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阻抗谱过程阻力与Ni-Cd电池荷电量之间的关系研究 被引量:6
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作者 孙秋霞 梁剑波 苏铭鸿 《化学研究》 CAS 2010年第3期88-91,96,共5页
电化学阻抗谱(EIS)是研究电池的重要技术之一,但解谱模型不一致限制了其应用.为此,探讨了输线模型的阻力特征,提出其串联分支电阻和电容的比值Ri/Ci与电池荷电量(SOC)存在单调关系;并通过重新拟合分析文献中镍镉电池的阻抗谱数据进行了... 电化学阻抗谱(EIS)是研究电池的重要技术之一,但解谱模型不一致限制了其应用.为此,探讨了输线模型的阻力特征,提出其串联分支电阻和电容的比值Ri/Ci与电池荷电量(SOC)存在单调关系;并通过重新拟合分析文献中镍镉电池的阻抗谱数据进行了验证.结果表明,可以根据误差分析确定CR传输线模型的最佳结构,且Ri/Ci与SOC存在近似直线关系,并与电池质量密切相关. 展开更多
关键词 电化学阻抗谱 CR传输线模型 过程阻力 Ni-Cd电池 电池荷电量
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EIS过程阻力与铅酸电池荷电量 被引量:6
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作者 孙秋霞 刘凌峰 何效强 《韶关学院学报》 2010年第3期55-59,共5页
电化学阻抗谱是研究电池的重要技术之一,但被解谱模型不一致限制了独立应用.研究表明:可以用传输线模型中串联电阻和电容的比值(Ri/Ci)表征过程阻力特征,并与电池荷电量(SOC%)有单调关系.借助文献中铅酸电池EIS数据进行了验证,表明Ri/C... 电化学阻抗谱是研究电池的重要技术之一,但被解谱模型不一致限制了独立应用.研究表明:可以用传输线模型中串联电阻和电容的比值(Ri/Ci)表征过程阻力特征,并与电池荷电量(SOC%)有单调关系.借助文献中铅酸电池EIS数据进行了验证,表明Ri/Ci的对数与SOC%有直线关系,且当SOC%从0变化到100时,Ri/Ci变化5~100倍,具有较高的灵敏度.最后探讨了溶液电阻在电池过程阻力中的重要作用. 展开更多
关键词 电化学阻抗谱 CR传输线 过程阻力 铅酸电池 SOC
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CR传输线模型解析AgO-Zn电池阻抗谱 被引量:2
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作者 孙秋霞 范启恒 骆海平 《广州化工》 CAS 2010年第6期125-127,共3页
电化学阻抗谱(EIS)是研究电池的重要技术之一,但需要合适的解谱方法才能提取有效信息。本文以文献中Ag-Zn电池的阻抗谱拟合数据为例,说明根据普适性CR传输线模型可得到原作者预言存在却无法证实的结果:存在与电池荷电量(SOC)有直线关系... 电化学阻抗谱(EIS)是研究电池的重要技术之一,但需要合适的解谱方法才能提取有效信息。本文以文献中Ag-Zn电池的阻抗谱拟合数据为例,说明根据普适性CR传输线模型可得到原作者预言存在却无法证实的结果:存在与电池荷电量(SOC)有直线关系,并在SOC=0.4发生转折的参数。结果还表明这种参数有多个,分别与Ag正极的半导体特征,以及放电过程中控制步骤的变化有关,充分显示了EIS信息丰富的特点。本方法结果客观、具有可操作性,因而有重要的理论意义和应用价值。 展开更多
关键词 电化学阻抗谱 CR传输线 过程阻力 AgO-Zn电池
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An Unsteady Heterogeneous Mass Transfer Model for Gas Absorption Enhanced by Dispersed Third Phase Droplets 被引量:5
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作者 沈树华 马友光 +1 位作者 卢素敏 朱春英 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第4期602-607,共6页
A model for one-dimensional unsteady heterogeneous mass transfer was developed based on Danck-werts' surface renewal theory in order to describe the mass transfer enhancement of absorption process for a slightly s... A model for one-dimensional unsteady heterogeneous mass transfer was developed based on Danck-werts' surface renewal theory in order to describe the mass transfer enhancement of absorption process for a slightly soluble gas in a gas-liquid-liquid system.The model accounts for the mass transfer resistance within the dispersed phase and the effect of emulsion viscosity on mass transfer.An analytical solution for enhancement factor was obtained by Laplace domain transformation.The absorption rates of carbon dioxide in the dodecane-in-water and castor oil-in-water systems were measured in a thermostatic reactor,and the enhancement factors were calculated at different volume fractions of dispersed phase and stirrer speeds.The model predictions agree well with the experimental data. 展开更多
关键词 enhancement factor mass transfer ABSORPTION gas-liquid-liquid
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Specific Power Consumption as Factor Disintegration Process Control of Digging-Wheel Excavators
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作者 Josef Jurman and Jiri Fries 《Journal of Mechanics Engineering and Automation》 2013年第9期591-594,共4页
The determination of digging resistance is of decisive importance when evaluating the mining process of digging-wheel excavators. Methodic of measuring and determinant relations (formulae) are different in various c... The determination of digging resistance is of decisive importance when evaluating the mining process of digging-wheel excavators. Methodic of measuring and determinant relations (formulae) are different in various countries and by the comparison of them, underlying data for complex and objective evaluation using the knowledge from the field of rock disintegration can be obtained. In virtue of analysis of many measurements in situ, rather high specific power consumption with a wheel of excavator has been proved. What was the criterion for evaluation was the power consumption related to the volume of a rock disintegrated per unit time. From theoretical analyses, possibilities of eliminating a negative influence of the human factor upon the mining process and thus possibilities of optimum utilizing the power input of a wheel drive follow. 展开更多
关键词 WHEEL EXCAVATOR energy CONSUMPTION DISINTEGRATION digging.
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