The woodland-steppe ecotone in the. southern Nei Mongol Plateau is located at the northern edge of the east Asian monsoon influences. A marked southeastern - northwestern (SE - NW) precipitation gradient exists in thi...The woodland-steppe ecotone in the. southern Nei Mongol Plateau is located at the northern edge of the east Asian monsoon influences. A marked southeastern - northwestern (SE - NW) precipitation gradient exists in this region. Quantitative reconstruction of palaeo-precipitation of this region is helpful to reveal the development of monsoon climate and to predict die future desertification. Based on modern vegetation and surface pollen studies, a pollen-precipitation transfer function in the study region was established. Pollen data from three sediment sequences within the ecotone were used to reconstruct palaeo-precipitation during the Holocene. The processes of precipitation changes in the three sequences were quite different. There was a tendency of precipitation declined from the onset of the Holocene to 1 100 a BP in Haoluku. But, in Liuzhouwan and Xiaoniuchang, both located south of Haoluku, the annual precipitation reached highest values during 7 800 - 6 200 a BP and 7 200 - 5 000 a BP, respectively. The influences of southwestern (SW) monsoon and the variances of topographical conditions have possibly caused these temporal-spatial variances.展开更多
The reaction of C3H8＋O（^3p）→C3HT＋OH is investigated using ab initio calculation and dynamical methods. Electronic structure calculations for all stationary points are obtained using a dual-level strategy. The geo...The reaction of C3H8＋O（^3p）→C3HT＋OH is investigated using ab initio calculation and dynamical methods. Electronic structure calculations for all stationary points are obtained using a dual-level strategy. The geometry optimization is performed using the unrestricted second-order Moller-Plesset perturbation method and the single-point energy is computed us- ing the coupled-cluster singles and doubles augmented by a perturbative treatment of triple excitations method. Results indicate that the main reaction channel is C3Hs＋O（^3p）→i- C3HT＋OH. Based upon the ab initio data, thermal rate constants are calculated using the variational transition state theory method with the temperature ranging from 298 K to 1000 K. These calculated rate constants are in better agreement with experiments than those reported in previous theoretical studies, and the branching ratios of the reaction are also calculated in the present work. Furthermore, the isotope effects of the title reaction are calculated and discussed. The present work reveals the reaction mechanism of hydrogenabstraction from propane involving reaction channel competitions is helpful for the understanding of propane combustion.展开更多
The potential energy surfaces （PES） of unimolecular dissociation reactions for di-ethyl beryl- lium and di-t-butyl beryllium are investigated by B3LYP, CCSD（T）, and G3B3 approaches. Possible reaction pathways thro...The potential energy surfaces （PES） of unimolecular dissociation reactions for di-ethyl beryl- lium and di-t-butyl beryllium are investigated by B3LYP, CCSD（T）, and G3B3 approaches. Possible reaction pathways through either the radical or transition state （TS） of the molecules are considered. The geometries, vibrational frequencies and relative energies for various sta- tionary points are determined. From the study of energetics, the TS pathways arising from concerted molecular eliminations are indicated to be the main dissociation pathways for both molecules. The PES differences of the dissociation reactions are investigated. The activation energies and rate constants will be helpful for investigating the predictive ability of the reaction in further theoretical and experimental research.展开更多
The results of this study prove that there is significant troposphere biennial oscillation(TBO) in the South Asian climate, especially with the Indian summer monsoon rainfall. In order to explore the mechanism of TBO ...The results of this study prove that there is significant troposphere biennial oscillation(TBO) in the South Asian climate, especially with the Indian summer monsoon rainfall. In order to explore the mechanism of TBO in the South Asian region, we defined a unified South Asian monsoon index to depict South Asian summer monsoon(SASM) and South Asian winter monsoon(SAWM) and the transition features between SASM and SAWM. Through further analysis, the connection between the abnormity of SASM and SAWM was discovered. Normally, a strong SAWM is beneficial for a weak SASM later, while a weak SAWM favors a strong SASM. Meanwhile, a strong SASM is favorable for a weak SAWM and a weak SAWM always happens after a weak SASM. Such results suggest the evolution of the South Asian monsoon, which may be an important mechanism to excite TBO in South Asia.展开更多
