Collisions between hot H atoms and CO2 molecules were studied experimentally by time resolved Fourier transform infrared emission spectroscopy. H atoms with three translational energies, 174.7, 241.0 and 306.2 k J/mol...Collisions between hot H atoms and CO2 molecules were studied experimentally by time resolved Fourier transform infrared emission spectroscopy. H atoms with three translational energies, 174.7, 241.0 and 306.2 k J/mol respectively, were generated by UV laser photolysis to initiate a chemical reaction of H+CO2→OH+CO. Vibrationally excited CO (v≤2) was observed in the spectrum, where CO was the product of the reaction. The highly efficient T-V energy transfer fro,n the hot H atoms to the CO2 was verified too. The highest vibrational level of v=4 in CO2 (va) was found. Rate ratio of the chemical reaction to the energy transfer was estimated as 10.展开更多
Triplet-triplet energy transfer in fluorene dimer with electronic structure calculations. The two is investigated by combining rate theories key parameters for the control of energy transfer, electronic coupling and r...Triplet-triplet energy transfer in fluorene dimer with electronic structure calculations. The two is investigated by combining rate theories key parameters for the control of energy transfer, electronic coupling and reorganization energy, are calculated based on the diabatic states constructed by the constrained density functional theory. The fluctuation of the electronic coupling is further revealed by molecular dynamics simulation. Succeedingly, the diagonal and off-diagonal fluctuations of the Hamiltonian are mapped from the correlation functions of those parameters, and the rate is then estimated both from the perturbation theory and wavepacket diffusion method. The results manifest that both the static and dynamic fluctuations enhance the rate significantly, but the rate from the dynamic fluctuation is smaller than that from the static fluctuation.展开更多
Er^3+ doped SrTiO3 ultrafine powders were prepared by solid state reaction in a molten NaCl flux. The structural properties were characterized by X-ray diffraction, field emission scanning electron microscopy, and Fo...Er^3+ doped SrTiO3 ultrafine powders were prepared by solid state reaction in a molten NaCl flux. The structural properties were characterized by X-ray diffraction, field emission scanning electron microscopy, and Fourier transform infrared spectroscopy. The Stokes emission spectra of Er^3+ in SrTiO3:Er^3+ ranging from green to near infrared region were investigated under 514.5 nm laser excitation. The green and red upconverted luminescence spectra of Er^3+ were measured under excitation into the 419/2 level by 785 nm laser. The upconversion mechanisms were studied in detail through laser power dependence and Er^3+ ion concentration dependence of upconverted emissions, and results show that excited state absorption and energy transfer process are the possible mechanisms for the upconversion. The upconversion properties indicate that SrTiO3:Er^3+ may be used in upconversion phosphors.展开更多
A novel twin-rotor piston engine (TRPE) mechanism with high volumetric output and power density was introduced. This new engine comprises an energy conversion system and a differential velocity drive mechanism (DVD...A novel twin-rotor piston engine (TRPE) mechanism with high volumetric output and power density was introduced. This new engine comprises an energy conversion system and a differential velocity drive mechanism (DVDM). Two special geared four-bar mechanisms, DVDM-1 and DVDM-2, were utilized and compared. Based on the closed loop vector method, a mathematical model for position, velocity, and acceleration of the two mechanisms was established. Numerical examples illustrate that the kinematic characteristics were presented. Expression of the displacement and compression ratio of the two engine mechanisms were derived and compared. It is concluded that both DVDM-1 and DVDM-2 adopted in the proposed TRPE with six vane pistons create thirty-six power strokes per revolution of the output shaft, and the summation of two angles covered by each rocker is always 2x/N as the output shaft rotates an angle of x/N. In DVDM-1, the span angle of a vane piston should be designed to be 10.2°, and the compression ratio should be equal to 10; in DVDM-2, the span angle of a vane piston should be designed to be 10.6°, and the compression ratio should be equal to 4.3.展开更多
