In the Davey-MacKay(DM) construction,the inner decoder treats unknown transmitted bits as random independent substitution errors. It limits the synchronization capability of the inner decoder, and thus weakens the err...In the Davey-MacKay(DM) construction,the inner decoder treats unknown transmitted bits as random independent substitution errors. It limits the synchronization capability of the inner decoder, and thus weakens the error-correcting capability of the DM construction.In order to improve the performance of the DM construction, an iterative decoding scheme is proposed, which iteratively utilizes the more accurate estimates of transmitted codewords. In the proposed scheme, the estimated average bit error rates and the estimated low-density parity-check(LDPC) codewords from the outer decoder are fed back into the inner decoder to update the synchronization process. Simulation results show that the proposed iterative decoding scheme significantly outperforms the traditional DM construction.展开更多
The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstructio...The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstruction theory.With the correlation dimensions obtained from the phase space reconstruction,the chaotic behavior of EN was quantitatively evaluated.The results show that both electrochemical potential noise (EPN) and electrochemical current noise (ECN) have chaotic properties.The correlation dimensions of EPN increase with corrosion extent,while those of ECN seem nearly unchanged.The increased correlation dimensions of EPN during the degradation process are associated with the increased susceptibility to local corrosion.展开更多
In order to study the anodic behavior and microstmctures of A1/Pb-Ag-Co anode during zinc electrowinning, by means of potentiodynamic investigations, scanning electron microscopy （SEM） and X-ray diffraction （XRD） ...In order to study the anodic behavior and microstmctures of A1/Pb-Ag-Co anode during zinc electrowinning, by means of potentiodynamic investigations, scanning electron microscopy （SEM） and X-ray diffraction （XRD） analyses, the mechanism of the anodic processes playing on the surface of A1/Pb-0.8%Ag and A1/Pb-0.75%Ag-0.03%Co anodes prepared by electro-deposition from methyl sulfonic acid bath for zinc electrowinning from model sulphate electrolytes have been measured. On the basis of the cyclic voltammograms obtained, information about the corrosion rate of the composite in PbO2 region has been concluded. The microstructures were also observed by means of SEM and XRD which showed Pb-0.75%Ag-0.03%Co alloy composite coating has uniform and chaotic orientation tetragonal symmetry crystallites of PbSO4, but Pb-0.8%Ag alloy composite coating has well-organized orientation crystallites of PbSO4 concentrated in the certain zones after 24 h of anodic polarization. It is important that Al/Pb-0.75%Ag-0.03%Co anode oxide film consists of non-conductive dense MnO2 and PbSO4 and a, fl-PbO2 penetrated into which, in fact, are the active centers of the oxygen evolution after 24 h of anodic polarization.展开更多
Nonlinear characteristic fault detection and diagnosis method based on higher-order statistical(HOS) is an effective data-driven method, but the calculation costs much for a large-scale process control system. An HOS-...Nonlinear characteristic fault detection and diagnosis method based on higher-order statistical(HOS) is an effective data-driven method, but the calculation costs much for a large-scale process control system. An HOS-ISM fault diagnosis framework combining interpretative structural model(ISM) and HOS is proposed:(1) the adjacency matrix is determined by partial correlation coefficient;(2) the modified adjacency matrix is defined by directed graph with prior knowledge of process piping and instrument diagram;(3) interpretative structural for large-scale process control system is built by this ISM method; and(4) non-Gaussianity index, nonlinearity index, and total nonlinearity index are calculated dynamically based on interpretative structural to effectively eliminate uncertainty of the nonlinear characteristic diagnostic method with reasonable sampling period and data window. The proposed HOS-ISM fault diagnosis framework is verified by the Tennessee Eastman process and presents improvement for highly non-linear characteristic for selected fault cases.展开更多
The nanometer coherent structure evolution of spinodal decomposition and ordering coexistence phase transformation in Fe-24Al alloys is investigated by the microscopic phase field kinetic model.The results show that t...The nanometer coherent structure evolution of spinodal decomposition and ordering coexistence phase transformation in Fe-24Al alloys is investigated by the microscopic phase field kinetic model.The results show that the concentration and long-range order parameters all continuously change towards to their equilibrium values during phase transformation.With the increase of elastic interaction energy,the anisotropy along [01] or [10] elastic soft direction is more obvious and the time reaching equilibrium state is also shortened.According to the results,the formation of nanometer coherent structures during phase transformation is composed of the initial decreasing stage of order degree stage,the incubation stage,the continuous increasing stage of concentration order parameter and long-range order parameter,and the later stable stage.The spinodal decomposition and ordering is interaction;the initial ordering stage is a necessary condition of the coexistence phase transformation.The nanometer coherent structures are not found to grow during the whole phase transformation.The simulation results are in accordance with the results in experiment obtained by the aging treatment in Fe-24Al alloys.展开更多
Two remarkable epimerization processes were uncovered during our pursuit of an enantioselective synthesis of(+)-aigialospirol featuring a cyclic acetal tethered ring-closing metathesis.Through modeling,we were able to...Two remarkable epimerization processes were uncovered during our pursuit of an enantioselective synthesis of(+)-aigialospirol featuring a cyclic acetal tethered ring-closing metathesis.Through modeling,we were able to turn these two unexpected epimerizations to our advantage via modeling to ensure a successful and concise total synthesis,thereby firmly establishing cyclic acetal tethered RCM as a powerful strategy in natural product synthesis.Most importantly,calculations allowed us to fully understand the nature and the mechanistic course of these two epimerizations that were imperative to the total synthesis efforts.展开更多
基金supported in part by National Natural Science Foundation of China(61671324)the Director’s Funding from Qingdao National Laboratory for Marine Science and Technology
文摘In the Davey-MacKay(DM) construction,the inner decoder treats unknown transmitted bits as random independent substitution errors. It limits the synchronization capability of the inner decoder, and thus weakens the error-correcting capability of the DM construction.In order to improve the performance of the DM construction, an iterative decoding scheme is proposed, which iteratively utilizes the more accurate estimates of transmitted codewords. In the proposed scheme, the estimated average bit error rates and the estimated low-density parity-check(LDPC) codewords from the outer decoder are fed back into the inner decoder to update the synchronization process. Simulation results show that the proposed iterative decoding scheme significantly outperforms the traditional DM construction.
