Isothermal and non-isothermal gasification kinetics of coal char were investigated by using thermogravimetric analysis(TGA) in CO2 atmosphere, and the experimental data were interpreted with the aids of random pore mo...Isothermal and non-isothermal gasification kinetics of coal char were investigated by using thermogravimetric analysis(TGA) in CO2 atmosphere, and the experimental data were interpreted with the aids of random pore model(RPM), unreacted shrinking core model(URCM) and volume model(VM). With the increase of heating rate, gasification curve moves into high temperature zone and peak rate of gasification increases; with the increase of gasification temperature, gasification rate increases and the total time of gasification is shortened. The increase of both heating rate and gasification temperature could improve gasification process of coal char. Kinetics analysis indicates that experimental data agree better with the RPM than with the other two models. The apparent activation energy of non-isothermal and isothermal gasification of coal char using RPM is 193.9 k J/mol and 212.6 k J/mol respectively, which are in accordance with reported data. Gasification process of coal char under different heating rates and different temperatures are predicted by the RPM derived in this study, and it is found that the RPM predicts the reaction process satisfactorily.展开更多
By testing the temperature of the coal and the stress of the working surface, we got the variation law of coal temperature and coal stress during the excavation. The result shows that the activities of mining affect t...By testing the temperature of the coal and the stress of the working surface, we got the variation law of coal temperature and coal stress during the excavation. The result shows that the activities of mining affect the coal temperature, the fluctuation of coal temperature and the coal stress is synchronous. During the smooth change of crustal stress, the coal temperature basically keeps unchanged, when the dynamic phenomenon appears, the coal temperature changes, as well the coal stress. Therefore, we can use the online coal temperature monitoring system to test the coal temperature of the working surface continuously, and it can provide basic information for forecasting coal mine power disaster before it happens.展开更多
The tribological properties of ZrO2 ceramic and 1Cr18Ni9Ti stainless steel rubbing pairs were investigated using a special tribo-tester under different concentrations of hydrogen peroxide (H2O2) solution.The compariso...The tribological properties of ZrO2 ceramic and 1Cr18Ni9Ti stainless steel rubbing pairs were investigated using a special tribo-tester under different concentrations of hydrogen peroxide (H2O2) solution.The comparison analyses of the friction coefficients,worn volume rates,worn particles and surface roughness were conducted under the tested conditions.There were significant differences of the tribological properties of the rubbing pairs in the different concentrations H2O2 solution because of oxidation and corrosion.This research has revealed that the main wear mechanisms between the rubbing pairs are severe adhesive wear,abrasive wear and corrosive wear in the H2O2 solution with different concentrations.A model has been established to assess the most suitable concentration of the H2O2 solution for the tribological properties of the rubbing pairs.The result shows that 50% concentration of the H2O2 solution is the most suitable.The assessment result is consistent with the experimental result.It is believed that the knowledge gained in this study is useful for the optimization of the friction pairs in the extreme condition.展开更多
基金supported by the National Science Foundation of China & Baosteel under Grant (No. 51134008)the National Key Technology R&D Program in the 12th Five year Plan of China (No. 2011BAC01B02)
文摘Isothermal and non-isothermal gasification kinetics of coal char were investigated by using thermogravimetric analysis(TGA) in CO2 atmosphere, and the experimental data were interpreted with the aids of random pore model(RPM), unreacted shrinking core model(URCM) and volume model(VM). With the increase of heating rate, gasification curve moves into high temperature zone and peak rate of gasification increases; with the increase of gasification temperature, gasification rate increases and the total time of gasification is shortened. The increase of both heating rate and gasification temperature could improve gasification process of coal char. Kinetics analysis indicates that experimental data agree better with the RPM than with the other two models. The apparent activation energy of non-isothermal and isothermal gasification of coal char using RPM is 193.9 k J/mol and 212.6 k J/mol respectively, which are in accordance with reported data. Gasification process of coal char under different heating rates and different temperatures are predicted by the RPM derived in this study, and it is found that the RPM predicts the reaction process satisfactorily.
文摘By testing the temperature of the coal and the stress of the working surface, we got the variation law of coal temperature and coal stress during the excavation. The result shows that the activities of mining affect the coal temperature, the fluctuation of coal temperature and the coal stress is synchronous. During the smooth change of crustal stress, the coal temperature basically keeps unchanged, when the dynamic phenomenon appears, the coal temperature changes, as well the coal stress. Therefore, we can use the online coal temperature monitoring system to test the coal temperature of the working surface continuously, and it can provide basic information for forecasting coal mine power disaster before it happens.
基金supported by the Key Basic Research Program of China(Grant No.2007CB607603)the Program for New Century Excellent Talents in University(Grant No.NCET-12-0910)
文摘The tribological properties of ZrO2 ceramic and 1Cr18Ni9Ti stainless steel rubbing pairs were investigated using a special tribo-tester under different concentrations of hydrogen peroxide (H2O2) solution.The comparison analyses of the friction coefficients,worn volume rates,worn particles and surface roughness were conducted under the tested conditions.There were significant differences of the tribological properties of the rubbing pairs in the different concentrations H2O2 solution because of oxidation and corrosion.This research has revealed that the main wear mechanisms between the rubbing pairs are severe adhesive wear,abrasive wear and corrosive wear in the H2O2 solution with different concentrations.A model has been established to assess the most suitable concentration of the H2O2 solution for the tribological properties of the rubbing pairs.The result shows that 50% concentration of the H2O2 solution is the most suitable.The assessment result is consistent with the experimental result.It is believed that the knowledge gained in this study is useful for the optimization of the friction pairs in the extreme condition.