Physical-layer network coding(PNC) promises substantial theoretical gain to achieve the maximum system throughput in cooperative relay transmission. However, with the increasing global warming, how to reduce power con...Physical-layer network coding(PNC) promises substantial theoretical gain to achieve the maximum system throughput in cooperative relay transmission. However, with the increasing global warming, how to reduce power consumption while satisfy system throughput requirement is becoming a vital issue. In this paper, we investigate energy-efficiency resource allocation(RA) based on PNC with amplify-and-forward(AF) protocol in orthogonal frequency division multiple(OFDM) bidirectional transmission. To minimize the overall transmit power consumption with required system throughput requirement, we consider joint subcarriers and power allocation and formulate the objective task into a constrained optimization problem where the best relay node is selected to minimize total transmit power. The closed form optimization power allocation solutions are acquired by analytical derivation. Based on derivation, we propose a novel optimal energy-efficient power allocation(OE-PA). Numerical results are given to evaluate the performance of the derived scheme as compared to other schemes and show that our scheme has signifi cant improvement to energy saving.展开更多
Objective:To calculate the focus absorption dose of 153Sm-EDTMP with the Monte Carlo(MC)EGS4 method for treatment of bone metastases from nasopharyngeal carcinoma or breast cancer,and investigate the relationship betw...Objective:To calculate the focus absorption dose of 153Sm-EDTMP with the Monte Carlo(MC)EGS4 method for treatment of bone metastases from nasopharyngeal carcinoma or breast cancer,and investigate the relationship between the focus absorption dose and painkilling effect of 153Sm-EDTMP.Methods:Four patients with multiple bone metastases from nasopharyngeal or breast carcinoma and suffered from grade IV bone pain were treated with radionuclide internal irradiation of 153Sm-EDTMP.The absorption dose and dose distribution of bone metastases and other targeted organs were calculated with MC EGS4 program based on the time-order SPECT/CT scanning and the measurement of the radioactivity in the urine accumulation.The release of bone pain and the improvement of life quality were observed.Results:Bone pain of the patients was significantly alleviated to grade II for 3–4 weeks after internal 153Sm-EDTMP irradiation.The 3-dimensional absorption dose distribution image of bone metastases and targeted organs showed that the dose distribution in bone metastases was not asymmetrical.After injection of 0.65×37 MBq/kg 153Sm-EDTMP,the highest absorption dose in bone lesions was about 4.9–5.9 Gy,and the dose in the lesion margin was about 2.0 Gy.Using the highest dose as reference dose point,the relative absorption dose values of bone marrow,vertebra and sex organ near lesions were 0.48–1.1 Gy,0.51–0.85 Gy,and 0.01–0.14 Gy,respectively.Conclusion:The absorption dose of bone metastases is significantly lower than treatment dose of 30 Gy after single irradiation of 153Sm-EDTMP.The painkilling effect is limited and in accordance with clinical observation.展开更多
The collective excitations of low-dimensional Bose-Einstein condensates with two- and three-body interactions in anharmonic potentials are investigated. Using the standard variational approach, the governing equations...The collective excitations of low-dimensional Bose-Einstein condensates with two- and three-body interactions in anharmonic potentials are investigated. Using the standard variational approach, the governing equations of motions for the low-energy excitations are obtained by solving time-dependent Gross-Pitaevskii-Ginzburg equation, and the excitation spectrums are calculated in small amplitude limit. The frequency shift and nonlinear mode coupling induced by the anharmonic distortion (adding cubic, quartic, or quintic terra to a harmonic trap) are studied.展开更多
