基于轨道变换法的多无人机跟踪相角修正研究

针对多无人飞行器协同standoff跟踪目标下的相角协调修正问题,提出了一种轨道变换法。建立了无人机运动学模型,用Lyapunov矢量场方法为无人机提供跟踪制导指令。通过在期望的standoff跟踪轨道外设置外轨道,将相角修正问题转化为无人机在两轨道上飞行时间差的控制问题,同时给出了确定多无人机机动变轨顺序的方法。最后对静止目标协同跟踪相角修正问题进行了仿真验证,仿真结果表明了该方法的正确性和有效性。

Diffusion Monte Carlo Study of Bond Dissociation Energies for BH2, B（OH）2, BCl2, and BCI

On basis of bond dissociation energies （BDEs） for BH2, B（OH）2, BCl2, and BCl, the diffusion Monte Carlo （DMC） method is applied to explore the BDEs of HB-H, HOB-OH, ClB-Cl, and B-Cl. The effect of the choice of orbitals, as well as the backflow transformation, is studied. The Slater-Jastrow DMC algorithm gives BDEs of 359.1±0.12 kJ/mol for HB-H, 410.5±0.50 kJ/mol for HOB-OH, 357.8±1.46 kJ/mol for ClB-Cl, and 504.5±0.96 kJ/mol for B-Cl using B3PW91 orbitals and similar BDEs when B3LYP orbitals are used. DMC with backflow corrections （BF-DMC） gives a HB-H BDE of 369.9±0.12 kJ/mol which is close to one of the available experimental value （375.8 kJ/mol）. In the case of HOB-OH BDE, the BF-DMC calculation is 446.04-1.84 k J/mol that is closer to the experimental BDE. The BF-DMC BDE for ClB-Cl is 343.2±2.34 kJ/mol and the BF-DMC B-Cl BDE is 523.3±0.33 kJ/mol, which are close to the experimental BDEs, 341.9 and 530.0 kJ/mol, respectively.