Two kinds of water-soluble and ultraviolet (UV) curable oligomers were synthesized and characterized. The oligomers were evaluated as resins for water-based UV curable coating. The rheology of the two oligomers' a...Two kinds of water-soluble and ultraviolet (UV) curable oligomers were synthesized and characterized. The oligomers were evaluated as resins for water-based UV curable coating. The rheology of the two oligomers' aqueous so-lutions was investigated in terms of solid fraction, pH dependence, and temperature dependence. The solutions were found to be Newtonian fluid showing rather low viscosity even at high solid fraction of 0.55. The drying process of the coatings and the properties of the cured coatings were studied by comparing them with water-dispersed UV-curable polyurethane methyl acrylate. It was evident that the water-soluble coating dried more slowly; and that the overall properties were inferior to those of the water-dispersed coating.展开更多
The study analyzes the characteristics of roof movement in mining top coal of inclined coal seam,and establishes the mechanical model of support and surrounding-rock stability in inclined coal seam.Besides,this study ...The study analyzes the characteristics of roof movement in mining top coal of inclined coal seam,and establishes the mechanical model of support and surrounding-rock stability in inclined coal seam.Besides,this study carries out the numerical calculation and field observation of roof movement and support stability,and provides the critical control measures.The results show that the fracture firstly appears in middle-upper roof and extends upwards in top coal caving in inclined coal seam;regular and irregular caving zones appear in middle-upper stress concentration region,and the asymmetric caving arch is finally formed.Support load of middle-upper working face is larger than that of the middle-lower face;dynamic load coefficient of upper support is large,and the load on the front of support is larger than that on the rear of it,which leads to poor support stability.Stability of support and surrounding-rock system depends mainly on upper-support stability.展开更多
文摘Two kinds of water-soluble and ultraviolet (UV) curable oligomers were synthesized and characterized. The oligomers were evaluated as resins for water-based UV curable coating. The rheology of the two oligomers' aqueous so-lutions was investigated in terms of solid fraction, pH dependence, and temperature dependence. The solutions were found to be Newtonian fluid showing rather low viscosity even at high solid fraction of 0.55. The drying process of the coatings and the properties of the cured coatings were studied by comparing them with water-dispersed UV-curable polyurethane methyl acrylate. It was evident that the water-soluble coating dried more slowly; and that the overall properties were inferior to those of the water-dispersed coating.
基金the financial support received from the National Natural Science Foundation of China (No.51174078)Ph.D.Foundation of Henan Polytechnic University (No.60207004) of Chinathe Fostering Foundation of Henan Polytechnic University for the Excellent Ph.D.Dissertation of China (No.508063)
文摘The study analyzes the characteristics of roof movement in mining top coal of inclined coal seam,and establishes the mechanical model of support and surrounding-rock stability in inclined coal seam.Besides,this study carries out the numerical calculation and field observation of roof movement and support stability,and provides the critical control measures.The results show that the fracture firstly appears in middle-upper roof and extends upwards in top coal caving in inclined coal seam;regular and irregular caving zones appear in middle-upper stress concentration region,and the asymmetric caving arch is finally formed.Support load of middle-upper working face is larger than that of the middle-lower face;dynamic load coefficient of upper support is large,and the load on the front of support is larger than that on the rear of it,which leads to poor support stability.Stability of support and surrounding-rock system depends mainly on upper-support stability.