White organic light-emitting diodes (WOLEDs) with a structure of indium-tin-oxide (ITO)/N,N'-bis- (1-naphthyl)-N,N'-diphenyl- (1, 1'-biphenyl)-4,4'-diamine (NPB)/1,2,3,4,5,6-hexakis(9,9-diethyl-9H-fluor...White organic light-emitting diodes (WOLEDs) with a structure of indium-tin-oxide (ITO)/N,N'-bis- (1-naphthyl)-N,N'-diphenyl- (1, 1'-biphenyl)-4,4'-diamine (NPB)/1,2,3,4,5,6-hexakis(9,9-diethyl-9H-fluoren-2- yl)benzene (HKEthFLYPh)/5,6,11,12-tetraphenylnaphtacene (rubrene)/tris(8-hydroxyquinoline) aluminum (Alq3)/Mg:Ag were fabricated by vacuum deposition method, in which a novel star-shaped hexafluorenyl- benzene HKEthFLYPh was used as an energy transfer layer, and an ultrathin layer of rubrene was inserted between HKEthFLYPh and Alq3 layers as a yellow light-emitting layer instead of using a time-consuming doping process. A fairly pure WOLED with Commissions Internationale De L'Eclairage (CIE) coordinates of (0.32, 0.33) was obtained when the thickness of rubrene was 0.3 nm, and the spectrum was insensitive to the applied voltage. The device yielded a maximum luminance of 4816 cd/m2 at 18 V.展开更多
In this letter, by means of the Lax pair, Darboux transformation, and variable separation approach, a new exact solution of a sixth-order (1+ 1)-dimensional nonlinear evolution equation, which includes some arbitrary ...In this letter, by means of the Lax pair, Darboux transformation, and variable separation approach, a new exact solution of a sixth-order (1+ 1)-dimensional nonlinear evolution equation, which includes some arbitrary functions,is obtained. Abundant new localized excitations can be found by selecting appropriate functions and they are illustrated both analytically and graphically.展开更多
In this paper, the design, construction and ocean testing of a wave energy conversion system are studied. Based on the motion characteristics of double buoys in ocean waves, a wave energy conversion system with perman...In this paper, the design, construction and ocean testing of a wave energy conversion system are studied. Based on the motion characteristics of double buoys in ocean waves, a wave energy conversion system with permanent magnet tubular linear generator (PMTLG) is proposed to convert ocean wave energy into electricity. The wave energy conversion system was installed in the Yellow Sea near Lianyungang, China. The ocean test re- suits indicate that it had dynamic and static performance, and obtained an expected amount of electricity. The calcu- lation result indicates the average output power was about 1 000 W, and the conversion efficiency from wave en- ergy into electricity was 1.4%. In addition, the wireless data communication, mechanics and oceanography were also discussed.展开更多
In this work,we employ electronic structure calculations and nonadiabatic dynamics simulations based on many-body Green function and BetheSalpeter equation(GW/BSE)methods to study excited-state properties of a zinc ph...In this work,we employ electronic structure calculations and nonadiabatic dynamics simulations based on many-body Green function and BetheSalpeter equation(GW/BSE)methods to study excited-state properties of a zinc phthalocyanine-fullerene(ZnPcC_(60))dyad with 6-6 and 5-6 configurations.In the former,the initially populated locally excited(LE)state of ZnPc is the lowest S1 state and thus,its subsequent charge separation is relatively slow.In contrast,in the latter,the S1 state is the LE state of C_(60)while the LE state of ZnPc is much higher in energy.There also exist several charge-transfer(CT)states between the LE states of ZnPc and C_(60).Thus,one can see apparent charge separation dynamics during excited-state relaxation dynamics from the LE state of ZnPc to that of C_(60).These points are verified in dynamics simulations.In the first 200 fs,there is a rapid excitation energy transfer from ZnPc to C_(60),followed by an ultrafast charge separation to form a CT intermediate state.This process is mainly driven by hole transfer from C_(60)to ZnPc.The present work demonstrates that different bonding patterns(i.e.5-6 and 6-6)of the C−N linker can be used to tune excited-state properties and thereto optoelectronic properties of covalently bonded ZnPc-C_(60)dyads.Methodologically,it is proven that combined GW/BSE nonadiabatic dynamics method is a practical and reliable tool for exploring photoinduced dynamics of nonperiodic dyads,organometallic molecules,quantum dots,nanoclusters,etc.展开更多
基金supported by the National Natural Science Foundation of China and the National Basic Research Program of China(973 Program).
