The population dynamics and breeding behaviors of Black-crowned Night Herons ( Nycticorax nycticorax ), Egrets (Egtetta garzetta), Chinese Pond Herons (Ardeola bacchus) and Great Egrets (Casmerodius albus) wer...The population dynamics and breeding behaviors of Black-crowned Night Herons ( Nycticorax nycticorax ), Egrets (Egtetta garzetta), Chinese Pond Herons (Ardeola bacchus) and Great Egrets (Casmerodius albus) were observed in Tanghai Wetlands, Hebei Province from August 2004 to July 2005. Further, we studied the relationship of nest space distribution and directly calculated the nest density of vertical and horizontal levels, the niche overlapping index and the niche breadth. The results showed that there were two breeding areas, named Area Ⅰ and Area Ⅱ . The maximum population occurred in the period from April to September and was approximately 5800 individuals. Area Ⅰ was occupied earlier than Area Ⅱ by approximately half a month. In the breeding period, Black-crowned Night Herons were dominant in numbers and most occupied the upper nests of the core areas. Great Egrets also took the upper nests but they have the smallest population. Most Egrets took the middle nests of the edges of the area. Chinese Pond Herons, with a smaller population than the Egret, mostly nested in the edges, but some of them also took the lower nests of the core area. On the whole, the vertical niche of Egrets is the widest, the horizontal niche of Black-crowned Night Herons is the widest and the niche breadth of Chinese Pond Herons is the largest. The nest distribution pattern is the most similar between Chinese Pond Herons and Black-crowned Night Herons, and the niche overlapping index of Chinese Pond Herons and Egrets is the largest. Black-crowned Night Herons and Great Egrets control Egrets and Chinese Pond Herons in competition. Rich food and the optimal ecological environments lead to plenty of herons in the wetlands. In addition, it is a distinguishing feature of the four species that nests are built in poplar trees over 22 m tall.展开更多
Information on lead redistribution and speciation changes in anthrosphere can help to analyze the whole lead cycle on the earth. Lead life cycle was traced based on the concepts of anthropogenic transfer and transform...Information on lead redistribution and speciation changes in anthrosphere can help to analyze the whole lead cycle on the earth. Lead life cycle was traced based on the concepts of anthropogenic transfer and transformation. Lead transfer and the distribution of chemical species throughout the anthropogenic flow were identified in 2010 in China. The results show that 1.85 Mt lead ore was consumed(besides 1.287 Mt imported concentrated ore and 1.39 Mt lead scraps. After undergoing transformations, 3.53 Mt lead entered end services in chemical species of Pb, Pb O2 and PbSO4, altogether accounting for over 80% of the total lead products. Finally, 2.10 Mt ore was emitted into the environment in such species as PbSO4(26%), PbO(19%) and Pb(15%). Lead transfer begins in primary raw material sectors, and then transfers to manufacturing sectors. Lead provides services mainly in such industrial sectors as transportation, electrical power and buildings or construction.展开更多
The depletion rate of phosphate in the soil-root interface zone increased along with growth and phosphateuptake of wheat or maize, which indicated that the phosphate distribution in soil near the root surfaceagreed we...The depletion rate of phosphate in the soil-root interface zone increased along with growth and phosphateuptake of wheat or maize, which indicated that the phosphate distribution in soil near the root surfaceagreed well with the phosphate movement in rhizosphere and phosphate uptake by plant. The relativeaccumulation zone of phosphate within 0.5 mm apart from the root surface developed at the 15th day or soafter cultivating wheat or maize since the root phosphate secretion increased gradually in this stage. Thephosphate distribution in the soil-root interface zone against the growing time (t) and the distance from theroot plane (x) could be described by the non-linear regression equation with the third powers of x and t.展开更多
The shear-induced migration of neutrally-buoyant non-colloidal circular particles in a two-dimensional circular Couette flow is investigated numerically with a distributed Lagrange multiplier based fictitious domain m...The shear-induced migration of neutrally-buoyant non-colloidal circular particles in a two-dimensional circular Couette flow is investigated numerically with a distributed Lagrange multiplier based fictitious domain method.The effects of inertia and volume fraction on the particle migration are examined.The results indicate that inertia has a negative effect on the particle migration.In consistence with the experimental observations,the rapid migration of particles near the inner cylinder at the early stage is observed in the simulation,which is believed to be related to the chain-like clustering of particles.The migration of circular particles in a plane Poiseuille flow is also examined in order to further confirm the effect of such clustering on the particle migration at early stage.There is tendency for the particles in the vicinity of outer cylinder in the Couette device to pack into concentric rings at late stage in case of high particle concentration.展开更多
