A decorated lattice is suggested and the Ising model on it with three kinds of interactions K1, K2, and K3 is studied. Using an equivalent transformation, the square decorated Ising lattice is transformed into a regul...A decorated lattice is suggested and the Ising model on it with three kinds of interactions K1, K2, and K3 is studied. Using an equivalent transformation, the square decorated Ising lattice is transformed into a regular square Ising lattice with nearest-neighbor, next-nearest-nelghbor, and four-spin interactions, and the critical fixed point is found at K1 = 0.5769, K2= -0.0671, and K3 = 0.3428, which determines the critical temperature of the system. It is also found that this system and the regular square Ising lattice, and the eight-vertex model belong to the same universality class.展开更多
In order to investigate the benefit of multiple-input multiple-output(MIMO) technique applying to the high altitude platform(HAP), a 2×2 MIMO statistical model, which can accurately describe the channel between H...In order to investigate the benefit of multiple-input multiple-output(MIMO) technique applying to the high altitude platform(HAP), a 2×2 MIMO statistical model, which can accurately describe the channel between HAP and high-speed train, is presented. And dual polarization diversity is particularly considered. Based on first-order three-state Markov chain, the single-input single-output(SISO) channel, a subset of the MIMO channel is first established. The ray tracing approach applied to the digital relief model(DRM) which covers the railway between Xi'an and Zhengzhou is used to obtain the state probability vector and matrix of the state transition probability. The proposed model considers both Doppler shift and temporal correlation, and the polarization correlation and spatial correlation statistical properties of large-scale fading and smallscale fading are analyzed. Moreover, useful numerical results on the MIMO HAP channel outage capacity are provided based on which, significant capacity gains with respect to the conventional SISO case are illustrated. Such statistical channel model can be applied to the future wireless communication system between HAP and high-speed train.展开更多
TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite photoanodes were successfully designed for the first time. The photoelectric conversion efficiency of TiO2-NaYF4:Er^3+/Yb^3+ C3N4 composite cell can result an efficiency of ...TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite photoanodes were successfully designed for the first time. The photoelectric conversion efficiency of TiO2-NaYF4:Er^3+/Yb^3+ C3N4 composite cell can result an efficiency of 7.37%, which is higher than those of pure TiO2 cell and TiO2-C3N4 composite cell. The enhancement of the efficiency can be attributed to the synergetic effect of NaYF4:Er^3+/Yb^3+ and C3N4. Elec- trochemical impedance spectroscopy analysis revealed that the interfacial resistance of the TiO2-dyelI3^-/I^- electrolyte interface of TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composites cell was much smaller than that of pure TiO2 cell. In addition, the TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite cell had longer electron recombination time and shorter electron transport time than that of pure TiO2 cell.展开更多
Electrocatalysis is deemed as a promising approach for sustainable energy conversion and chemical production.Although a variety of cathode reactions(e.g.,hydrogen evolution and CO_(2)/N_(2)reduction)produce valuable f...Electrocatalysis is deemed as a promising approach for sustainable energy conversion and chemical production.Although a variety of cathode reactions(e.g.,hydrogen evolution and CO_(2)/N_(2)reduction)produce valuable fuels and chemicals,the extensively studied oxygen evolution reaction(OER)at anode only generates O_(2),which is not a high-value product.Substituting the OER with thermodynamically more favorable biomass derivative oxidation reactions(BDORs)not only enables energy-saving electrocatalysis,but also provides value-added anode products.Recent achievements have demonstrated that non-noble electrocatalysts are promising for BDORs.Herein,we provide a comprehensive review on recent achievements in the field of electrochemical BDORs catalyzed by non-noble catalysts.We start by summarizing the electrocatalytic oxidation of different types of biomass-derived substrates,aiming to show the advantages of the electrocatalytic pathway and to introduce the state-of-the-art non-noble catalysts.The reaction mechanisms of non-noble-material-catalyzed BDORs are then summarized and classified into three types according to the acceptor of hydrogen species during the dehydrogenation of biomass derivatives.Subsequently,discussions are devoted to the strategies for promoting the performances of non-noble electrocatalysts.Finally,we propose our opinions regarding future trends and major challenges in this field.展开更多
基金The project supported by the Natural Science Foundation of Xiaogan University and the Science Foundation of Qufu Normal University
文摘A decorated lattice is suggested and the Ising model on it with three kinds of interactions K1, K2, and K3 is studied. Using an equivalent transformation, the square decorated Ising lattice is transformed into a regular square Ising lattice with nearest-neighbor, next-nearest-nelghbor, and four-spin interactions, and the critical fixed point is found at K1 = 0.5769, K2= -0.0671, and K3 = 0.3428, which determines the critical temperature of the system. It is also found that this system and the regular square Ising lattice, and the eight-vertex model belong to the same universality class.