A non-equilibrium model of multicomponent melt solidification has been developed in which a Stefan problem with two boundaries is solved numerically, the boundaries being between the solid phase and the two-phase tran...A non-equilibrium model of multicomponent melt solidification has been developed in which a Stefan problem with two boundaries is solved numerically, the boundaries being between the solid phase and the two-phase transition zone and between the two-phase transition zone and the liquid phase. The two-phase zone is represented as a porous medium with variable porosity. The additional force resisting the melt flow due to porosity and introduced by analogy with Darcy＇s law is taken into account. Computer simulation has been performed of the experiment on Sn-20 wt.%Pb binary alloy solidification by the method of downward-directed crystallization along the gravity vector. The paper shows the results of a quasi two-dimensional benchmark experiment on horizontal （i.e., at the right angle to the gravity vector） directional solidification of a binary Sn-3 wt.%Pb alloy. The calculations were done using two crystallization models： the equilibrium model and the non-equilibrium one. It is shown that the non-equilibrium model gives a better description of the thermal field evolution and solute distribution caused by natural convection.展开更多
Starting from famous Schrodinger equation within the framework of semi-c/assicai theory of light-matter interaction, we firstly obtain the anaiytical non-resonant solutions of the driven bipartite system＇s entangleme...Starting from famous Schrodinger equation within the framework of semi-c/assicai theory of light-matter interaction, we firstly obtain the anaiytical non-resonant solutions of the driven bipartite system＇s entanglement dynamics in independent and coherent double pathways. Numerical simulations show that under non-resonant condition, entanglement sudden death and revival between these transition patterns behave quite differently, indicating the utmost importance of transition pathways＇ interference. Furthermore, the laser pulse＇s area and detuning exert significant but quite distinct influences on the entanglement dynamics. Our analyses are helpful in manipulating entanglement in current experimental technology.展开更多
High temperature treatment of tungsten alloy of W-5wt.% TM （transition metals, TM = Ni, Fe, Cu, Co） nanopowder was run under different temperatures to cover the oxidation rate at different temperatures. The correlat...High temperature treatment of tungsten alloy of W-5wt.% TM （transition metals, TM = Ni, Fe, Cu, Co） nanopowder was run under different temperatures to cover the oxidation rate at different temperatures. The correlation was developed for certain temperatures to find an equation for the relation between time and weight. The thermal treatment was done for different quantities at certain times. The proposed equation studies the correlation between temperature, time, and weight. For each temperature, a number of points were recorded from the measured oxidation curve. The shape of the curves is well-represented in this paper. The final results will present the highest temperature, the maximum weight, and the maximum time for full oxidation at high and low temperatures.展开更多
We constructed a single C-Bezier curve with a shape parameter for G^2 joining two circular arcs. It was shown that an S-shaped transition curve, which is able to manage a broader scope about two circle radii than the ...We constructed a single C-Bezier curve with a shape parameter for G^2 joining two circular arcs. It was shown that an S-shaped transition curve, which is able to manage a broader scope about two circle radii than the Bezier curves, has no curvature extrema, while a C-shaped transition curve has a single curvature extremum. Regarding the two kinds of curves, specific algorithms were presented in detail, strict mathematical proofs were given, and the effectiveness of the method was shown by examples This method has the following three advantages： （1） the pattern is unified; （2） the parameter able to adjust the shape of the transition curve is available; （3） the transition curve is only a single segment, and the algorithm can be formulated as a low order equation to be solved for its positive root. These advantages make the method simple and easy to implement.展开更多
The determination of volume fraction of interracial transition zone （ITZ） is very important for investigating the quantitative relationship between the microstructure and macroscopical property of concrete. In this ...The determination of volume fraction of interracial transition zone （ITZ） is very important for investigating the quantitative relationship between the microstructure and macroscopical property of concrete. In this paper, based on Lu and Torquato＇s most nearest surface distribution function, a calculating process of volume fraction of ITZ is given in detail according to the actual sieve curve in concrete. Then, quantitative formulas are put forward to measure the influencing factors on the ｜TZ vol- ume fraction. In order to validate the given model, the volume fractions of ITZ obtained by numerical calculation are compared with those by computer simulation. The results show that the two are in good agreement. The order of the factors influencing the ITZ volume fraction is the ITZ thickness, the volume fraction of aggregate and the maximum aggregate diameter for Fuller gradation in turn. The 1TZ volume fraction obtained from the equal volume fraction （EVF） gradation is always larger than that from the Fuller gradation for a given volume fraction of aggregate.展开更多