The fabrication and characterization of a laser ionization source for ion mobility spectrometer (IMS) is described with the calculated parameter of the drift tube. Ions are created in air at ambient pressure using l...The fabrication and characterization of a laser ionization source for ion mobility spectrometer (IMS) is described with the calculated parameter of the drift tube. Ions are created in air at ambient pressure using laser ionization ( A = 248 nm) with air as the drift gas. Mobility spectra for positive ions at different electric fields are obtained with the length of drift tube of 25 and 50 mm, respectively. The distribution of the electric field in the drift tube (50 mm) has also been investigated by SIMION simulation with the ion shutter closed and open respectively.展开更多
Objective To explore the influence of oxidized high-density lipoprotein (oxHDL) on the maturation and migration of bone marrow-derived dendritic cells (BMDCs) from C57BL/6J mice. Methods The C57BL/6J mice bone ma...Objective To explore the influence of oxidized high-density lipoprotein (oxHDL) on the maturation and migration of bone marrow-derived dendritic cells (BMDCs) from C57BL/6J mice. Methods The C57BL/6J mice bone marrow cell suspension was prepared and purified. Recombinant granulocyte-macrophage colony-stimulating factor (rmGM-CSF) and recombinant interleukin-4 (rmlL-4) were used to promote monocytes to differentiate and suppress lymphocytes. Then 50μg/mL oxHDL was added to stimulate BMDCs, using 50μg/mL high-density lipoprotein (HDL) as homologous protein control, PBS as negative control, and 1 μg/mL lipopolysaccharide (LPS) as positive control. The CD86 and MHCII expression rates were detected with fluorescence-activated cell sorting (FACS). Liquid scintillation counting (LSC) was used in mixed lymphocyte reactions (MLRs) to reflect the ability of BMDCs in stimulating the proliferation of homologous T cells, Levels of cytokines IL-12 and IL-10 were detected by ELISA. The cell migration was evaluated with the transwell system. Results Compared with PBS group, the expressions of CD86 and MHCII, counts per minute of MLRs, secretion of IL-12 and IL-10, and number of migrated cells in oxHDL group and LPS group significantly increased (all P 〈 0.05), while the increment was less in oxHDL group than LPS group. The number of migrated cells in oxHDL group was about twice of that in HDL group. Conclusion OxHDL may promote the maturation and migration of BMDCs in vitro.展开更多
A new mobile multicast scheme called mobility prediction based mobile multicast(MPBMM) was proposed. In MPBMM, when a mobile node (MN) roams among subnets during a multicast session, MN predicts the next subnet, to wh...A new mobile multicast scheme called mobility prediction based mobile multicast(MPBMM) was proposed. In MPBMM, when a mobile node (MN) roams among subnets during a multicast session, MN predicts the next subnet, to which MN will attach, by the information of its position and mobility speed, consequently speeds up the handoff procedure. Simulation results show that the proposed scheme can minimize the loss of multicast packets, reduce the delay of subnet handoff, decrease the frequency of multicast tree reconfiguration, and optimize the delivery path of multicast packets. When MN moves among subnets at different speeds (from 5 to 25 ms), the maximum loss ratio of multicast packets is less than0.2%, the maximum inter-arrival time of multicast packets is 117 ms, so the proposed scheme can meet the QoS requirements of real-time services. In addition, MPBMM can support the mobility of multicast source.展开更多
Performance evaluation shows that Hierarchical Mobile IPv6 (HMIPv6) cannot outperform standard Mobile IPv6 (MIPv6) in all scenarios. Thus, adaptive protocol selection under certain circumstances is desired. Moreover, ...Performance evaluation shows that Hierarchical Mobile IPv6 (HMIPv6) cannot outperform standard Mobile IPv6 (MIPv6) in all scenarios. Thus, adaptive protocol selection under certain circumstances is desired. Moreover, it is necessary to balance the load among different Mobility Anchor Points (MAPs). This paper proposes an efficient three-level hierarchical ar- chitecture for mobility management in HMIPv6 networks, in which a mobile node (MN) may register with either a higher/lower MAP or its home agent according to its speed and the number of connecting correspondent nodes (CNs). An admission control algorithm and a replacement algorithm are introduced to achieve load balancing between two MAP levels and among different MAPs within the same MAP level. Admission control is based on the number of CNs but not MNs that an MAP serves. In case there is no capacity for an MN, the MAP chooses an existing MN to be replaced. The replaced MN uses the MAP selection al- gorithm again to choose another mobility agent. Simulation results showed that the proposed scheme achieves better performance not only in reducing the signaling overhead, but also in load balancing among different MAPs.展开更多
