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改进的边价连接性指数及其应用 被引量:12
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作者 沐来龙 冯长君 《化工学报》 EI CAS CSCD 北大核心 2004年第4期531-540,共10页
由成键原子的轨道电负性 χp 定义键校正参数Sj,Sj 反映了边j的不同成键情况 根据直接与边i相邻的化学键的数目及其键校正参数Sj,定义了边i的边价fi.基于邻接矩阵与边价 (fi)定义边价连接性指数(mF) ,其中的0 F、1F及端基数 (N)与 16 ... 由成键原子的轨道电负性 χp 定义键校正参数Sj,Sj 反映了边j的不同成键情况 根据直接与边i相邻的化学键的数目及其键校正参数Sj,定义了边i的边价fi.基于邻接矩阵与边价 (fi)定义边价连接性指数(mF) ,其中的0 F、1F及端基数 (N)与 16 3种链烃 (烷烃、单烯烃、双烯烃及炔烃等 )、 72种脂肪族醛酮的沸点(Tb)关联 ,得到良好的数学模型 .模型经Jackknife法检验具有总体稳健性 .可以预示 ,该指数将在定量构效关系研究中成为重要参数 . 展开更多
关键词 边价连接性指数 链烃 脂肪醛 脂肪酮 沸点 定量构效关系
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链烃标准熵的边价拓扑研究 被引量:2
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作者 冯长君 沐来龙 《北京化工大学学报(自然科学版)》 CAS CSCD 北大核心 2005年第6期57-60,共4页
由顶点i与j形成边k的特征值(δk):δk=4.96/(χp,i+χp,j),链烃中边j的边价jδV定义为与边j相邻边的δk值之和。在分子图的邻接矩阵基础上,定义新的边价连接性指数(mF)及其逆指数(mF′)。使用其中的0F,1F,0F′,1F′与228种链烃(含157种... 由顶点i与j形成边k的特征值(δk):δk=4.96/(χp,i+χp,j),链烃中边j的边价jδV定义为与边j相邻边的δk值之和。在分子图的邻接矩阵基础上,定义新的边价连接性指数(mF)及其逆指数(mF′)。使用其中的0F,1F,0F′,1F′与228种链烃(含157种链烷烃,71种不饱和烃)标准熵(S m)的复相关因数为0.999,计算值与实验值基本吻合。优于Thinh基团加和法的估算结果。 展开更多
关键词 边价连接性指数 标准熵 链烃 定量结构-性质相关(QSPR)
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脂肪族饱和一元醇沸点的拓扑研究 被引量:11
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作者 沐来龙 冯长君 《有机化学》 SCIE CAS CSCD 北大核心 2004年第4期403-408,351,共7页
基于邻接矩阵与边价 (fi)定义边价连接性指数 ( mF) ,其中的0 F、醇距离参数L及醇类型参数与 119种脂肪族饱和一元醇的沸点 (Tb)关联、得到良好的数学模型 :ln( 72 4-Tb) =6 0 70 10 -0 0 5 7180 F -0 0 0 3 71L -0 0 75 49δ-1 (n =... 基于邻接矩阵与边价 (fi)定义边价连接性指数 ( mF) ,其中的0 F、醇距离参数L及醇类型参数与 119种脂肪族饱和一元醇的沸点 (Tb)关联、得到良好的数学模型 :ln( 72 4-Tb) =6 0 70 10 -0 0 5 7180 F -0 0 0 3 71L -0 0 75 49δ-1 (n =119) ,R =0 9974.相关性优于文献值 .可以预示 ,该模型能更精确的预测饱和醇的沸点 . 展开更多
关键词 边价连接性指数 脂肪醇 沸点 定量构效关系
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不饱和链烃沸点的拓扑研究 被引量:7
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作者 沐来龙 冯长君 《有机化学》 SCIE CAS CSCD 北大核心 2004年第2期173-183,115,共12页
基于邻接矩阵与边价 (fi)定义边价连接性指数 ( mF) ,其中的0 F ,1 F与 2 94种不饱和链烃 (包括烯烃、炔烃及烯炔烃 )的沸点 (Tb)关联 ,得到良好的数学模型 :ln( 70 0 -Tb) =6 5 2 3 3 1-0 0 0 4880 F2 -0 3 46771 F0 5(n =2 94,R =0... 基于邻接矩阵与边价 (fi)定义边价连接性指数 ( mF) ,其中的0 F ,1 F与 2 94种不饱和链烃 (包括烯烃、炔烃及烯炔烃 )的沸点 (Tb)关联 ,得到良好的数学模型 :ln( 70 0 -Tb) =6 5 2 3 3 1-0 0 0 4880 F2 -0 3 46771 F0 5(n =2 94,R =0 9979,R2 =0 995 8,F =3 490 4,S =5 12 ) ,该回归模型经Jackknife法检验具有总体稳健性 .可以预示 ,该指数将在定量构效关系研究中成为重要参数 . 展开更多
