Carbon deposition is sensitive to the metal particle sizes of supported Ni catalysts in CH_4/CO_2 reforming.To explore the reason of this phenomenon,Ni4,Ni8,and Ni12 which re flect the different cluster thicknesses su...Carbon deposition is sensitive to the metal particle sizes of supported Ni catalysts in CH_4/CO_2 reforming.To explore the reason of this phenomenon,Ni4,Ni8,and Ni12 which re flect the different cluster thicknesses supported on the MgO(100) slabs,have been employed to simulate Ni/MgO catalysts,and the reaction pathways of CH_4/CO_2 reforming on Nix/MgO(100) models are investigated by density functional theory.The reforming mechanisms of CH_4/CO_2 on different Nix/MgO(100) indicate the energy barriers of CH_4 dissociated adsorption,CH dissociation,and C oxidation three factors are all declining with the decrease of the Ni cluster sizes.The Hirshfeld charges analyses of three steps as described above show only Ni atoms in bottom two layers can obtain electrons from the MgO supporters,and the main electron transfer occurs between adsorbed species and their directly contacted Ni atoms.Due to more electron-rich Ni atoms in contact with the MgO supporters,the Ni/MgO catalysts with small Ni particles have a strong metal particle size effect and lead to its better catalytic activity.展开更多
This paper describes the key issues of high-speed brushless permanent magnet motor design, such as rotor design, stator design, and determination of the main dimensions, and the overall design process was given. In th...This paper describes the key issues of high-speed brushless permanent magnet motor design, such as rotor design, stator design, and determination of the main dimensions, and the overall design process was given. In this paper, a two-pole three-phase high-speed brushless PM (permanent magnet) motor with ratings air-gap length and stator slot number on the motor performance of 7.5 kW, 30,000 rpm is designed, and the effect of the different was analyzed. The results show that larger number of stator slot decreases the rotor loss and the rotor torque ripple. Larger air-gap length decreases the rotor loss.展开更多
Small-sized axial fans are used as air coolers for electric equipments.But there is a strong demand for higher power of fans according to the increase of quantity of heat from electric devices.Therefore,higher rotatio...Small-sized axial fans are used as air coolers for electric equipments.But there is a strong demand for higher power of fans according to the increase of quantity of heat from electric devices.Therefore,higher rotational speed design is conducted,although it causes the deterioration of the efficiency and the increase of noise.Then the adoption of contra-rotating rotors for the small-sized axial fan is proposed for the improvement of the performance.In the present paper,the performance and the internal flow condition of the small-sized axial fan are shown as a first step of the research for the contra-rotating small-sized axial fan and the important points to apply contra-rotating rotors to the small-sized axial fan are discussed.Furthermore,the numerical flow analysis is conducted to investigate the performance of the contra-rotating small-sized axial fan and internal flow conditions and pressure distributions are clarified and the effect of contra-rotating rotors is considered.展开更多
基金Supported by the National Natural Science Foundation of China(U1361202,51276120)
文摘Carbon deposition is sensitive to the metal particle sizes of supported Ni catalysts in CH_4/CO_2 reforming.To explore the reason of this phenomenon,Ni4,Ni8,and Ni12 which re flect the different cluster thicknesses supported on the MgO(100) slabs,have been employed to simulate Ni/MgO catalysts,and the reaction pathways of CH_4/CO_2 reforming on Nix/MgO(100) models are investigated by density functional theory.The reforming mechanisms of CH_4/CO_2 on different Nix/MgO(100) indicate the energy barriers of CH_4 dissociated adsorption,CH dissociation,and C oxidation three factors are all declining with the decrease of the Ni cluster sizes.The Hirshfeld charges analyses of three steps as described above show only Ni atoms in bottom two layers can obtain electrons from the MgO supporters,and the main electron transfer occurs between adsorbed species and their directly contacted Ni atoms.Due to more electron-rich Ni atoms in contact with the MgO supporters,the Ni/MgO catalysts with small Ni particles have a strong metal particle size effect and lead to its better catalytic activity.
文摘This paper describes the key issues of high-speed brushless permanent magnet motor design, such as rotor design, stator design, and determination of the main dimensions, and the overall design process was given. In this paper, a two-pole three-phase high-speed brushless PM (permanent magnet) motor with ratings air-gap length and stator slot number on the motor performance of 7.5 kW, 30,000 rpm is designed, and the effect of the different was analyzed. The results show that larger number of stator slot decreases the rotor loss and the rotor torque ripple. Larger air-gap length decreases the rotor loss.
基金supports by the project research aid from The University of Tokushima,Japan Science and Technology Agency and Komiya research aid
文摘Small-sized axial fans are used as air coolers for electric equipments.But there is a strong demand for higher power of fans according to the increase of quantity of heat from electric devices.Therefore,higher rotational speed design is conducted,although it causes the deterioration of the efficiency and the increase of noise.Then the adoption of contra-rotating rotors for the small-sized axial fan is proposed for the improvement of the performance.In the present paper,the performance and the internal flow condition of the small-sized axial fan are shown as a first step of the research for the contra-rotating small-sized axial fan and the important points to apply contra-rotating rotors to the small-sized axial fan are discussed.Furthermore,the numerical flow analysis is conducted to investigate the performance of the contra-rotating small-sized axial fan and internal flow conditions and pressure distributions are clarified and the effect of contra-rotating rotors is considered.