Methyl vinyl ketone oxide,an unsaturated four-carbon Criegee intermediate produced from the ozonolysis of isoprene has been recognized to play a key role in determining the tropospheric OH concentration.It exists in f...Methyl vinyl ketone oxide,an unsaturated four-carbon Criegee intermediate produced from the ozonolysis of isoprene has been recognized to play a key role in determining the tropospheric OH concentration.It exists in four configurations(anti-anti,anti-syn,synanti,and syn-syn)due to two different substituents of saturated methyl and unsaturated vinyl groups.In this study,we have carried out the electronic structure calculation at the multi-configurational CASSCF and multi-state MS-CASPT2 levels,as well as the trajectory surface-hopping nonadiabatic dynamics simulation at the CASSCF level to reveal the different fates of syn/anti configurations in photochemical process.Our results show that the dominant channel for the S1-state decay is a ring closure,isomerization to dioxirane,during which,the syn(C-O)configuration with an intramolecular hydrogen bond shows slower nonadiabatic photoisomerization.More importantly,it has been found for the first time in photochemistry of Criegee intermediate that the cooperation of two heavy groups(methyl and vinyl)leads to an evident pyramidalization of C3 atom in methyl-vinyl Criegee intermediate,which then results in two structurally-independent minimal-energy crossing points(CIs)towards the syn(C-O)and anti(C-O)sides,respectively.The preference of surface hopping for a certain CI is responsible for the different dynamics of each configuration.展开更多
Pure Cu nanowires as catalyst were prepared by electrochemical deposition and were used in CO2 hydrogenation to methanol.The active sites of the Cu based catalyst were discussed.The performance and structural developm...Pure Cu nanowires as catalyst were prepared by electrochemical deposition and were used in CO2 hydrogenation to methanol.The active sites of the Cu based catalyst were discussed.The performance and structural development of the catalyst were observed during CO2 hydrogenation.A mechanism for the deactivation of the catalyst was discussed.The key factors that affect the deactivation of the catalyst were found.Cu nanowire sample was characterized by SEM,EDS,XRD,and BET.The results show that Cu nanowires have very high sintering resistance and catalytic stability.This helps to develop high performance catalysts.The changes in the grain size,SEM morphology and catalytic properties of the sample during CO2 hydrogenation show that the migration of the Cu atoms on the surface of the Cu nanowires can occur.Continuous migration of Cu atoms and sintering of Cu grains can lead to flow blockage in gas channels.The gas channel flow blockage or the sintering of Cu grains can lead to deactivation of the catalyst.However,the shape of catalytic performance curve indicates that the main reason for the deactivation of the catalyst is the gas channel flow blockage.展开更多
We studied migratory Red-crowned cranes from 1991-2012 in order to track population dynamics and trends for these cranes over time at Shuangtaihekou,northeastern China.Our results show that the earliest arrival date o...We studied migratory Red-crowned cranes from 1991-2012 in order to track population dynamics and trends for these cranes over time at Shuangtaihekou,northeastern China.Our results show that the earliest arrival date of the Red-crowned Crane (Grus japonensis) was usually around 1 March in the spring and the latest departure date of the cranes around 8 November.The peak period for the number of cranes observed in the spring was 10-20 March over these 22 years.The staging period in the spring is about 25 days.Comparing the highest number of Red-crowned cranes observed in the spring,the migratory population was around 400 birds in the 1990s,then,increased to over 800 birds in 2000.For a short while,the population maintained itself around 600-800 birds.After that,the population started to decline,until during the most recent years,we observed around 400 birds at peak times of each season.Our results match a similar population change pattern observed in the wintering area for a western population,which has been declining since 2000.There is an urgent need to reinforce protection and management,as well as to maintain and improve the quality of their habitats.展开更多