关键词 边价连接性指数 不饱和链烃 沸点 定量构效关系
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脂肪醇的溶解度及生物活性的QSPR/QSAR研究 被引量:3
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作者 杨伟华 冯长君 《哈尔滨工业大学学报》 EI CAS CSCD 北大核心 2005年第11期1552-1554,共3页
对含杂原子边价进行了修正,得出修正点价iδV.据分子图的邻接矩阵,用修正点价iδV建构新的边价连接性指数mF,并用mF研究了脂肪醇化合物在水中的溶解度(SW),正辛醇/水分配系数(KOW)及对水生生物的急性毒性(LC50).用0阶指数0F和碳原子数N... 对含杂原子边价进行了修正,得出修正点价iδV.据分子图的邻接矩阵,用修正点价iδV建构新的边价连接性指数mF,并用mF研究了脂肪醇化合物在水中的溶解度(SW),正辛醇/水分配系数(KOW)及对水生生物的急性毒性(LC50).用0阶指数0F和碳原子数N关联-lgSW、lgKOW,二元相关系数分别为0.990 7,0.995 3.用0阶指数0F关联10种醇对呆鲦鱼的毒性lgLC50,相关系数r为0.987 2;关联13种醇对Golden orfe鱼的毒性-lgLC50,相关系数r为0.980 8.结果表明相关性良好.新方法计算方便,物理意义明确,预测值与相应的实验值较吻合. 展开更多
关键词 边价连接性指数 脂肪醇 溶解度 正辛醇/水分配系数 急性毒性 QSPR/QSAR 非特异性毒性
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21世纪乡镇企业发展的十大趋势
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作者 陈剑光 《中国.城乡桥》 2001年第1期4-5,共2页
从90年代中期以后,伴随着社会主义市场经济的发展,乡镇企业产权制度改革的不断深化,整体素质的稳步提高,结构和布局的逐渐优化,区域互助的广泛开展。虽然这个进程还在继续,但乡镇企业面向下一世纪的发展已经出现了一种明显的发展趋势,... 从90年代中期以后,伴随着社会主义市场经济的发展,乡镇企业产权制度改革的不断深化,整体素质的稳步提高,结构和布局的逐渐优化,区域互助的广泛开展。虽然这个进程还在继续,但乡镇企业面向下一世纪的发展已经出现了一种明显的发展趋势,需要我们认真把握,加强引导,概括为“十大趋势”: 展开更多
关键词 十大趋势 乡镇企业发展 乡镇企业家 21世纪 优势企业 后发展地区 核心资本 竟争 边价 扶持办法
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电力市场中计算输电电价的一种新方法 被引量:28
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作者 任震 吴国玥 黄雯莹 《中国电机工程学报》 EI CSCD 北大核心 2003年第1期37-40,170,共5页
该文基于边际成本理论,提出了一种计算输电电价的新方法,在保留边际成本定价中的经济信息的同时,综合考虑了无功电价,又考虑了电网的年收支平衡,最后,通过潮流跟踪法,确定有功、无功电价及固定成本在各个用户间的分配,使定价模型更加合... 该文基于边际成本理论,提出了一种计算输电电价的新方法,在保留边际成本定价中的经济信息的同时,综合考虑了无功电价,又考虑了电网的年收支平衡,最后,通过潮流跟踪法,确定有功、无功电价及固定成本在各个用户间的分配,使定价模型更加合理、完善。经IEEE6节点系统算例证明,该文所提的模型和算法是正确而有效的,具有重要的理论意义和工程实际价值,特别是对于在厂网分开后电网建设以及维护电网稳定的资金筹措有相当的指导价值。 展开更多
关键词 电网 无功功率 边际成本理论 潮流计算 电力市场 输电电价
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Positive Solutions of Boundary Value Problems for Systems of Nonlinear Second-order Differential Equations 被引量:3
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作者 ZHENG Dong-mei LU Shi-ping 《Chinese Quarterly Journal of Mathematics》 CSCD 2011年第2期179-184,共6页
By using fixed-point index theory,we study boundary value problems for systems of nonlinear second-order differential equation,and a result on existence and multiplicity of positive solutions is obtained.