文摘Collisions between hot H atoms and CO2 molecules were studied experimentally by time resolved Fourier transform infrared emission spectroscopy. H atoms with three translational energies, 174.7, 241.0 and 306.2 k J/mol respectively, were generated by UV laser photolysis to initiate a chemical reaction of H+CO2→OH+CO. Vibrationally excited CO (v≤2) was observed in the spectrum, where CO was the product of the reaction. The highly efficient T-V energy transfer fro,n the hot H atoms to the CO2 was verified too. The highest vibrational level of v=4 in CO2 (va) was found. Rate ratio of the chemical reaction to the energy transfer was estimated as 10.
基金This work was supported by the National Natural Science Foundation of China (No.20833004 and No.21073146) and the Research Fund for the Doctoral Program of Higher Education of China (No.200803840009).
文摘Triplet-triplet energy transfer in fluorene dimer with electronic structure calculations. The two is investigated by combining rate theories key parameters for the control of energy transfer, electronic coupling and reorganization energy, are calculated based on the diabatic states constructed by the constrained density functional theory. The fluctuation of the electronic coupling is further revealed by molecular dynamics simulation. Succeedingly, the diagonal and off-diagonal fluctuations of the Hamiltonian are mapped from the correlation functions of those parameters, and the rate is then estimated both from the perturbation theory and wavepacket diffusion method. The results manifest that both the static and dynamic fluctuations enhance the rate significantly, but the rate from the dynamic fluctuation is smaller than that from the static fluctuation.
基金This work was supported by the Department of Education of Zhejiang Province (No.20060496) and the Natural Science Foundation of Zhejiang Province (No.Y406309).
文摘Er^3+ doped SrTiO3 ultrafine powders were prepared by solid state reaction in a molten NaCl flux. The structural properties were characterized by X-ray diffraction, field emission scanning electron microscopy, and Fourier transform infrared spectroscopy. The Stokes emission spectra of Er^3+ in SrTiO3:Er^3+ ranging from green to near infrared region were investigated under 514.5 nm laser excitation. The green and red upconverted luminescence spectra of Er^3+ were measured under excitation into the 419/2 level by 785 nm laser. The upconversion mechanisms were studied in detail through laser power dependence and Er^3+ ion concentration dependence of upconverted emissions, and results show that excited state absorption and energy transfer process are the possible mechanisms for the upconversion. The upconversion properties indicate that SrTiO3:Er^3+ may be used in upconversion phosphors.
基金Project(7131109) supported the by National Defense Pre-research Foundation of ChinaProject(50975278) supported by National the Natural Science Foundation of China
文摘A novel twin-rotor piston engine (TRPE) mechanism with high volumetric output and power density was introduced. This new engine comprises an energy conversion system and a differential velocity drive mechanism (DVDM). Two special geared four-bar mechanisms, DVDM-1 and DVDM-2, were utilized and compared. Based on the closed loop vector method, a mathematical model for position, velocity, and acceleration of the two mechanisms was established. Numerical examples illustrate that the kinematic characteristics were presented. Expression of the displacement and compression ratio of the two engine mechanisms were derived and compared. It is concluded that both DVDM-1 and DVDM-2 adopted in the proposed TRPE with six vane pistons create thirty-six power strokes per revolution of the output shaft, and the summation of two angles covered by each rocker is always 2x/N as the output shaft rotates an angle of x/N. In DVDM-1, the span angle of a vane piston should be designed to be 10.2°, and the compression ratio should be equal to 10; in DVDM-2, the span angle of a vane piston should be designed to be 10.6°, and the compression ratio should be equal to 4.3.