In this paper we propose an Ising model on an infinite ladder lattice, which is made of two infinite Ising spin chains with interactions. It is essentially a quasi-one-dimessional Ising model because the length of the...In this paper we propose an Ising model on an infinite ladder lattice, which is made of two infinite Ising spin chains with interactions. It is essentially a quasi-one-dimessional Ising model because the length of the ladder lattice is infinite, while its width is finite. We investigate the phase transition and dynamic behavior of Ising model on this quasi-one-dimessional system. We use the generalized transfer matrix method to investigate the phase transition of the system. It is found that there is no nonzero temperature phase transition in this system. At the same time, we are interested in Glauber dynamics. Based on that, we obtain the time evolution of the local spin magnetization by exactly solving a set of master equations.展开更多
High resolution laser induced fluorescence, spectra of IrN in the spectral region between 394 and 520 nm were recorded using laser vaporization/reaction free jet expansion and laser induced fluorescence spectroscopy. ...High resolution laser induced fluorescence, spectra of IrN in the spectral region between 394 and 520 nm were recorded using laser vaporization/reaction free jet expansion and laser induced fluorescence spectroscopy. Seven new vibronic transition bands were observed and analyzed. Two Ω=1 and five Ω=0 new states were identified. Least squares fit of rotationally resolved transition lines yielded accurate molecular constants for the upper states. Spectra of isotopic molecules were observed, which provided confirmation for the vibrational assignment. Comparison of the observed electronic states of IrB, IrC, and IrN provides a good understanding of the chemical bonding of this group of molecules.展开更多
The boron adsorption kinetic experiment in soil by means of a flow displacement technique showed that the kinetic data could be described with some mathematic equations. The average values of the correlation coefficie...The boron adsorption kinetic experiment in soil by means of a flow displacement technique showed that the kinetic data could be described with some mathematic equations. The average values of the correlation coefficient for zero-order, first-order, parabolic diffusion, Elovich, power function and exponential equations were 0.957, 0.982, 0.981, 0.984, 0.981 and 0.902, respectively. The correlation between adsorbed boron or its other expression form and time were the highest for first-order, parabolic diffusion, Elovich, and power function equations, the second for the zeroorder equation, and the lowest for the exponential equation. The parabolic diffusion equation fitted well the experimental results, with the least standard error among the six kinetic equations, showing that the movement of boron from soil solution to soil colloid surface may be controlled by boron diffusion speed. The boron content of rape seedling obtained from soil cultivation was correlated with the rate constants of the kinetic equations. The constants of first-order, parabolic diffusion,and exponential equations were significantly correlated with the boron content of the crop of NPK treatment at a 95% probability level, with correlation coefficients being 0.686, 0.691 and 0.641, respectively. In the case of zero-order equation, it was significant at 99% probability level (r =0.736). These results showed that the absorption kinetic constants of soil boron were closely related with the rape plant response to boron.展开更多
In this paper, we propose a scheme for generating an arbitrary three-dimensional pure state of vibrational motion of a trapped ion. Our scheme is based on a sequence of laser pulses, which are tuned to the appropriate...In this paper, we propose a scheme for generating an arbitrary three-dimensional pure state of vibrational motion of a trapped ion. Our scheme is based on a sequence of laser pulses, which are tuned to the appropriate vibrational sidebands with respect to the appropriate electronic transition.展开更多
Collisional quantum interference (CQI) on rotational energy transfer was observed in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14) system in collision with Na [Chem. Phys. Lett. 318 (2000) 107], and the degree of the inter...Collisional quantum interference (CQI) on rotational energy transfer was observed in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14) system in collision with Na [Chem. Phys. Lett. 318 (2000) 107], and the degree of the interference was measured. The integral interference angle was obtaJned through theoretical calculation. We will research the factors that have effect on collisional quantum interference on rotational energy transfer in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14)-Na system. Basing on the time-dependent first order Born approximation, and taking into account the anlsotroplc Lennard Jones interaction potentials and "straight-line" trajectory approximation, we obtain the factors that have effect on CQI in Na2-Na system, and obtain the relation between the integral interference angle and rotational quantum number.展开更多
