive transit circular arc is used to contour two adjacent moves together on the comer to make smooth paths. The radios of transit circular arc can be adjusted with con...To improve the efficiency of CNC machining, assumptive transit circular arc is used to contour two adjacent moves together on the comer to make smooth paths. The radios of transit circular arc can be adjusted with contour accuracy, and the feed rate on the corner can be controlled through limiting the maximum feed rate of transit circular arc segment. A look-ahead algorithm for a series of moves is proposed for speed adjustment in advance, which avoids the occurrence of overload of cutting tool on the comer and reduces the servo track error of parts on the corner or of circular arc move. Equivalent trapezoidal velocity profile is used to analyze the speed of S-curve velocity profile and work out its accurate interpolation, which overcomes the disadvantage of looking up table to calculate feed rate approximately, hence high accuracy and fine surface quality can be obtained while the machining speed is high. The proposed methods can meet the requirements of real-time analysis of high-speed machining. The presented algorithm is effective and has been adopted by CNC system of newly developed high-speed milling machine.展开更多
A zero-speed fin stabilizer system was developed for rolling control of a marine robot.As a robot steering device near the sea surface with low speed,it will have rolling motion due to disturbance from waves.Based on ...A zero-speed fin stabilizer system was developed for rolling control of a marine robot.As a robot steering device near the sea surface with low speed,it will have rolling motion due to disturbance from waves.Based on the working principle of a zero-speed fin stabilizer and a marine robot’s dynamic properties,a roll damping controller was designed with a master-slave structure.It was composed of a sliding mode controller and an output tracking controller that calculates the desired righting moment and drives the zero-speed fin stabilizer.The methods of input-output linearization and model reference were used to realize the tracking control.Simulations were presented to demonstrate the validity of the control law proposed.展开更多
This study quantifies the main characteristics of a terrain-following, G-coordinate through mathematical analyses of its covariant and contravariant basis vectors as well as the vertical coordinate of σ. A 3-D schema...This study quantifies the main characteristics of a terrain-following, G-coordinate through mathematical analyses of its covariant and contravariant basis vectors as well as the vertical coordinate of σ. A 3-D schematic of the σ-coordinate in a curvilinear coordinate system is provided in this study. The characteristics of the basis vectors were broken down into their ＂local vector charac- teristics＂ and ＂spatial distribution characteristics＂, and the exact expressions of the covariant; in addition, the con- travariant basis vectors of the G-coordinate used to eluci- date their detailed characteristics were properly solved. Through rewriting the expression of the vertical coordi- nate of G, a mathematical expression of all the cr-coor- dinate surfaces was found, thereby quantifying the so- called terrain-following characteristics and lack of flexi- bility to adjust the slope variation of G-coordinate sur- faces for the classic definition of G. Finally, an analysis on the range value of the vertical coordinate demonstrated that the general value range of G could be obtained by eliminating the G-coordinate surfaces below the Earth＇s surface. All these quantitative descriptions of the charac- teristics of G-coordinate were the foundation for improv- ing the G-coordinate or creating a new one.展开更多
Tracking tests for different polymer materials were carried out to investigate the chaotic behavior of surface discharge. The discharge sequences measured during the discharge process were analyzed for finding the evi...Tracking tests for different polymer materials were carried out to investigate the chaotic behavior of surface discharge. The discharge sequences measured during the discharge process were analyzed for finding the evidence of chaos existence. Four kinds of nonlinear analysis methods were adopted： estimating the largest Lyapunov exponent, calculating the fractal dimension with increasing the embedding dimension, drawing the recurrence plots, and plotting the Poincare maps. It is found that the largest Lyapunov exponent of the discharge is positive, and the plot of fractal dimension, as a function of embedding dimension, will saturate at a value. The recur- rence plots show the chaotic frame-work patterns, and the Poincar6 maps also have the chaotic characteristics. The results indicate that the chaotic behavior does exist in the discharge currents of the tracking test.展开更多
文摘A new fluorescence silver nanosensor assisted by surfactant has been synthesized and applied to ultra trace nickel determination. Operational variables which influence nanomaterial synthesis have been studied and optimized. Synthesis was very fast and simple using non polluting solvents; silver chemical reduction was carried out at room temperature. Spectroscopic studies were carried out in order to assure the uniformed of nanomaterial obtained. Fluorescent signal of silver nanoparticles resulted enhanced in presence of Ni（II）. At optimal experimental conditions, a detection limit of 0.036 pg＇L1 and quantification limit 0.12 pg＇L~ were obtained. The calibration sensitivity was 2 x 1014 L.pg-l.cm1 for the new methodology, with a range of linearity of six orders of magnitude between 0.12 and 2.93 × 10^5 pg L^-1. The tolerance levels for potential interferent ions were studied with good results. The proposed methodology represents a promising approach for Ni（II） traces quantification due to its low operation cost, simplicity of instrumentation, high sampling speed and non-polluting solvents.