基金sponsored by National Natural Science Foundation of China (No.91538104,No.91438205)China Postdoctoral Science Foundation (No.2011M500664)
文摘In order to investigate the benefit of multiple-input multiple-output(MIMO) technique applying to the high altitude platform(HAP), a 2×2 MIMO statistical model, which can accurately describe the channel between HAP and high-speed train, is presented. And dual polarization diversity is particularly considered. Based on first-order three-state Markov chain, the single-input single-output(SISO) channel, a subset of the MIMO channel is first established. The ray tracing approach applied to the digital relief model(DRM) which covers the railway between Xi'an and Zhengzhou is used to obtain the state probability vector and matrix of the state transition probability. The proposed model considers both Doppler shift and temporal correlation, and the polarization correlation and spatial correlation statistical properties of large-scale fading and smallscale fading are analyzed. Moreover, useful numerical results on the MIMO HAP channel outage capacity are provided based on which, significant capacity gains with respect to the conventional SISO case are illustrated. Such statistical channel model can be applied to the future wireless communication system between HAP and high-speed train.
基金supported by the National Natural Science Foundation of China (21471050 and 21501052)the China Postdoctoral Science Foundation (2015M570304)+2 种基金the Postdoctoral Science Foundation of Heilongjiang Province (LBH-TZ06019)Heilongjiang Province Natural Science Foundation (ZD201301)the Science Foundation for Excellent Youth of Harbin City of China (2016RQQXJ099)
文摘TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite photoanodes were successfully designed for the first time. The photoelectric conversion efficiency of TiO2-NaYF4:Er^3+/Yb^3+ C3N4 composite cell can result an efficiency of 7.37%, which is higher than those of pure TiO2 cell and TiO2-C3N4 composite cell. The enhancement of the efficiency can be attributed to the synergetic effect of NaYF4:Er^3+/Yb^3+ and C3N4. Elec- trochemical impedance spectroscopy analysis revealed that the interfacial resistance of the TiO2-dyelI3^-/I^- electrolyte interface of TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composites cell was much smaller than that of pure TiO2 cell. In addition, the TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite cell had longer electron recombination time and shorter electron transport time than that of pure TiO2 cell.
基金supported by the National Natural Science Foundation of China (21978147 and 21935001)Haihe Laboratory of Sustainable Chemical Transformationssupported by the Shuimu Tsinghua Scholar Program (2021SM072)
文摘Electrocatalysis is deemed as a promising approach for sustainable energy conversion and chemical production.Although a variety of cathode reactions(e.g.,hydrogen evolution and CO_(2)/N_(2)reduction)produce valuable fuels and chemicals,the extensively studied oxygen evolution reaction(OER)at anode only generates O_(2),which is not a high-value product.Substituting the OER with thermodynamically more favorable biomass derivative oxidation reactions(BDORs)not only enables energy-saving electrocatalysis,but also provides value-added anode products.Recent achievements have demonstrated that non-noble electrocatalysts are promising for BDORs.Herein,we provide a comprehensive review on recent achievements in the field of electrochemical BDORs catalyzed by non-noble catalysts.We start by summarizing the electrocatalytic oxidation of different types of biomass-derived substrates,aiming to show the advantages of the electrocatalytic pathway and to introduce the state-of-the-art non-noble catalysts.The reaction mechanisms of non-noble-material-catalyzed BDORs are then summarized and classified into three types according to the acceptor of hydrogen species during the dehydrogenation of biomass derivatives.Subsequently,discussions are devoted to the strategies for promoting the performances of non-noble electrocatalysts.Finally,we propose our opinions regarding future trends and major challenges in this field.