High field asymmetric wave ion mobility spectrometry (FAIMS) is a powerful tool to detect and characterize gas-phase ions, while the unsolvable partial differential equation of ions moving in ion drift tube poses a ...High field asymmetric wave ion mobility spectrometry (FAIMS) is a powerful tool to detect and characterize gas-phase ions, while the unsolvable partial differential equation of ions moving in ion drift tube poses a big challenge to FAIMS spectral peak analysis. In this work, a universal and effective model of FAIMS spectral peak profile has been proposed by introducing ion trajectory and loss height. With this model, the influence of the structure of ion drift tube, dispersion voltages, compensation voltages, and carrier gas flow rate on the FAIMS spectral peak characteristics like peak shape, full width at half maximum and peak height is analyzed and discussed. The results show that the influence of different factors on the FAIMS spectral peak profile can be qualitatively described by the model which agrees with the experimental data.展开更多
文摘The population dynamics and breeding behaviors of Black-crowned Night Herons ( Nycticorax nycticorax ), Egrets (Egtetta garzetta), Chinese Pond Herons (Ardeola bacchus) and Great Egrets (Casmerodius albus) were observed in Tanghai Wetlands, Hebei Province from August 2004 to July 2005. Further, we studied the relationship of nest space distribution and directly calculated the nest density of vertical and horizontal levels, the niche overlapping index and the niche breadth. The results showed that there were two breeding areas, named Area Ⅰ and Area Ⅱ . The maximum population occurred in the period from April to September and was approximately 5800 individuals. Area Ⅰ was occupied earlier than Area Ⅱ by approximately half a month. In the breeding period, Black-crowned Night Herons were dominant in numbers and most occupied the upper nests of the core areas. Great Egrets also took the upper nests but they have the smallest population. Most Egrets took the middle nests of the edges of the area. Chinese Pond Herons, with a smaller population than the Egret, mostly nested in the edges, but some of them also took the lower nests of the core area. On the whole, the vertical niche of Egrets is the widest, the horizontal niche of Black-crowned Night Herons is the widest and the niche breadth of Chinese Pond Herons is the largest. The nest distribution pattern is the most similar between Chinese Pond Herons and Black-crowned Night Herons, and the niche overlapping index of Chinese Pond Herons and Egrets is the largest. Black-crowned Night Herons and Great Egrets control Egrets and Chinese Pond Herons in competition. Rich food and the optimal ecological environments lead to plenty of herons in the wetlands. In addition, it is a distinguishing feature of the four species that nests are built in poplar trees over 22 m tall.
基金Project(41171361)supported by the National Natural Science Foundation of China
文摘Information on lead redistribution and speciation changes in anthrosphere can help to analyze the whole lead cycle on the earth. Lead life cycle was traced based on the concepts of anthropogenic transfer and transformation. Lead transfer and the distribution of chemical species throughout the anthropogenic flow were identified in 2010 in China. The results show that 1.85 Mt lead ore was consumed(besides 1.287 Mt imported concentrated ore and 1.39 Mt lead scraps. After undergoing transformations, 3.53 Mt lead entered end services in chemical species of Pb, Pb O2 and PbSO4, altogether accounting for over 80% of the total lead products. Finally, 2.10 Mt ore was emitted into the environment in such species as PbSO4(26%), PbO(19%) and Pb(15%). Lead transfer begins in primary raw material sectors, and then transfers to manufacturing sectors. Lead provides services mainly in such industrial sectors as transportation, electrical power and buildings or construction.
文摘The depletion rate of phosphate in the soil-root interface zone increased along with growth and phosphateuptake of wheat or maize, which indicated that the phosphate distribution in soil near the root surfaceagreed well with the phosphate movement in rhizosphere and phosphate uptake by plant. The relativeaccumulation zone of phosphate within 0.5 mm apart from the root surface developed at the 15th day or soafter cultivating wheat or maize since the root phosphate secretion increased gradually in this stage. Thephosphate distribution in the soil-root interface zone against the growing time (t) and the distance from theroot plane (x) could be described by the non-linear regression equation with the third powers of x and t.
基金Supported by the National Natural Science Foundation of China (No. 10472104).