关键词 boundary value problems fixed-point index positive solution CONE
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Existence of Positive Solution for Superlinear Semipositone Singular Second-order m-point Boundary Value Problem 被引量:4
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作者 ZHANG Xing-qiu 《Chinese Quarterly Journal of Mathematics》 CSCD 2010年第1期151-158,共8页
By applying fixed point theorem, the existence of positive solution is considered for superlinear semipositone singular m-point boundary value problem -(Lφ)(x)=(p(x)φ′(x))′+q(x)φ(x) and ξi ∈ (0,... By applying fixed point theorem, the existence of positive solution is considered for superlinear semipositone singular m-point boundary value problem -(Lφ)(x)=(p(x)φ′(x))′+q(x)φ(x) and ξi ∈ (0,1)with 0〈ξ1〈ξ2……〈ξm-2〈1,αi ∈ R^+,f ∈C[(0,1)×R^+,R^+],f(x,φ) may be singular at x=0 and x=1,g(x):(0,1)→R is Lebesgue measurable, g may tend to negative infinity and have finitely many singularities. 展开更多
关键词 SEMIPOSITONE SUPERLINEAR singular m-point boundary value fixed point theo-rem positive solution
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Singular Perturbations for a Class of Fourth-order Nonlinear Boundary Value Problem 被引量:2
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作者 LI Xu WANG Shi-peng 《Chinese Quarterly Journal of Mathematics》 CSCD 2011年第2期217-222,共6页
This paper is devoted to study the following the singularly perturbed fourth-order ordinary differential equation ∈y(4) =f(t,y',y'',y'''),0t1,0ε1 with the nonlinear boundary conditions y(0)=y'(1)=0,p... This paper is devoted to study the following the singularly perturbed fourth-order ordinary differential equation ∈y(4) =f(t,y',y'',y'''),0t1,0ε1 with the nonlinear boundary conditions y(0)=y'(1)=0,p(y''(0),y'''(0))=0,q(y''(1),y'''(1))=0 where f:[0,1]×R3→R is continuous,p,q:R2→R are continuous.Under certain conditions,by introducing an appropriate stretching transformation and constructing boundary layer corrective terms,an asymptotic expansion for the solution of the problem is obtained.And then the uniformly validity of solution is proved by using the differential inequalities. 展开更多
关键词 singular perturbation nonlinear boundary value problem differential inequality asymptotic expansion
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Existence of Solutions for a Multi-point Boundary Value Problems with Three Dimension Kernal at Resonance
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作者 LIANG Ju-hua REN Li-shun ZHAO Zhi-liang 《Chinese Quarterly Journal of Mathematics》 CSCD 2011年第1期138-143,共6页
In this paper,a multi-point boundary value problems for a three order nonlinear deferential equation is considered.With the help of coincidence theorem due to Mawhin,a existence theorem is obtained.
关键词 boundary value problems coincidence degree theorem existence theorem 2000 MR Subject Classification:34B10 34B15
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Existence of Solutions for Generalized Sturm-Liouville m-point Boundary Value Problems in Banach Spaces
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作者 YANG Jing-bao WEI Zhong-li 《Chinese Quarterly Journal of Mathematics》 CSCD 2011年第2期265-269,共5页
By applying the fixed-point theorem of strict-set-contraction,this paper establishes the existence of one solution or one positive solution to the generalized Sturm-Liouville m-point boundary value problem in Banach s... By applying the fixed-point theorem of strict-set-contraction,this paper establishes the existence of one solution or one positive solution to the generalized Sturm-Liouville m-point boundary value problem in Banach spaces. 展开更多
关键词 Banach spaces fixed-point theorem of strict-set-contraction STURM-LIOUVILLE m-pointt boundary value problem positive solution
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Reservoir-landslide Hazard Assessment Based on GIS: A Case Study in Wanzhou Section of the Three Gorges Reservoir 被引量:5
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作者 WANG Meng QIAO Jian-ping 《Journal of Mountain Science》 SCIE CSCD 2013年第6期1085-1096,共12页
Reservoir-landslide is mainly caused by changes in hydrodynamic conditions of slope interior at the time of water storage or discharge. The current study mainly focuses on the typical reservoirlandslide, but the sudde... Reservoir-landslide is mainly caused by changes in hydrodynamic conditions of slope interior at the time of water storage or discharge. The current study mainly focuses on the typical reservoirlandslide, but the sudden occurrence of some unknown landslides brought a lot of difficulties for hazards prevention. Therefore, we proposed a method to evaluate the regional scale reservoir-landslide hazard. We took Wanzhou section of Three Gorges Reservoir(China) as the study area and systemically and synthetically carried out the reservoir-landslide hazard evaluation under the condition of water level regulation. Firstly, we made reservoir-landslide susceptibility assessment by using the methods of spatial analysis and statistics based on geological and geomorphological materials and field survey data, and then, analyzed the regional-scale slope stability based on the infinite slope model used to analyze the bank slope stability change under the condition of water fluctuation, finally, developed a reservoir-landslide hazard evaluation model based on the results of susceptibility and stability. The hazard evaluation model was used to predict and evaluate the hazard change under the role of water level regulation. The results showed that the landslide hazard of the whole region decreased during water storage, landslide hazards increased during water discharge. The faster the regulation speed, the greater the slope hazard. The results can provide the basis for hazard management and regional land-use planning. 展开更多