Integrability plays a central role in solving many body problems in physics. The explicit construction of the Jack polynomials is an essential ingredient in solving the Calogero–Sutherland model, which is a one-dimen...Integrability plays a central role in solving many body problems in physics. The explicit construction of the Jack polynomials is an essential ingredient in solving the Calogero–Sutherland model, which is a one-dimensional integrable system. Starting from a special class of the Jack polynomials associated to the hook Young diagram, we find a systematic way in the explicit construction of the transition coefficients in the power-sum basis, which is closely related to a set of mutually commuting operators, i.e. the conserved charges.展开更多
The aim of this paper is to predict the phenomenon of laminar separation, transition and reattachment in a low-pressure turbine （LPT）. Self-developed large eddy simulation program of compressible N-S equations was u...The aim of this paper is to predict the phenomenon of laminar separation, transition and reattachment in a low-pressure turbine （LPT）. Self-developed large eddy simulation program of compressible N-S equations was used to describe the flow structures of T 106A LPT blade profile at Reynolds number of 1.1×10^5 based on the exit isentropic velocity and chord length. The com- putational results show the distributions of time-averaged wall-static pressure coefficient and mean skin-friction coefficient on the blade surface. The locations of laminar separation and reattachment points occur around 87% and 98% axial chord, which agree well with experiment data. The two-dimensional shear layer is gradually unstable along the downstream half of the suc- tion side as a result of the spanwise fluctuation and the roll up of shear layer via Kelvin-Helmholtz （KH） instability. Three-dimensional motions appear near 84% axial chord which later triggers spanwise vortexes and streamwise vortexes, leading to transition to turbulence in the separation bubble. Through introducing the concept of dissipation function, the high loss mainly comes from the places where strong shear layer and intense fluctuation exist. Furthermore, the separation region is only an accumulation center of the low-energy fluid rather than an area of loss source.展开更多
Curve and surface blending is an important operation in CAD systems, in which a non-uniform rational B-spline （NURBS） has been used as the de facto standard. In local comer blending, two curves intersecting at that ...Curve and surface blending is an important operation in CAD systems, in which a non-uniform rational B-spline （NURBS） has been used as the de facto standard. In local comer blending, two curves intersecting at that comer are first made disjoint, and then the third blending curve is added-in to smoothly join the two curves with G^1- or G^2-continuity. In this paper we present a study to solve the joint problem based on curve extension. The following nice properties of this extension algorithm are exploited in depth： （1） The parameterization of the original shapes does not change; （2） No additional fragments are created. Various examples are presented to demonstrate that our solution is simple and efficient.展开更多
文摘The woodland-steppe ecotone in the. southern Nei Mongol Plateau is located at the northern edge of the east Asian monsoon influences. A marked southeastern - northwestern (SE - NW) precipitation gradient exists in this region. Quantitative reconstruction of palaeo-precipitation of this region is helpful to reveal the development of monsoon climate and to predict die future desertification. Based on modern vegetation and surface pollen studies, a pollen-precipitation transfer function in the study region was established. Pollen data from three sediment sequences within the ecotone were used to reconstruct palaeo-precipitation during the Holocene. The processes of precipitation changes in the three sequences were quite different. There was a tendency of precipitation declined from the onset of the Holocene to 1 100 a BP in Haoluku. But, in Liuzhouwan and Xiaoniuchang, both located south of Haoluku, the annual precipitation reached highest values during 7 800 - 6 200 a BP and 7 200 - 5 000 a BP, respectively. The influences of southwestern (SW) monsoon and the variances of topographical conditions have possibly caused these temporal-spatial variances.
文摘The reaction of C3H8＋O（^3p）→C3HT＋OH is investigated using ab initio calculation and dynamical methods. Electronic structure calculations for all stationary points are obtained using a dual-level strategy. The geometry optimization is performed using the unrestricted second-order Moller-Plesset perturbation method and the single-point energy is computed us- ing the coupled-cluster singles and doubles augmented by a perturbative treatment of triple excitations method. Results indicate that the main reaction channel is C3Hs＋O（^3p）→i- C3HT＋OH. Based upon the ab initio data, thermal rate constants are calculated using the variational transition state theory method with the temperature ranging from 298 K to 1000 K. These calculated rate constants are in better agreement with experiments than those reported in previous theoretical studies, and the branching ratios of the reaction are also calculated in the present work. Furthermore, the isotope effects of the title reaction are calculated and discussed. The present work reveals the reaction mechanism of hydrogenabstraction from propane involving reaction channel competitions is helpful for the understanding of propane combustion.