文摘The shear-induced migration of neutrally-buoyant non-colloidal circular particles in a two-dimensional circular Couette flow is investigated numerically with a distributed Lagrange multiplier based fictitious domain method.The effects of inertia and volume fraction on the particle migration are examined.The results indicate that inertia has a negative effect on the particle migration.In consistence with the experimental observations,the rapid migration of particles near the inner cylinder at the early stage is observed in the simulation,which is believed to be related to the chain-like clustering of particles.The migration of circular particles in a plane Poiseuille flow is also examined in order to further confirm the effect of such clustering on the particle migration at early stage.There is tendency for the particles in the vicinity of outer cylinder in the Couette device to pack into concentric rings at late stage in case of high particle concentration.
文摘The fabrication and characterization of a laser ionization source for ion mobility spectrometer (IMS) is described with the calculated parameter of the drift tube. Ions are created in air at ambient pressure using laser ionization ( A = 248 nm) with air as the drift gas. Mobility spectra for positive ions at different electric fields are obtained with the length of drift tube of 25 and 50 mm, respectively. The distribution of the electric field in the drift tube (50 mm) has also been investigated by SIMION simulation with the ion shutter closed and open respectively.
基金Supported by the Foundation of Hunan Educational Committee (06C692)
文摘Objective To explore the influence of oxidized high-density lipoprotein (oxHDL) on the maturation and migration of bone marrow-derived dendritic cells (BMDCs) from C57BL/6J mice. Methods The C57BL/6J mice bone marrow cell suspension was prepared and purified. Recombinant granulocyte-macrophage colony-stimulating factor (rmGM-CSF) and recombinant interleukin-4 (rmlL-4) were used to promote monocytes to differentiate and suppress lymphocytes. Then 50μg/mL oxHDL was added to stimulate BMDCs, using 50μg/mL high-density lipoprotein (HDL) as homologous protein control, PBS as negative control, and 1 μg/mL lipopolysaccharide (LPS) as positive control. The CD86 and MHCII expression rates were detected with fluorescence-activated cell sorting (FACS). Liquid scintillation counting (LSC) was used in mixed lymphocyte reactions (MLRs) to reflect the ability of BMDCs in stimulating the proliferation of homologous T cells, Levels of cytokines IL-12 and IL-10 were detected by ELISA. The cell migration was evaluated with the transwell system. Results Compared with PBS group, the expressions of CD86 and MHCII, counts per minute of MLRs, secretion of IL-12 and IL-10, and number of migrated cells in oxHDL group and LPS group significantly increased (all P 〈 0.05), while the increment was less in oxHDL group than LPS group. The number of migrated cells in oxHDL group was about twice of that in HDL group. Conclusion OxHDL may promote the maturation and migration of BMDCs in vitro.
基金Project (60573127) supported by the National Natural Science Foundation of ChinaProject (20040533036) supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China+1 种基金Project (05JJ40131) supported by the Natural Science Foundation of Hunan Province, ChinaProject(03C326) supported by the Natural Science Foundation of Education Department of Hunan Province, China
文摘A new mobile multicast scheme called mobility prediction based mobile multicast(MPBMM) was proposed. In MPBMM, when a mobile node (MN) roams among subnets during a multicast session, MN predicts the next subnet, to which MN will attach, by the information of its position and mobility speed, consequently speeds up the handoff procedure. Simulation results show that the proposed scheme can minimize the loss of multicast packets, reduce the delay of subnet handoff, decrease the frequency of multicast tree reconfiguration, and optimize the delivery path of multicast packets. When MN moves among subnets at different speeds (from 5 to 25 ms), the maximum loss ratio of multicast packets is less than0.2%, the maximum inter-arrival time of multicast packets is 117 ms, so the proposed scheme can meet the QoS requirements of real-time services. In addition, MPBMM can support the mobility of multicast source.
基金Project supported by the National Natural Science Foundation of China (Nos. 60662003 and 60462003), the Huawei Funds for Scienceand Technology (No. YJCB2004025SP) and the Science and Tech-nology Plan of Zhejiang Province (No. 2005C21002), China
文摘Performance evaluation shows that Hierarchical Mobile IPv6 (HMIPv6) cannot outperform standard Mobile IPv6 (MIPv6) in all scenarios. Thus, adaptive protocol selection under certain circumstances is desired. Moreover, it is necessary to balance the load among different Mobility Anchor Points (MAPs). This paper proposes an efficient three-level hierarchical ar- chitecture for mobility management in HMIPv6 networks, in which a mobile node (MN) may register with either a higher/lower MAP or its home agent according to its speed and the number of connecting correspondent nodes (CNs). An admission control algorithm and a replacement algorithm are introduced to achieve load balancing between two MAP levels and among different MAPs within the same MAP level. Admission control is based on the number of CNs but not MNs that an MAP serves. In case there is no capacity for an MN, the MAP chooses an existing MN to be replaced. The replaced MN uses the MAP selection al- gorithm again to choose another mobility agent. Simulation results showed that the proposed scheme achieves better performance not only in reducing the signaling overhead, but also in load balancing among different MAPs.