基金Sponsored by the National Excellent Young Teacher Encouragement Plan of China
文摘To improve the efficiency of CNC machining, assumptive transit circular arc is used to contour two adjacent moves together on the comer to make smooth paths. The radios of transit circular arc can be adjusted with contour accuracy, and the feed rate on the corner can be controlled through limiting the maximum feed rate of transit circular arc segment. A look-ahead algorithm for a series of moves is proposed for speed adjustment in advance, which avoids the occurrence of overload of cutting tool on the comer and reduces the servo track error of parts on the corner or of circular arc move. Equivalent trapezoidal velocity profile is used to analyze the speed of S-curve velocity profile and work out its accurate interpolation, which overcomes the disadvantage of looking up table to calculate feed rate approximately, hence high accuracy and fine surface quality can be obtained while the machining speed is high. The proposed methods can meet the requirements of real-time analysis of high-speed machining. The presented algorithm is effective and has been adopted by CNC system of newly developed high-speed milling machine.
基金Supported by the National Natural Science Foundation under Grant No50879012
文摘A zero-speed fin stabilizer system was developed for rolling control of a marine robot.As a robot steering device near the sea surface with low speed,it will have rolling motion due to disturbance from waves.Based on the working principle of a zero-speed fin stabilizer and a marine robot’s dynamic properties,a roll damping controller was designed with a master-slave structure.It was composed of a sliding mode controller and an output tracking controller that calculates the desired righting moment and drives the zero-speed fin stabilizer.The methods of input-output linearization and model reference were used to realize the tracking control.Simulations were presented to demonstrate the validity of the control law proposed.
基金supported by the National Natural Science Foundation of China under Grant Nos. 40821092,40633016,and 40875022
文摘This study quantifies the main characteristics of a terrain-following, G-coordinate through mathematical analyses of its covariant and contravariant basis vectors as well as the vertical coordinate of σ. A 3-D schematic of the σ-coordinate in a curvilinear coordinate system is provided in this study. The characteristics of the basis vectors were broken down into their ＂local vector charac- teristics＂ and ＂spatial distribution characteristics＂, and the exact expressions of the covariant; in addition, the con- travariant basis vectors of the G-coordinate used to eluci- date their detailed characteristics were properly solved. Through rewriting the expression of the vertical coordi- nate of G, a mathematical expression of all the cr-coor- dinate surfaces was found, thereby quantifying the so- called terrain-following characteristics and lack of flexi- bility to adjust the slope variation of G-coordinate sur- faces for the classic definition of G. Finally, an analysis on the range value of the vertical coordinate demonstrated that the general value range of G could be obtained by eliminating the G-coordinate surfaces below the Earth＇s surface. All these quantitative descriptions of the charac- teristics of G-coordinate were the foundation for improv- ing the G-coordinate or creating a new one.
基金Supported by National Natural Science Foundation of China (No.50777048)Tianjin Natural Science Foundation (No.07JCYBJC07700)
文摘Tracking tests for different polymer materials were carried out to investigate the chaotic behavior of surface discharge. The discharge sequences measured during the discharge process were analyzed for finding the evidence of chaos existence. Four kinds of nonlinear analysis methods were adopted： estimating the largest Lyapunov exponent, calculating the fractal dimension with increasing the embedding dimension, drawing the recurrence plots, and plotting the Poincare maps. It is found that the largest Lyapunov exponent of the discharge is positive, and the plot of fractal dimension, as a function of embedding dimension, will saturate at a value. The recur- rence plots show the chaotic frame-work patterns, and the Poincar6 maps also have the chaotic characteristics. The results indicate that the chaotic behavior does exist in the discharge currents of the tracking test.
