MnSAPO-34 molecular sieves were synthesized by vapor-phase transport (VPT) method using triethylamine (Et3N) as a structure directing agent (SDA), and were characterized by XRD, BET, SEM, UV-Vis, FT-IR, and TG a...MnSAPO-34 molecular sieves were synthesized by vapor-phase transport (VPT) method using triethylamine (Et3N) as a structure directing agent (SDA), and were characterized by XRD, BET, SEM, UV-Vis, FT-IR, and TG analy- ses. The influence of the zeolite crystallization conditions and the dry-gel composition were investigated. The results showed that the synthesis conditions had an effect on the crystalline phase. Pure MnSAPO-34 had been obtained when it was crystallized at 140 C for 18 hours. The ratio of MnO/A1203 in the starting gel ranging from 0.1 to 0.2 resulted in pure MnSAPO-34 with a CHA topology. Beyond this scope, MnSAPO-5 with an AFI topology structure was obtained as an impurity substance. UV-Vis spectroscopy and FT-IR spectroscopy study indicated that manganese was incorporated into the framework of the molecular sieve. The catalytic performance of MnSAPO-34 molecular sieve was tested by ketalization reaction of l, 2-propanediol with cyclohexanone. High yield of cyclohexanone-1, 2-propanediol ketal was obtained.展开更多
This paper researched on the atmospheric transmission performance of 0.4 μm~0.8 μm ray radiation based on the characteristic of the middle latitude atmosphere in China.By analysis of the characteristic of the actua...This paper researched on the atmospheric transmission performance of 0.4 μm~0.8 μm ray radiation based on the characteristic of the middle latitude atmosphere in China.By analysis of the characteristic of the actual atmosphere,the absorption of molecular and the scattering of the steam and ozone,as well as the aerosol scattering(big granule scattering) are play a leading role to the 0.4 μm~0.8 μm ray radiation.Then a better atmospheric transmission formula in horizontal path has been deducted.The result of computer simulation indicates that this equation can best calculate the transmission performance of 0.4 μm~0.8 μm visible radiation in the middle latitude area of China.This computing result was applied to the nuclear explosion parameter detection system based on 0.4 μm~0.8 μm visible radiation.Through nuclear explosion simulator to produce ray radiation,the tested result indicates that this method has the better measuring precision than the traditional method with the software of LOWTRAN.The calculation result of this formula not only can apply directly to each kind of optoelectronics detecting system,but also to the optical wireless communication system based on the 0.4 μm~0.8 μm ray radiation.展开更多
There is low formation pressure coefficient and high formation temperature in ludong-wucaiwan area. Gas cut and gas channeling happen seriously during oil and gas well cementing. The existing anti-migration additive h...There is low formation pressure coefficient and high formation temperature in ludong-wucaiwan area. Gas cut and gas channeling happen seriously during oil and gas well cementing. The existing anti-migration additive has only effects on single trait, so it is difficult to meet cementing requirement. According to this situation we could use latex slurry to anti-gas channeling. We have synthesised a set of anti-gas channeling lightweight temperature-resistant latex slurry and formed a new channeling preventing latex slurry through plenty of previous laboratory experiments. Finally the performance of latex slurry on temperature-resistant, anti-gas channeling and the anti-gas channeling of cement paste are studied. The experimental results show that this latex system has strong temperature-resistant and anti-gas channeling, which completely meet the requirement of cementing in this area.展开更多
This paper presents an overview of the safety performance of the major existing pipeline transmission system in Canada, USA and Europe. The article deals the experience of Georgia in the development of pipeline transp...This paper presents an overview of the safety performance of the major existing pipeline transmission system in Canada, USA and Europe. The article deals the experience of Georgia in the development of pipeline transport. The information on the distribution of catastrophic failures and incidents per individual cause is given. The role of corrosion in these failures is considered. To ensure efficient and reliable operations of oil and gas pipelines, the new compositions of competitive cost effective protective pipe enamel coatings have been developed.展开更多
Simulation has proven to be an effective tool for analyzing pipeline network systems (PNS) in order to determine the design and operational variables which are essential for evaluating the performance of the system....Simulation has proven to be an effective tool for analyzing pipeline network systems (PNS) in order to determine the design and operational variables which are essential for evaluating the performance of the system. This paper discusses the use of simulation for performance analysis of transmission PNS. A simulation model was developed for determining flow and pressure variables for different configuration of PNS. The mathematical formulation for the simulation model was derived based on the principles of energy conservation, mass balance, and compressor characteristics. For the determination of the pressure and flow variables, solution procedure was developed based on iterative Newton Raphson scheme and implemented using visual C++6. Evaluations of the simulation model with the existing pipeline network system showed that the model enabled to determine the operational variables with less than ten iterations. The performances of the compressor working in the pipeline network system xvhich includes energy consumption, compression ratio and discharge pressure were evaluated to meet pressure requirements ranging from 4000-5000 kPa at various speed. Results of the analyses from the simulation indicated that the model could be used for performance analysis to assist decisions regarding the design and optimal operations of transmission PNS.展开更多
Off-statistics input data sets are common in axial-flow fans design and may easily result in some violation of the requirements of a good aerodynamic blade design.In order to circumvent this problem,in the present pap...Off-statistics input data sets are common in axial-flow fans design and may easily result in some violation of the requirements of a good aerodynamic blade design.In order to circumvent this problem,in the present paper,a solution to the radial equilibrium equation is found which minimizes the outlet kinetic energy and fulfills the aerodynamic constraints,thus ensuring that the resulting blade has acceptable aerodynamic performance.The presented method is based on the optimization of a three-parameters vortex law and of the meridional channel size.The aerodynamic quantities to be employed as constraints are individuated and their suitable ranges of variation are proposed.The method is validated by means of a design with critical input data values and CFD analysis.Then,by means of systematic computations with different input data sets,some correlations and charts are obtained which are analogous to classic correlations based on statistical investigations on existing machines.Such new correlations help size a fan of given characteristics as well as study the feasibility of a given design.展开更多