基金supported by the the National Natural Science Foundation of China(No.21873060and No.21473107)the Fundamental Research Funds for the Central Universities(No.GK201901007,No.2018CBLY004)。
文摘Methyl vinyl ketone oxide,an unsaturated four-carbon Criegee intermediate produced from the ozonolysis of isoprene has been recognized to play a key role in determining the tropospheric OH concentration.It exists in four configurations(anti-anti,anti-syn,synanti,and syn-syn)due to two different substituents of saturated methyl and unsaturated vinyl groups.In this study,we have carried out the electronic structure calculation at the multi-configurational CASSCF and multi-state MS-CASPT2 levels,as well as the trajectory surface-hopping nonadiabatic dynamics simulation at the CASSCF level to reveal the different fates of syn/anti configurations in photochemical process.Our results show that the dominant channel for the S1-state decay is a ring closure,isomerization to dioxirane,during which,the syn(C-O)configuration with an intramolecular hydrogen bond shows slower nonadiabatic photoisomerization.More importantly,it has been found for the first time in photochemistry of Criegee intermediate that the cooperation of two heavy groups(methyl and vinyl)leads to an evident pyramidalization of C3 atom in methyl-vinyl Criegee intermediate,which then results in two structurally-independent minimal-energy crossing points(CIs)towards the syn(C-O)and anti(C-O)sides,respectively.The preference of surface hopping for a certain CI is responsible for the different dynamics of each configuration.
基金Project(51074205)supported by the National Natural Science Foundation of China
文摘Pure Cu nanowires as catalyst were prepared by electrochemical deposition and were used in CO2 hydrogenation to methanol.The active sites of the Cu based catalyst were discussed.The performance and structural development of the catalyst were observed during CO2 hydrogenation.A mechanism for the deactivation of the catalyst was discussed.The key factors that affect the deactivation of the catalyst were found.Cu nanowire sample was characterized by SEM,EDS,XRD,and BET.The results show that Cu nanowires have very high sintering resistance and catalytic stability.This helps to develop high performance catalysts.The changes in the grain size,SEM morphology and catalytic properties of the sample during CO2 hydrogenation show that the migration of the Cu atoms on the surface of the Cu nanowires can occur.Continuous migration of Cu atoms and sintering of Cu grains can lead to flow blockage in gas channels.The gas channel flow blockage or the sintering of Cu grains can lead to deactivation of the catalyst.However,the shape of catalytic performance curve indicates that the main reason for the deactivation of the catalyst is the gas channel flow blockage.
文摘We studied migratory Red-crowned cranes from 1991-2012 in order to track population dynamics and trends for these cranes over time at Shuangtaihekou,northeastern China.Our results show that the earliest arrival date of the Red-crowned Crane (Grus japonensis) was usually around 1 March in the spring and the latest departure date of the cranes around 8 November.The peak period for the number of cranes observed in the spring was 10-20 March over these 22 years.The staging period in the spring is about 25 days.Comparing the highest number of Red-crowned cranes observed in the spring,the migratory population was around 400 birds in the 1990s,then,increased to over 800 birds in 2000.For a short while,the population maintained itself around 600-800 birds.After that,the population started to decline,until during the most recent years,we observed around 400 birds at peak times of each season.Our results match a similar population change pattern observed in the wintering area for a western population,which has been declining since 2000.There is an urgent need to reinforce protection and management,as well as to maintain and improve the quality of their habitats.
文摘In this paper we propose an Ising model on an infinite ladder lattice, which is made of two infinite Ising spin chains with interactions. It is essentially a quasi-one-dimessional Ising model because the length of the ladder lattice is infinite, while its width is finite. We investigate the phase transition and dynamic behavior of Ising model on this quasi-one-dimessional system. We use the generalized transfer matrix method to investigate the phase transition of the system. It is found that there is no nonzero temperature phase transition in this system. At the same time, we are interested in Glauber dynamics. Based on that, we obtain the time evolution of the local spin magnetization by exactly solving a set of master equations.