关键词 Reservoir-landslide Hazards assessment
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A NEW MODELLING METHOD FOR EVALUATING EXTERNAL DISTURBING POTENTIAL BASED ON THEORY OF UNIFIED REPRESENTATION OF GRAVITATIONAL FIELD
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作者 ZHU Zhuowen HUANG Jinshui CAO Huasheng LUO Zhicai 《Geo-Spatial Information Science》 2000年第2期41-46,共6页
For a special use a new modelling method of evaluating external disturbing potential is presented in this paper.Being different from classical methods in physical geodesy this method is grounded upon the theory of uni... For a special use a new modelling method of evaluating external disturbing potential is presented in this paper.Being different from classical methods in physical geodesy this method is grounded upon the theory of unified representation of gravitational field.The models created in this way are particularly satisfactory for a high_speed computation of gravitational field in low altitude because they take account of topographic effects and have their kernel functions with simple structure and weak singularity. 展开更多
关键词 theory of unified representation of gravitational field evaluation of disturbing gravitational field topographic effect gravimetric inverse boundary value problem singlelayer potential
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An Extreme Value Approach to Test the Effect of Price Limits on Volatility
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作者 Haitham Nobanee Khalil Hilu 《Journal of Modern Accounting and Auditing》 2013年第10期1382-1391,共10页
Many stock exchanges around the world enforcing daily price limits on the amount asset prices can change to prevent the market from overreacting and to reduce volatility. Price limits are artificial boundaries set by ... Many stock exchanges around the world enforcing daily price limits on the amount asset prices can change to prevent the market from overreacting and to reduce volatility. Price limits are artificial boundaries set by market regulators who restrict price changes of a stock to a pre-specified range during a trading day or a single trading session. The primary aim of price limit rules is to stabilize the markets during panic trading, to moderate vitality by repressing excessive speculation, and to allow stocks to be traded at prices close to their fair value. However, their impact on the market is a somewhat unresolved issue (Harris, 1998). Using a methodology of comparing volatility based on the extreme value technique, the authors empirically investigate the impact of price limits on the volatility of the Stock Exchange of Thailand. The empirical results support price limits advocates, suggesting that price limits rules moderate stock price volatility. 展开更多
关键词 price limits extreme value theory VOLATILITY Stock Exchange of Thailand
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A new double reduction method for slope stability analysis 被引量:15
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作者 白冰 袁维 李小春 《Journal of Central South University》 SCIE EI CAS 2014年第3期1158-1164,共7页
The core of strength reduction method(SRM) involves finding a critical strength curve that happens to make the slope globally fail and a definition of factor of safety(FOS). A new double reduction method, including a ... The core of strength reduction method(SRM) involves finding a critical strength curve that happens to make the slope globally fail and a definition of factor of safety(FOS). A new double reduction method, including a detailed calculation procedure and a definition of FOS for slope stability was developed based on the understanding of SRM. When constructing the new definition of FOS, efforts were made to make sure that it has concise physical meanings and fully reflects the shear strength of the slope. Two examples, slopes A and B with the slope angles of 63° and 34° respectively, were given to verify the method presented. It is found that, for these two slopes, the FOSs from original strength reduction method are respectively 1.5% and 38% higher than those from double reduction method. It is also found that the double reduction method predicts a deeper potential slide line and a larger slide mass. These results show that on one hand, the double reduction method is comparative to the traditional methods and is reasonable, and on the other hand, the original strength reduction method may overestimate the safety of a slope. The method presented is advised to be considered as an additional option in the practical slope stability evaluations although more useful experience is required. 展开更多
关键词 slope stability strength reduction method double strength reduction method factor of safety limit equilibrium method
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Integral Operator Solving Process of the Boundary Value Problem of Abstract Kinetic Equation with the First Kind of Critical Parameter and Generalized Periodic Boundary Conditions
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作者 YU De-jian 《Chinese Quarterly Journal of Mathematics》 CSCD 2010年第1期110-117,共8页
In this paper the concepts of the boundary value problem of abstract kinetic equation with the first kind of critical parameter γ 0 and generalized periodic boundary conditions are introduced in a Lebesgue space whic... In this paper the concepts of the boundary value problem of abstract kinetic equation with the first kind of critical parameter γ 0 and generalized periodic boundary conditions are introduced in a Lebesgue space which consists of functions with vector valued in a general Banach space, and then describe the solution of these abstract boundary value problem by the abstract linear integral operator of Volterra type. We call this process the integral operator solving process. 展开更多