基金supported by the Key Laboratory of Fine Chemicals,Jiangsu Provincefinancially supported by the Jiangsu Province Science and Technology Support Program (BE2011651)the Key University Science Research Project of Jiangsu Province (11KJA610002)
文摘MnSAPO-34 molecular sieves were synthesized by vapor-phase transport (VPT) method using triethylamine (Et3N) as a structure directing agent (SDA), and were characterized by XRD, BET, SEM, UV-Vis, FT-IR, and TG analy- ses. The influence of the zeolite crystallization conditions and the dry-gel composition were investigated. The results showed that the synthesis conditions had an effect on the crystalline phase. Pure MnSAPO-34 had been obtained when it was crystallized at 140 C for 18 hours. The ratio of MnO/A1203 in the starting gel ranging from 0.1 to 0.2 resulted in pure MnSAPO-34 with a CHA topology. Beyond this scope, MnSAPO-5 with an AFI topology structure was obtained as an impurity substance. UV-Vis spectroscopy and FT-IR spectroscopy study indicated that manganese was incorporated into the framework of the molecular sieve. The catalytic performance of MnSAPO-34 molecular sieve was tested by ketalization reaction of l, 2-propanediol with cyclohexanone. High yield of cyclohexanone-1, 2-propanediol ketal was obtained.
文摘This paper researched on the atmospheric transmission performance of 0.4 μm~0.8 μm ray radiation based on the characteristic of the middle latitude atmosphere in China.By analysis of the characteristic of the actual atmosphere,the absorption of molecular and the scattering of the steam and ozone,as well as the aerosol scattering(big granule scattering) are play a leading role to the 0.4 μm~0.8 μm ray radiation.Then a better atmospheric transmission formula in horizontal path has been deducted.The result of computer simulation indicates that this equation can best calculate the transmission performance of 0.4 μm~0.8 μm visible radiation in the middle latitude area of China.This computing result was applied to the nuclear explosion parameter detection system based on 0.4 μm~0.8 μm visible radiation.Through nuclear explosion simulator to produce ray radiation,the tested result indicates that this method has the better measuring precision than the traditional method with the software of LOWTRAN.The calculation result of this formula not only can apply directly to each kind of optoelectronics detecting system,but also to the optical wireless communication system based on the 0.4 μm~0.8 μm ray radiation.
文摘There is low formation pressure coefficient and high formation temperature in ludong-wucaiwan area. Gas cut and gas channeling happen seriously during oil and gas well cementing. The existing anti-migration additive has only effects on single trait, so it is difficult to meet cementing requirement. According to this situation we could use latex slurry to anti-gas channeling. We have synthesised a set of anti-gas channeling lightweight temperature-resistant latex slurry and formed a new channeling preventing latex slurry through plenty of previous laboratory experiments. Finally the performance of latex slurry on temperature-resistant, anti-gas channeling and the anti-gas channeling of cement paste are studied. The experimental results show that this latex system has strong temperature-resistant and anti-gas channeling, which completely meet the requirement of cementing in this area.
文摘This paper presents an overview of the safety performance of the major existing pipeline transmission system in Canada, USA and Europe. The article deals the experience of Georgia in the development of pipeline transport. The information on the distribution of catastrophic failures and incidents per individual cause is given. The role of corrosion in these failures is considered. To ensure efficient and reliable operations of oil and gas pipelines, the new compositions of competitive cost effective protective pipe enamel coatings have been developed.
文摘Simulation has proven to be an effective tool for analyzing pipeline network systems (PNS) in order to determine the design and operational variables which are essential for evaluating the performance of the system. This paper discusses the use of simulation for performance analysis of transmission PNS. A simulation model was developed for determining flow and pressure variables for different configuration of PNS. The mathematical formulation for the simulation model was derived based on the principles of energy conservation, mass balance, and compressor characteristics. For the determination of the pressure and flow variables, solution procedure was developed based on iterative Newton Raphson scheme and implemented using visual C++6. Evaluations of the simulation model with the existing pipeline network system showed that the model enabled to determine the operational variables with less than ten iterations. The performances of the compressor working in the pipeline network system xvhich includes energy consumption, compression ratio and discharge pressure were evaluated to meet pressure requirements ranging from 4000-5000 kPa at various speed. Results of the analyses from the simulation indicated that the model could be used for performance analysis to assist decisions regarding the design and optimal operations of transmission PNS.
文摘Off-statistics input data sets are common in axial-flow fans design and may easily result in some violation of the requirements of a good aerodynamic blade design.In order to circumvent this problem,in the present paper,a solution to the radial equilibrium equation is found which minimizes the outlet kinetic energy and fulfills the aerodynamic constraints,thus ensuring that the resulting blade has acceptable aerodynamic performance.The presented method is based on the optimization of a three-parameters vortex law and of the meridional channel size.The aerodynamic quantities to be employed as constraints are individuated and their suitable ranges of variation are proposed.The method is validated by means of a design with critical input data values and CFD analysis.Then,by means of systematic computations with different input data sets,some correlations and charts are obtained which are analogous to classic correlations based on statistical investigations on existing machines.Such new correlations help size a fan of given characteristics as well as study the feasibility of a given design.