文摘High resolution laser induced fluorescence, spectra of IrN in the spectral region between 394 and 520 nm were recorded using laser vaporization/reaction free jet expansion and laser induced fluorescence spectroscopy. Seven new vibronic transition bands were observed and analyzed. Two Ω=1 and five Ω=0 new states were identified. Least squares fit of rotationally resolved transition lines yielded accurate molecular constants for the upper states. Spectra of isotopic molecules were observed, which provided confirmation for the vibrational assignment. Comparison of the observed electronic states of IrB, IrC, and IrN provides a good understanding of the chemical bonding of this group of molecules.
文摘The boron adsorption kinetic experiment in soil by means of a flow displacement technique showed that the kinetic data could be described with some mathematic equations. The average values of the correlation coefficient for zero-order, first-order, parabolic diffusion, Elovich, power function and exponential equations were 0.957, 0.982, 0.981, 0.984, 0.981 and 0.902, respectively. The correlation between adsorbed boron or its other expression form and time were the highest for first-order, parabolic diffusion, Elovich, and power function equations, the second for the zeroorder equation, and the lowest for the exponential equation. The parabolic diffusion equation fitted well the experimental results, with the least standard error among the six kinetic equations, showing that the movement of boron from soil solution to soil colloid surface may be controlled by boron diffusion speed. The boron content of rape seedling obtained from soil cultivation was correlated with the rate constants of the kinetic equations. The constants of first-order, parabolic diffusion,and exponential equations were significantly correlated with the boron content of the crop of NPK treatment at a 95% probability level, with correlation coefficients being 0.686, 0.691 and 0.641, respectively. In the case of zero-order equation, it was significant at 99% probability level (r =0.736). These results showed that the absorption kinetic constants of soil boron were closely related with the rape plant response to boron.
基金Supported by Key Program of National Natural Science Foundation of China under Grant No. 60931002National Natural Science Foundation of China under Grant No.10704001+3 种基金Anhui Provincial Natural Science Foundation under Grant No. 070412060the Major Program of the Education Department of Anhui Province under Grant No. KJ2010ZD08the Key Program of the Education Department of Anhui Province under Grant No. KJ2010A287the Personal Development Foundation of Anhui Province under Grant No. 2009Z022
文摘In this paper, we propose a scheme for generating an arbitrary three-dimensional pure state of vibrational motion of a trapped ion. Our scheme is based on a sequence of laser pulses, which are tuned to the appropriate vibrational sidebands with respect to the appropriate electronic transition.
基金The project supported by National Natural Science Foundation of China under Grant No. 10374040
文摘Collisional quantum interference (CQI) on rotational energy transfer was observed in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14) system in collision with Na [Chem. Phys. Lett. 318 (2000) 107], and the degree of the interference was measured. The integral interference angle was obtaJned through theoretical calculation. We will research the factors that have effect on collisional quantum interference on rotational energy transfer in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14)-Na system. Basing on the time-dependent first order Born approximation, and taking into account the anlsotroplc Lennard Jones interaction potentials and "straight-line" trajectory approximation, we obtain the factors that have effect on CQI in Na2-Na system, and obtain the relation between the integral interference angle and rotational quantum number.
基金This work was supported by the National Natural Science Foundation of China (No.60871037 andNo.61004133) and the Innovation and Technology Fund of Hefei Institutes of Physical Science.
文摘High field asymmetric wave ion mobility spectrometry (FAIMS) is a powerful tool to detect and characterize gas-phase ions, while the unsolvable partial differential equation of ions moving in ion drift tube poses a big challenge to FAIMS spectral peak analysis. In this work, a universal and effective model of FAIMS spectral peak profile has been proposed by introducing ion trajectory and loss height. With this model, the influence of the structure of ion drift tube, dispersion voltages, compensation voltages, and carrier gas flow rate on the FAIMS spectral peak characteristics like peak shape, full width at half maximum and peak height is analyzed and discussed. The results show that the influence of different factors on the FAIMS spectral peak profile can be qualitatively described by the model which agrees with the experimental data.