基金Supported by Major State Basic Research Program of China ("973" Program,No. 2011CB610505)Specialized Research Fund for the Doctoral Program of Higher Education (No. 20120032110029)
文摘The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstruction theory.With the correlation dimensions obtained from the phase space reconstruction,the chaotic behavior of EN was quantitatively evaluated.The results show that both electrochemical potential noise (EPN) and electrochemical current noise (ECN) have chaotic properties.The correlation dimensions of EPN increase with corrosion extent,while those of ECN seem nearly unchanged.The increased correlation dimensions of EPN during the degradation process are associated with the increased susceptibility to local corrosion.
基金Project(51004056)supported by the National Natural Science Foundation of China
文摘In order to study the anodic behavior and microstmctures of A1/Pb-Ag-Co anode during zinc electrowinning, by means of potentiodynamic investigations, scanning electron microscopy （SEM） and X-ray diffraction （XRD） analyses, the mechanism of the anodic processes playing on the surface of A1/Pb-0.8%Ag and A1/Pb-0.75%Ag-0.03%Co anodes prepared by electro-deposition from methyl sulfonic acid bath for zinc electrowinning from model sulphate electrolytes have been measured. On the basis of the cyclic voltammograms obtained, information about the corrosion rate of the composite in PbO2 region has been concluded. The microstructures were also observed by means of SEM and XRD which showed Pb-0.75%Ag-0.03%Co alloy composite coating has uniform and chaotic orientation tetragonal symmetry crystallites of PbSO4, but Pb-0.8%Ag alloy composite coating has well-organized orientation crystallites of PbSO4 concentrated in the certain zones after 24 h of anodic polarization. It is important that Al/Pb-0.75%Ag-0.03%Co anode oxide film consists of non-conductive dense MnO2 and PbSO4 and a, fl-PbO2 penetrated into which, in fact, are the active centers of the oxygen evolution after 24 h of anodic polarization.
基金Supported by the National Natural Science Foundation of China(61374166)the Doctoral Fund of Ministry of Education of China(20120010110010)the Natural Science Fund of Ningbo(2012A610001)
文摘Nonlinear characteristic fault detection and diagnosis method based on higher-order statistical(HOS) is an effective data-driven method, but the calculation costs much for a large-scale process control system. An HOS-ISM fault diagnosis framework combining interpretative structural model(ISM) and HOS is proposed:(1) the adjacency matrix is determined by partial correlation coefficient;(2) the modified adjacency matrix is defined by directed graph with prior knowledge of process piping and instrument diagram;(3) interpretative structural for large-scale process control system is built by this ISM method; and(4) non-Gaussianity index, nonlinearity index, and total nonlinearity index are calculated dynamically based on interpretative structural to effectively eliminate uncertainty of the nonlinear characteristic diagnostic method with reasonable sampling period and data window. The proposed HOS-ISM fault diagnosis framework is verified by the Tennessee Eastman process and presents improvement for highly non-linear characteristic for selected fault cases.
文摘The nanometer coherent structure evolution of spinodal decomposition and ordering coexistence phase transformation in Fe-24Al alloys is investigated by the microscopic phase field kinetic model.The results show that the concentration and long-range order parameters all continuously change towards to their equilibrium values during phase transformation.With the increase of elastic interaction energy,the anisotropy along [01] or [10] elastic soft direction is more obvious and the time reaching equilibrium state is also shortened.According to the results,the formation of nanometer coherent structures during phase transformation is composed of the initial decreasing stage of order degree stage,the incubation stage,the continuous increasing stage of concentration order parameter and long-range order parameter,and the later stable stage.The spinodal decomposition and ordering is interaction;the initial ordering stage is a necessary condition of the coexistence phase transformation.The nanometer coherent structures are not found to grow during the whole phase transformation.The simulation results are in accordance with the results in experiment obtained by the aging treatment in Fe-24Al alloys.
基金PRF-AC(42106) for support and Dr.Victor Young and Ben Kucera(University of Minnesota) for X-ray analysis.CCG thanks UW for an NIH-CBI Training Grant
文摘Two remarkable epimerization processes were uncovered during our pursuit of an enantioselective synthesis of(+)-aigialospirol featuring a cyclic acetal tethered ring-closing metathesis.Through modeling,we were able to turn these two unexpected epimerizations to our advantage via modeling to ensure a successful and concise total synthesis,thereby firmly establishing cyclic acetal tethered RCM as a powerful strategy in natural product synthesis.Most importantly,calculations allowed us to fully understand the nature and the mechanistic course of these two epimerizations that were imperative to the total synthesis efforts.