基金ACKNOWLEDGMENTS This work was supported by the NationM Nature Science Foundation of China （No.11104256） and the Open Project of State Key Laboratory Cultivation base for Nonmetal Composites and Functional Mate- rials （No.11zxfk19）. We thank Dr. Shuang-lin Hu from the Chemistry Department of Uppsala University in Sweden for helpful suggestion. We would also thank the Hefei National Laboratory for Physical Sciences at the Microscale in University of Science and Technology of China for the computational facilities （Gaussian 09）.
文摘The potential energy surfaces （PES） of unimolecular dissociation reactions for di-ethyl beryl- lium and di-t-butyl beryllium are investigated by B3LYP, CCSD（T）, and G3B3 approaches. Possible reaction pathways through either the radical or transition state （TS） of the molecules are considered. The geometries, vibrational frequencies and relative energies for various sta- tionary points are determined. From the study of energetics, the TS pathways arising from concerted molecular eliminations are indicated to be the main dissociation pathways for both molecules. The PES differences of the dissociation reactions are investigated. The activation energies and rate constants will be helpful for investigating the predictive ability of the reaction in further theoretical and experimental research.
基金National Natural Science Foundation of China(U0833602)National Grand Fundamental Research 973 Program of China(2010CB950400)
文摘The results of this study prove that there is significant troposphere biennial oscillation(TBO) in the South Asian climate, especially with the Indian summer monsoon rainfall. In order to explore the mechanism of TBO in the South Asian region, we defined a unified South Asian monsoon index to depict South Asian summer monsoon(SASM) and South Asian winter monsoon(SAWM) and the transition features between SASM and SAWM. Through further analysis, the connection between the abnormity of SASM and SAWM was discovered. Normally, a strong SAWM is beneficial for a weak SASM later, while a weak SAWM favors a strong SASM. Meanwhile, a strong SASM is favorable for a weak SAWM and a weak SAWM always happens after a weak SASM. Such results suggest the evolution of the South Asian monsoon, which may be an important mechanism to excite TBO in South Asia.
文摘A non-equilibrium model of multicomponent melt solidification has been developed in which a Stefan problem with two boundaries is solved numerically, the boundaries being between the solid phase and the two-phase transition zone and between the two-phase transition zone and the liquid phase. The two-phase zone is represented as a porous medium with variable porosity. The additional force resisting the melt flow due to porosity and introduced by analogy with Darcy＇s law is taken into account. Computer simulation has been performed of the experiment on Sn-20 wt.%Pb binary alloy solidification by the method of downward-directed crystallization along the gravity vector. The paper shows the results of a quasi two-dimensional benchmark experiment on horizontal （i.e., at the right angle to the gravity vector） directional solidification of a binary Sn-3 wt.%Pb alloy. The calculations were done using two crystallization models： the equilibrium model and the non-equilibrium one. It is shown that the non-equilibrium model gives a better description of the thermal field evolution and solute distribution caused by natural convection.
基金Supported by the National Basic Research Program(973 Program)of China under Grant No.2012CB921900the National Natural Science Foundation of China under Grant No.10574166the Guangdong Natural Science Foundation under Grant No.8151027501000062
文摘Starting from famous Schrodinger equation within the framework of semi-c/assicai theory of light-matter interaction, we firstly obtain the anaiytical non-resonant solutions of the driven bipartite system＇s entanglement dynamics in independent and coherent double pathways. Numerical simulations show that under non-resonant condition, entanglement sudden death and revival between these transition patterns behave quite differently, indicating the utmost importance of transition pathways＇ interference. Furthermore, the laser pulse＇s area and detuning exert significant but quite distinct influences on the entanglement dynamics. Our analyses are helpful in manipulating entanglement in current experimental technology.
文摘High temperature treatment of tungsten alloy of W-5wt.% TM （transition metals, TM = Ni, Fe, Cu, Co） nanopowder was run under different temperatures to cover the oxidation rate at different temperatures. The correlation was developed for certain temperatures to find an equation for the relation between time and weight. The thermal treatment was done for different quantities at certain times. The proposed equation studies the correlation between temperature, time, and weight. For each temperature, a number of points were recorded from the measured oxidation curve. The shape of the curves is well-represented in this paper. The final results will present the highest temperature, the maximum weight, and the maximum time for full oxidation at high and low temperatures.
