Glass substrates which realize high out-coupling efficiency OLEDs （organic light emitting diodes） were developed. A scattering layer whose matrix was made of high refractive index glass was formed on a glass substra...Glass substrates which realize high out-coupling efficiency OLEDs （organic light emitting diodes） were developed. A scattering layer whose matrix was made of high refractive index glass was formed on a glass substrate, and pores in the glass matrix work as scattering centers. The out-coupling efficiency of an OLED using this substrate is 1.8 times higher compared with an OLED using an untreated glass substrate. Furthermore angular dependency of the color and color variation between panels can be successfully suppressed.展开更多
How to control the dipole orientation of organic emitters is a challenge in the field of organic light-emitting diodes(OLEDs).Herein,a linear thermally activated delayed fluorescence(TADF)molecule,PhNAI-PMSBA,bearing ...How to control the dipole orientation of organic emitters is a challenge in the field of organic light-emitting diodes(OLEDs).Herein,a linear thermally activated delayed fluorescence(TADF)molecule,PhNAI-PMSBA,bearing a 1,8-naphthalimide-acridine framework was designed by a doublesite long-axis extension strategy to actively control the dipole orientation.The horizontal ratio of emitting dipole orientation of PhNAI-PMSBA reaches 95%,substantially higher than that of isotropic emitters(67%).This unique feature is associated with the intrinsically horizontal molecular orientation of PhNAI-PMSBA and the good agreement between its transition dipole moment direction and molecular long axis.The PhNAI-PMSBA-based OLED achieves an ultrahigh optical outcoupling efficiency of 43.2%and thus affords one of the highest red electroluminescence with an external quantum efficiency of 22.3%and the Commission International de l’Eclairage 1931 coordinates at around(0.60,0.40).展开更多
Blue top-emitting organic light-emitting devices （TEOLEDs） are demonstrated by employing Alq3 as phase shift adjustment layer （PSAL） to increase the phase shift on reflection of the top electrode within a range, w...Blue top-emitting organic light-emitting devices （TEOLEDs） are demonstrated by employing Alq3 as phase shift adjustment layer （PSAL） to increase the phase shift on reflection of the top electrode within a range, which also improves the light out-coupling. By adjusting the thickness of P SAL, the CIEx,y of devices, which utilize 2, 7-Di-pyrenyl-9, 9-spiro-bifluorene （DPSF） as emitting layer, changes from （0.16, 0.50） to （0.18, 0.37）. The maximnum current efficiency of 7.1 cd/A is acquired under 4.5 V with an increasing luminance of 139 cd/m^2. Compared with adjusting the total thickness of organic layer, it is more beneficial for achieving blue TEOLEDs with high efficiency.展开更多
文摘Glass substrates which realize high out-coupling efficiency OLEDs （organic light emitting diodes） were developed. A scattering layer whose matrix was made of high refractive index glass was formed on a glass substrate, and pores in the glass matrix work as scattering centers. The out-coupling efficiency of an OLED using this substrate is 1.8 times higher compared with an OLED using an untreated glass substrate. Furthermore angular dependency of the color and color variation between panels can be successfully suppressed.
基金the National Natural Science Foundation of China(51873158,51573141,91833304 and 91433201)the National Key R&D Program of China(2016YFB0401002)+4 种基金Shenzhen Science and Technolgy Program(KQTD20170330110107046 and JCYJ20190808151209557)the Key Technological Innovation Program of Hubei Province(2018AAA013)the Natural Science Foundation for Distinguished Young Scholars of Hubei Province(2017CFA033)the support from the Ministry of Science and Technology of Taiwan(MOST 107-2221-E-002-160-MY3 and 108-2221-E-002-148-MY3)the post-doctoral fellowship from the Ministry of Education(MOE)of Taiwan。
文摘How to control the dipole orientation of organic emitters is a challenge in the field of organic light-emitting diodes(OLEDs).Herein,a linear thermally activated delayed fluorescence(TADF)molecule,PhNAI-PMSBA,bearing a 1,8-naphthalimide-acridine framework was designed by a doublesite long-axis extension strategy to actively control the dipole orientation.The horizontal ratio of emitting dipole orientation of PhNAI-PMSBA reaches 95%,substantially higher than that of isotropic emitters(67%).This unique feature is associated with the intrinsically horizontal molecular orientation of PhNAI-PMSBA and the good agreement between its transition dipole moment direction and molecular long axis.The PhNAI-PMSBA-based OLED achieves an ultrahigh optical outcoupling efficiency of 43.2%and thus affords one of the highest red electroluminescence with an external quantum efficiency of 22.3%and the Commission International de l’Eclairage 1931 coordinates at around(0.60,0.40).
文摘Blue top-emitting organic light-emitting devices （TEOLEDs） are demonstrated by employing Alq3 as phase shift adjustment layer （PSAL） to increase the phase shift on reflection of the top electrode within a range, which also improves the light out-coupling. By adjusting the thickness of P SAL, the CIEx,y of devices, which utilize 2, 7-Di-pyrenyl-9, 9-spiro-bifluorene （DPSF） as emitting layer, changes from （0.16, 0.50） to （0.18, 0.37）. The maximnum current efficiency of 7.1 cd/A is acquired under 4.5 V with an increasing luminance of 139 cd/m^2. Compared with adjusting the total thickness of organic layer, it is more beneficial for achieving blue TEOLEDs with high efficiency.