基金supported by the Science Instrument Special Funds of the National Natural Science Foundation of China under Grant No.61027003the National High Technology Research and Development Program of China under Grant No.2012AA01A50604
文摘Physical-layer network coding(PNC) promises substantial theoretical gain to achieve the maximum system throughput in cooperative relay transmission. However, with the increasing global warming, how to reduce power consumption while satisfy system throughput requirement is becoming a vital issue. In this paper, we investigate energy-efficiency resource allocation(RA) based on PNC with amplify-and-forward(AF) protocol in orthogonal frequency division multiple(OFDM) bidirectional transmission. To minimize the overall transmit power consumption with required system throughput requirement, we consider joint subcarriers and power allocation and formulate the objective task into a constrained optimization problem where the best relay node is selected to minimize total transmit power. The closed form optimization power allocation solutions are acquired by analytical derivation. Based on derivation, we propose a novel optimal energy-efficient power allocation(OE-PA). Numerical results are given to evaluate the performance of the derived scheme as compared to other schemes and show that our scheme has signifi cant improvement to energy saving.
基金grants from the Key Sci-Tech Research Foundationof Guangzhou City(No.2002XZ-J200131)Natural Science Foundationof Guangdong Province(No.031563)National Natural ScienceFoundation(No.10675175).
文摘Objective:To calculate the focus absorption dose of 153Sm-EDTMP with the Monte Carlo(MC)EGS4 method for treatment of bone metastases from nasopharyngeal carcinoma or breast cancer,and investigate the relationship between the focus absorption dose and painkilling effect of 153Sm-EDTMP.Methods:Four patients with multiple bone metastases from nasopharyngeal or breast carcinoma and suffered from grade IV bone pain were treated with radionuclide internal irradiation of 153Sm-EDTMP.The absorption dose and dose distribution of bone metastases and other targeted organs were calculated with MC EGS4 program based on the time-order SPECT/CT scanning and the measurement of the radioactivity in the urine accumulation.The release of bone pain and the improvement of life quality were observed.Results:Bone pain of the patients was significantly alleviated to grade II for 3–4 weeks after internal 153Sm-EDTMP irradiation.The 3-dimensional absorption dose distribution image of bone metastases and targeted organs showed that the dose distribution in bone metastases was not asymmetrical.After injection of 0.65×37 MBq/kg 153Sm-EDTMP,the highest absorption dose in bone lesions was about 4.9–5.9 Gy,and the dose in the lesion margin was about 2.0 Gy.Using the highest dose as reference dose point,the relative absorption dose values of bone marrow,vertebra and sex organ near lesions were 0.48–1.1 Gy,0.51–0.85 Gy,and 0.01–0.14 Gy,respectively.Conclusion:The absorption dose of bone metastases is significantly lower than treatment dose of 30 Gy after single irradiation of 153Sm-EDTMP.The painkilling effect is limited and in accordance with clinical observation.
基金supported by the Natural Science Foundation of Shaanxi University of Science and Technology under Grant No.SUST-ZX07-32partly by National Natural Science Foundation of China under Grant No.10774120
文摘The collective excitations of low-dimensional Bose-Einstein condensates with two- and three-body interactions in anharmonic potentials are investigated. Using the standard variational approach, the governing equations of motions for the low-energy excitations are obtained by solving time-dependent Gross-Pitaevskii-Ginzburg equation, and the excitation spectrums are calculated in small amplitude limit. The frequency shift and nonlinear mode coupling induced by the anharmonic distortion (adding cubic, quartic, or quintic terra to a harmonic trap) are studied.
基金This work was supported by the National Natural Science Foundation of China (No.60425101 and No.20674049), the Program for New Century Excellent Talents in University (No.NCET-06-0812), and the Young Talent Project at University of Electronic Science and Technology of China (No.060206).
