Elemental mercury（Hg^0）re-emissions from slurries and solutions were evaluated in a lab-scale simulated scrubber.Oxidized mercury（Hg^2 ＋）standard solution was injected into the simulated scrubber at a desired rat...Elemental mercury（Hg^0）re-emissions from slurries and solutions were evaluated in a lab-scale simulated scrubber.Oxidized mercury（Hg^2 ＋）standard solution was injected into the simulated scrubber at a desired rate to simulate absorbing and dissolving of Hg^2 ＋in the flue gas across wet flue gas desulfurization（WFGD）systems. PS analytical mercury analyzer was used to continuously determine Hg0re-emission concentrations in the carrier gas from the scrubber.Sulfite ion in the slurry of CaSO3 was validated to reduce Hg ^2＋to Hg^ 0,while no Hg ^0 re-emission occurred from slurries of CaSO4 and CaO.Transitional metal ions with low chemical valence such as Fe^2 ＋,Pb ^2＋,Ni ^2＋, AsO2^-and Cu ^＋were used to prepare solutions with concentration levels of mmol·L^-1.Reduction reaction of Hg^2 ＋to Hg 0was observed from these solutions.Reduction capabilities for the different transitional metal ions in the solutions were：Pb^2 ＋〉Cu ^＋〉Fe^ 2＋〉 AsO2^-〉Ni ^2＋.展开更多
基金Supported by the US Agency for International Development(USAID)cooperation agreement(486-A-00-06-000140-00)
文摘Elemental mercury（Hg^0）re-emissions from slurries and solutions were evaluated in a lab-scale simulated scrubber.Oxidized mercury（Hg^2 ＋）standard solution was injected into the simulated scrubber at a desired rate to simulate absorbing and dissolving of Hg^2 ＋in the flue gas across wet flue gas desulfurization（WFGD）systems. PS analytical mercury analyzer was used to continuously determine Hg0re-emission concentrations in the carrier gas from the scrubber.Sulfite ion in the slurry of CaSO3 was validated to reduce Hg ^2＋to Hg^ 0,while no Hg ^0 re-emission occurred from slurries of CaSO4 and CaO.Transitional metal ions with low chemical valence such as Fe^2 ＋,Pb ^2＋,Ni ^2＋, AsO2^-and Cu ^＋were used to prepare solutions with concentration levels of mmol·L^-1.Reduction reaction of Hg^2 ＋to Hg 0was observed from these solutions.Reduction capabilities for the different transitional metal ions in the solutions were：Pb^2 ＋〉Cu ^＋〉Fe^ 2＋〉 AsO2^-〉Ni ^2＋.
