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利用循环伏安法模拟技术理解电极过程可逆性 被引量:4
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作者 于鑫萍 周炎 +2 位作者 张军 于剑峰 冯锡兰 《化学教育(中英文)》 CAS 北大核心 2020年第24期61-64,共4页
循环伏安法测定电极过程可逆性实验在仪器分析实验中有着重要的意义。现行的实验设计中一般将铁氰化钾作为氧化还原反应研究的对象。由于铁氰化钾/亚铁氰化钾的氧化还原过程在电化学上可逆,学生通过实验很难理解电化学不可逆的过程,不... 循环伏安法测定电极过程可逆性实验在仪器分析实验中有着重要的意义。现行的实验设计中一般将铁氰化钾作为氧化还原反应研究的对象。由于铁氰化钾/亚铁氰化钾的氧化还原过程在电化学上可逆,学生通过实验很难理解电化学不可逆的过程,不易区分可逆和不可逆过程。本文利用循环伏安模拟的方法,通过改变电子转移速率常数(k^0),得到不同的循环伏安谱图,结合课本上对于可逆性的判据(Epa-Epc=0.056 V/n,ipa/ipc≈-1)来解释不同的电子转移速率对于电极过程可逆性的影响。 展开更多
关键词 循环伏安法 仪器分析实验 循环伏安法模拟 实验教学改革 电极过程可逆性
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导热能力损耗的机理及其数学表述 被引量:86
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作者 韩光泽 过增元 《中国电机工程学报》 EI CSCD 北大核心 2007年第17期98-102,共5页
热量传递势容(势容,又称为火积)反映了物体的导热能力,它等于物体的热容量与温度乘积的一半。提出了热力功的概念,它被定义为传热温度与被传递热量的乘积。传热过程中的热力功等于势容的改变量,热力功就是传递过程中的势容。在导热过程... 热量传递势容(势容,又称为火积)反映了物体的导热能力,它等于物体的热容量与温度乘积的一半。提出了热力功的概念,它被定义为传热温度与被传递热量的乘积。传热过程中的热力功等于势容的改变量,热力功就是传递过程中的势容。在导热过程中势容会出现损耗,势容损耗的机理是,传热物体的温度高于吸热物体的温度,传热物体的温度所做的热力功多于吸热物体的温度所做的热力功。导热过程中的势容损耗被定义为传热物体的温度与吸热物体温度的差所做的热力功。单位时间单位体积内的势容损耗等于导热系数与温度梯度平方的乘积,该表达式可作为导热系统优化的目标函数。势容可同时作为热力学中导热过程可逆性的判据。 展开更多
关键词 热力功 热量传递势容损耗 [火积] 导热优化 过程可逆性
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A novel method based on entransy theory for setting energy targets of heat exchanger network 被引量:5
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作者 Li Xia Yuanli Feng +1 位作者 Xiaoyan Sun Shuguang Xiang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第8期1037-1042,共6页
A T-Q diagram based on entransy theory is applied to graphically and quantitatively describe the irreversibility of the heat transfer processes.The hot and cold composite curves can be obtained in the T-Q diagram.The ... A T-Q diagram based on entransy theory is applied to graphically and quantitatively describe the irreversibility of the heat transfer processes.The hot and cold composite curves can be obtained in the T-Q diagram.The entransy recovery and entransy dissipation that are affected by temperature differences can be obtained through the shaded area under the composite curves.The method for setting the energy target of the HENs in T-Q diagram based on entransy theory is proposed.A case study of the diesel oil hydrogenation unit is used to illustrate the application of the method.The results show that three different heat transfer temperature differences is 10 K,15 K and 20 K,and the entransy recovery is 5.498×10~7k W·K,5.377×10~7k W·K,5.257×10~7k W·K,respectively.And the entransy transfer efficiency is 92.29%,91.63%,90.99%.Thus,the energy-saving potential of the HENs is obtained by setting the energy target based on the entransy transfer efficiency. 展开更多
关键词 Heat transfer Process systems Entransy Energy target T-Qdiagram
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Combustion Irreversibilities: Numerical Simulation and Analysis
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作者 Valter Silva Abel Rouboa 《Journal of Thermal Science》 SCIE EI CAS CSCD 2012年第4期377-383,共7页
An exergy analysis was performed considering the combustion of methane and agro-industrial residues produced in Portugal (forest residues and vines pruning). Regarding that the irreversibilities of a thermodynamic pro... An exergy analysis was performed considering the combustion of methane and agro-industrial residues produced in Portugal (forest residues and vines pruning). Regarding that the irreversibilities of a thermodynamic process are path dependent, the combustion process was considering as resulting from different hypothetical paths each one characterized by four main sub-processes: reactant mixing, fuel oxidation, internal thermal energy exchange (heat transfer), and product mixing. The exergetic efficiency was computed using a zero dimensional model developed by using a Visual Basic home code. It was concluded that the exergy losses were mainly due to the internal thermal energy exchange sub-process. The exergy losses from this sub-process are higher when the reactants are preheated up to the ignition temperature without previous fuel oxidation. On the other hand, the global exergy destruction can be minored increasing the pressure, the reactants temperature and the oxygen content on the oxidant stream. This methodology allows the identification of the phenomena and processes that have larger exergy losses, the understanding of why these losses occur and how the exergy changes with the parameters associated to each system which is crucial to implement the syngas combustion from biomass products as a competitive technology. 展开更多
关键词 EXERGY Combustion paths Combustion sub-processes Exergetic efficiency Visual Basic SYNGAS
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