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氢键流体中Janus粒子的过量熵
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作者 陈晴晴 李江涛 +2 位作者 黄欣蓉 顾芳 王海军 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2024年第2期139-146,共8页
Janus粒子在结构和性质上的特殊性使其在不同溶剂中呈现出丰富的聚集态结构和相态结构,这与其在溶液中的过量熵密切相关.本文以Janus粒子与氢键流体的稀溶液体系为例,利用经典流体的密度泛函理论研究了氢键流体中Janus粒子的过量熵.首... Janus粒子在结构和性质上的特殊性使其在不同溶剂中呈现出丰富的聚集态结构和相态结构,这与其在溶液中的过量熵密切相关.本文以Janus粒子与氢键流体的稀溶液体系为例,利用经典流体的密度泛函理论研究了氢键流体中Janus粒子的过量熵.首先在极稀条件下给出Janus粒子外氢键流体中的局域密度分布,由此得到Janus粒子与氢键流体的二体分布函数,进而计算了不同情况下的过量熵.在此基础上,阐明了Janus粒子与氢键流体间的相互作用、氢键流体的体相密度、氢键强度和氢键官能度等因素对过量熵的影响.本研究旨在揭示这些因素对过量熵的调控机制,在定量水平上明确Janus粒子在溶液中组装的驱动力,从而为深入研究其聚集态结构提供可借鉴的理论线索. 展开更多
关键词 Janus粒子 氢键流体 过量熵 经典密度泛函理论
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A Complex Systems Science Perspective on Wireless Networks
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作者 MACALUSO Irene GALIOTTO Carlo +1 位作者 MARCHETTI Nicola DOYLE Linda 《Journal of Systems Science & Complexity》 SCIE EI CSCD 2016年第4期1034-1056,共23页
The paper targets a future world where all wireless networks are self-organising entities and in which the predominant mode of spectrum access is dynamic. The paper explores whether the behaviour of a collection of au... The paper targets a future world where all wireless networks are self-organising entities and in which the predominant mode of spectrum access is dynamic. The paper explores whether the behaviour of a collection of autonomous self-organising wireless systems can be treated as a complex system and whether complex systems science can shed light on the design and deployment of these networks. The authors focus on networks that self-organise from a frequency perspective to understand the behaviour of a collection of wireless self-organising nodes. Each autonomous network is modelled as a cell in a lattice and follows a simple set of self-organisation rules. Two scenarios are considered, one in which each cell is based on cellular automata and which provides an abstracted view of interference and a second in which each cell uses a self-organising technique which more accurately accounts for interference. The authors use excess entropy to measure complexity and in combination with entropy gain an understanding of the structure emerging in the lattice for the self-organising networks. The authors show that the self-organising systems presented here do exhibit complex behaviour. Finally,the authors look at the robustness of these complex systems and show that they are robust against changes in the environment. 展开更多
关键词 动态光谱存取 过量熵 坚韧性 组织无线网络的自我
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