基金supported by the National Natural Science Foundation ofChina (No. 60673031)the National Basic Research Program(973) of China (No. 2004CB719400)
文摘We constructed a single C-Bezier curve with a shape parameter for G^2 joining two circular arcs. It was shown that an S-shaped transition curve, which is able to manage a broader scope about two circle radii than the Bezier curves, has no curvature extrema, while a C-shaped transition curve has a single curvature extremum. Regarding the two kinds of curves, specific algorithms were presented in detail, strict mathematical proofs were given, and the effectiveness of the method was shown by examples This method has the following three advantages： （1） the pattern is unified; （2） the parameter able to adjust the shape of the transition curve is available; （3） the transition curve is only a single segment, and the algorithm can be formulated as a low order equation to be solved for its positive root. These advantages make the method simple and easy to implement.
基金supported by the National Basic Research Program of China ("973" Project) (Grant No. 2009CB623200)the National High-Tech Research and Development Program of China ("863" Project)(Grant No. 2008AA030794)
文摘The determination of volume fraction of interracial transition zone （ITZ） is very important for investigating the quantitative relationship between the microstructure and macroscopical property of concrete. In this paper, based on Lu and Torquato＇s most nearest surface distribution function, a calculating process of volume fraction of ITZ is given in detail according to the actual sieve curve in concrete. Then, quantitative formulas are put forward to measure the influencing factors on the ｜TZ vol- ume fraction. In order to validate the given model, the volume fractions of ITZ obtained by numerical calculation are compared with those by computer simulation. The results show that the two are in good agreement. The order of the factors influencing the ITZ volume fraction is the ITZ thickness, the volume fraction of aggregate and the maximum aggregate diameter for Fuller gradation in turn. The 1TZ volume fraction obtained from the equal volume fraction （EVF） gradation is always larger than that from the Fuller gradation for a given volume fraction of aggregate.
基金Supported by National Natural Science Foundation of China under Grant No.11035008
文摘Integrability plays a central role in solving many body problems in physics. The explicit construction of the Jack polynomials is an essential ingredient in solving the Calogero–Sutherland model, which is a one-dimensional integrable system. Starting from a special class of the Jack polynomials associated to the hook Young diagram, we find a systematic way in the explicit construction of the transition coefficients in the power-sum basis, which is closely related to a set of mutually commuting operators, i.e. the conserved charges.
基金supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(Grant No.51121004)the National Natural Science Foundation of China(Grant No.50976026)
文摘The aim of this paper is to predict the phenomenon of laminar separation, transition and reattachment in a low-pressure turbine （LPT）. Self-developed large eddy simulation program of compressible N-S equations was used to describe the flow structures of T 106A LPT blade profile at Reynolds number of 1.1×10^5 based on the exit isentropic velocity and chord length. The com- putational results show the distributions of time-averaged wall-static pressure coefficient and mean skin-friction coefficient on the blade surface. The locations of laminar separation and reattachment points occur around 87% and 98% axial chord, which agree well with experiment data. The two-dimensional shear layer is gradually unstable along the downstream half of the suc- tion side as a result of the spanwise fluctuation and the roll up of shear layer via Kelvin-Helmholtz （KH） instability. Three-dimensional motions appear near 84% axial chord which later triggers spanwise vortexes and streamwise vortexes, leading to transition to turbulence in the separation bubble. Through introducing the concept of dissipation function, the high loss mainly comes from the places where strong shear layer and intense fluctuation exist. Furthermore, the separation region is only an accumulation center of the low-energy fluid rather than an area of loss source.
基金supported by the National Natural Science Foundation of China (Nos. 60603085 and 60736019)the Hi-Tech Research and Development (863) Program of China (No. 2007AA01Z336)Tsinghua Basic Research Foundation, China # Expanded based on "Note on industrial applications of Hu’s surface
文摘Curve and surface blending is an important operation in CAD systems, in which a non-uniform rational B-spline （NURBS） has been used as the de facto standard. In local comer blending, two curves intersecting at that comer are first made disjoint, and then the third blending curve is added-in to smoothly join the two curves with G^1- or G^2-continuity. In this paper we present a study to solve the joint problem based on curve extension. The following nice properties of this extension algorithm are exploited in depth： （1） The parameterization of the original shapes does not change; （2） No additional fragments are created. Various examples are presented to demonstrate that our solution is simple and efficient.
