Diurnal minor and trace elements in glacial outflow water draining the Qiyi Glacier and associated hydrological controls as well as the filtration effects on water chemistry were examined. Results show that major ions...Diurnal minor and trace elements in glacial outflow water draining the Qiyi Glacier and associated hydrological controls as well as the filtration effects on water chemistry were examined. Results show that major ions, Li, St, and Ba are exported pre- dominately as mobile monovalent or divalent ions and are controlled by hydrological variations over the diurnal cycle exhibit- ing an inverse concentration with discharge, suggesting that Li, Sr, and Ba can be used as tracers in subglacial hydrological investigations. Conversely, other elements （e.g. Fe, Al, and Cr） exhibit variations that are not strongly correlated with the dis- charge reflecting the physicochemical controls. The non-filtered operation appears not to strongly influence Sr and Ba, but has an effect on some elements such as Fe, Al, V, Ti, and Co, indicating that these changed elements are transported in particulate forms and thus their concentrations are highly dependent on particulate numbers in solutions. This implies that the immediate filtration after sampling is essential in hydrochemical studies at Alpine glacial basins due to subsequent mineral dissolution.展开更多
基金supportedby Key Program of National Natural Science Foundation of China (Grant No. 41030527)Hundred Talents Program of the Chinese Academy of Sciences (Grant No. 0827611002)+4 种基金West Light Program for Talent Cultiration of Chinese Academy of Sciences (CAS), Open Foundation of SKLCS, CAS (Grant No. SKLCS09-04)China Postdoctoral Science Foundation (Grant No. 20110490062)Indenendent Program of SKLCS,CAS (Grant No. SKLCS-ZZ-2012-02-01)National Natural Science Foundation of China (Grant Nos. 40930526 and 40771046)Foundation for Excellent Youth Scholars of CAREERI, CAS
文摘Diurnal minor and trace elements in glacial outflow water draining the Qiyi Glacier and associated hydrological controls as well as the filtration effects on water chemistry were examined. Results show that major ions, Li, St, and Ba are exported pre- dominately as mobile monovalent or divalent ions and are controlled by hydrological variations over the diurnal cycle exhibit- ing an inverse concentration with discharge, suggesting that Li, Sr, and Ba can be used as tracers in subglacial hydrological investigations. Conversely, other elements （e.g. Fe, Al, and Cr） exhibit variations that are not strongly correlated with the dis- charge reflecting the physicochemical controls. The non-filtered operation appears not to strongly influence Sr and Ba, but has an effect on some elements such as Fe, Al, V, Ti, and Co, indicating that these changed elements are transported in particulate forms and thus their concentrations are highly dependent on particulate numbers in solutions. This implies that the immediate filtration after sampling is essential in hydrochemical studies at Alpine glacial basins due to subsequent mineral dissolution.