关键词 abstract kinetic equation with the first kind of critical parameter boundary value problem of abstract kinetic equation generalized periodic boundary conditions abstract linear integral operator of Volterra type integral operator solving process
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Applying real time seismic monitoring technology for slope stability assessment—An Indian opencast coal mine perspective 被引量:9
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作者 Vinoth S. Ajay Kumar L. 《International Journal of Mining Science and Technology》 SCIE EI 2014年第1期75-80,共6页
This paper outlines the results obtained from real time microseismic monitoring of an opencast coal mine in South India.The objective of the study is to investigate the stress changes within the rockmass along the slo... This paper outlines the results obtained from real time microseismic monitoring of an opencast coal mine in South India.The objective of the study is to investigate the stress changes within the rockmass along the slope due to underground mine development operation and their impact on the stability of the highwall slope.The installed microseismic systems recorded the seismic triggerings down toà2 moment magnitude.In general,most of the events recorded during the monitoring period are weak in seismic energy.The study adopts a simple and more reliable tool to characterize the seismically active zone for assessing the stability of the highwall in real time.The impact of underground working on the slope is studied on the basis of the seismic event impact contours and seismic clusters.During the monitoring period,it is observed that the intensity of the overall microseismic activity along the slope due to the mine development operations did not cause any adverse impact on the highwall stability. 展开更多
关键词 Seismic monitoring Induced seismicity Seismic clusters Slope stability Opencast mining
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Evaluation of an ocean data assimilation system for Chinese marginal seas with a focus on the South China Sea
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作者 许大志 李熙晨 +1 位作者 朱江 齐义泉 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2011年第2期414-426,共13页
Data assimilation is a powerful tool to improve ocean forecasting by reducing uncertainties in forecast initial conditions.Recently,an ocean data assimilation system based on the ensemble optimal interpolation(EnOI) s... Data assimilation is a powerful tool to improve ocean forecasting by reducing uncertainties in forecast initial conditions.Recently,an ocean data assimilation system based on the ensemble optimal interpolation(EnOI) scheme and HYbrid Coordinate Ocean Model(HYCOM) for marginal seas around China was developed.This system can assimilate both satellite observations of sea surface temperature(SST) and along-track sea level anomaly(SLA) data.The purpose of this study was to evaluate the performance of the system.Two experiments were performed,which spanned a 3-year period from January 1,2004 to December 30,2006,with and without data assimilation.The data assimilation results were promising,with a positive impact on the modeled fields.The SST and SLA were clearly improved in terms of bias and root mean square error over the whole domain.In addition,the assimilations provided improvements in some regions to the surface field where mesoscale processes are not well simulated by the model.Comparisons with surface drifter trajectories showed that assimilated SST and SLA also better represent surface currents,with drifter trajectories fitting better to the contours of SLA field than that without assimilation.The forecasting capacity of this assimilation system was also evaluated through a case study of a birth-and-death process of an anticyclone eddy in the Northern South China Sea(NSCS),in which the anticyclone eddy was successfully hindcasted by the assimilation system.This study suggests the data assimilation system gives reasonable descriptions of the near-surface ocean state and can be applied to forecast mesoscale ocean processes in the marginal seas around China. 展开更多
关键词 data assimilation EnOI Scheme HYCOM model South China Sea
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Application of artificial slope stability evaluation of improved response surface method in Donggang Power Plant
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作者 LI Xiangli 《Global Geology》 2014年第1期38-43,共6页
The study of artificial slope stability has been a key item of geological engineering projects. Though more evaluation methods are available,result of stability evaluation simulation does not explain the actual proble... The study of artificial slope stability has been a key item of geological engineering projects. Though more evaluation methods are available,result of stability evaluation simulation does not explain the actual problem owing to the diversified geological engineering factors and complexity. The author made a detailed study based on surveys of large amount of geological engineering research on Donggang Power Plant slope project,discussed the comprehensive factors influencing the project,and gave analytical calculation and evaluation to the improved response surface of the slope project. The study result shows that the slope is stable,which can provide scientific basis for designing the slope. 展开更多
关键词 SLOPE improved response surface method RELIABILITY plastic deformation STABILITY
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