文摘White organic light-emitting diodes (WOLEDs) with a structure of indium-tin-oxide (ITO)/N,N'-bis- (1-naphthyl)-N,N'-diphenyl- (1, 1'-biphenyl)-4,4'-diamine (NPB)/1,2,3,4,5,6-hexakis(9,9-diethyl-9H-fluoren-2- yl)benzene (HKEthFLYPh)/5,6,11,12-tetraphenylnaphtacene (rubrene)/tris(8-hydroxyquinoline) aluminum (Alq3)/Mg:Ag were fabricated by vacuum deposition method, in which a novel star-shaped hexafluorenyl- benzene HKEthFLYPh was used as an energy transfer layer, and an ultrathin layer of rubrene was inserted between HKEthFLYPh and Alq3 layers as a yellow light-emitting layer instead of using a time-consuming doping process. A fairly pure WOLED with Commissions Internationale De L'Eclairage (CIE) coordinates of (0.32, 0.33) was obtained when the thickness of rubrene was 0.3 nm, and the spectrum was insensitive to the applied voltage. The device yielded a maximum luminance of 4816 cd/m2 at 18 V.
文摘In this letter, by means of the Lax pair, Darboux transformation, and variable separation approach, a new exact solution of a sixth-order (1+ 1)-dimensional nonlinear evolution equation, which includes some arbitrary functions,is obtained. Abundant new localized excitations can be found by selecting appropriate functions and they are illustrated both analytically and graphically.
基金Supported by the National Natural Science Foundation of China(No.41076054)Special Foundation for State Oceanic Administration of China(No.GHME2011GD02)Scientific Research Foundation of Graduate School of Southeast University(No.YBJJ1416)
文摘In this paper, the design, construction and ocean testing of a wave energy conversion system are studied. Based on the motion characteristics of double buoys in ocean waves, a wave energy conversion system with permanent magnet tubular linear generator (PMTLG) is proposed to convert ocean wave energy into electricity. The wave energy conversion system was installed in the Yellow Sea near Lianyungang, China. The ocean test re- suits indicate that it had dynamic and static performance, and obtained an expected amount of electricity. The calcu- lation result indicates the average output power was about 1 000 W, and the conversion efficiency from wave en- ergy into electricity was 1.4%. In addition, the wireless data communication, mechanics and oceanography were also discussed.
基金support from the National Natural Science Foundation of China(No.21688102,No.21590801,and No.21520102005)support from Sichuan Science and Technology Program Grant(2020YJ0161)。
文摘In this work,we employ electronic structure calculations and nonadiabatic dynamics simulations based on many-body Green function and BetheSalpeter equation(GW/BSE)methods to study excited-state properties of a zinc phthalocyanine-fullerene(ZnPcC_(60))dyad with 6-6 and 5-6 configurations.In the former,the initially populated locally excited(LE)state of ZnPc is the lowest S1 state and thus,its subsequent charge separation is relatively slow.In contrast,in the latter,the S1 state is the LE state of C_(60)while the LE state of ZnPc is much higher in energy.There also exist several charge-transfer(CT)states between the LE states of ZnPc and C_(60).Thus,one can see apparent charge separation dynamics during excited-state relaxation dynamics from the LE state of ZnPc to that of C_(60).These points are verified in dynamics simulations.In the first 200 fs,there is a rapid excitation energy transfer from ZnPc to C_(60),followed by an ultrafast charge separation to form a CT intermediate state.This process is mainly driven by hole transfer from C_(60)to ZnPc.The present work demonstrates that different bonding patterns(i.e.5-6 and 6-6)of the C−N linker can be used to tune excited-state properties and thereto optoelectronic properties of covalently bonded ZnPc-C_(60)dyads.Methodologically,it is proven that combined GW/BSE nonadiabatic dynamics method is a practical and reliable tool for exploring photoinduced dynamics of nonperiodic dyads,organometallic molecules,quantum dots,nanoclusters,etc.