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红外光谱法测定聚丙烯中乙烯含量 被引量:8
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作者 赵家琳 孙步均 高杜鹃 《甘肃科技》 2010年第9期54-55,共2页
根据Basell公司提供的聚丙烯标样,用红外光谱仪测定了聚丙烯中乙烯含量。选择近红外谱区的吸收作为聚丙烯测定参数。使用峰面积法计算吸光度。对于不同乙烯含量范围的样品,选择不同的乙烯测定参数。
关键词 红外 聚丙烯 乙烯含量 近红外谱区 峰面积法 乙烯测定参数
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运用PLS算法由小麦冠层反射光谱反演氮素垂直分布 被引量:53
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作者 王纪华 黄文江 +6 位作者 劳彩莲 张录达 罗长兵 王韬 刘良云 宋晓宇 马智宏 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2007年第7期1319-1322,共4页
文章提出了利用遥感光谱数据反演小麦冠层氮素垂直分布的化学计量学方法,运用偏最小二乘算法(PLS),穷尽测定的小麦田间冠层可见光和近红外光谱不同波长处的冠层光谱反射率及其组合与小麦不同层次的叶绿素、叶片全氮含量之间的关系。通... 文章提出了利用遥感光谱数据反演小麦冠层氮素垂直分布的化学计量学方法,运用偏最小二乘算法(PLS),穷尽测定的小麦田间冠层可见光和近红外光谱不同波长处的冠层光谱反射率及其组合与小麦不同层次的叶绿素、叶片全氮含量之间的关系。通过2001~2002年的建模和2003~2004年的验证试验,求得了用PLS算法对叶片全氮上层、中层、下层垂直分布估算结果的相关性。表明PLS算法能够用于反演作物冠层生物化学参数的垂直分布。运用PLS的小麦氮素垂直分布的估算方法,较以往单一冠层估算方法精度明显提高,对于生产上迫切需求对作物中、下层叶片氮素状况的监测来指导适时和适量施肥具有指导意义。 展开更多
关键词 冬小麦 偏最小二乘法 可见近红外谱区 冠层反射光 氮素垂直分布
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A Comparative Study on the Quality Components Between Self Pollinated Seeds and Naturally Pollinated Seeds in Brassica napus L. in Sichuan Ecological Region 被引量:2
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作者 张锦芳 蒲晓斌 +4 位作者 李浩杰 黄驰 李蒲 张谦 蒋梁材 《Agricultural Science & Technology》 CAS 2009年第1期19-21,80,共4页
[ Objective] This study was to reveal the differences in crude fat and glucosinolates between self pollinated seeds and naturally pollinated seeds in Brassica napus in sichuan ecological region.. [ Method] Near-infrar... [ Objective] This study was to reveal the differences in crude fat and glucosinolates between self pollinated seeds and naturally pollinated seeds in Brassica napus in sichuan ecological region.. [ Method] Near-infrared spectroscopy method (NIRS) was employed to measure the quality components in self pollinated seeds and naturally pollinated seeds of 861 shares of Brassica napus from Sichuan ecological region. And correlation analysis and regression analysis were conducted based on the experimental data via SPSS (statistics package for social science). [ Result] The contents of crude fat in the self pollinated seeds were commonly a higher than that in the naturally pollinated seeds at 0.01 significant level; while the contents of glucosinolates in the self pollinated seeds and the naturally pollinated seeds were insignificantly different. Both the correlation relationship and linear regression for the crude fat between the self pollinated seeds and naturally pollinated seeds reached the significant level. The regression equations for the contents of crude fat(y1 ) and glucosinolates( y2 ) in the naturally pollinated seeds and of crude fat( x1 ) and glucosinolates( x2 ) in self pollinated seeds were respectively determined to be y1 = 16.844 +0.614x1 and y2 = -0.620 + 1.017 x2. [ Conclusion] In Brassica napus breeding, crude fat in naturally pollinated seeds should be emphatically taken into account, meanwhile concurrently considering that in self pollinated seeds; while glucosinolates in both the self pollinated seeds and the naturally pollinated seeds must be simultaneously concerned. 展开更多
关键词 Brassica napus L. Self pollinated seeds Naturally pollinated seeds Content of crude fat Content of gluccsinolates Near-infrared spectroscopy method
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Determination of Soil Parameters in Apple-Growing Regions by Near-and Mid-Infrared Spectroscopy 被引量:8
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作者 DONG Yi-Wei YANG Shi-Qi +5 位作者 XU Chun-Ying LI Yu-Zhong BAI Wei FAN Zhong-Nan WANG Ya-Nan LI Qiao-Zhen 《Pedosphere》 SCIE CAS CSCD 2011年第5期591-602,共12页
Soil quality monitoring is important in precision agriculture.This study aimed to examine the possibility of assessing the soil parameters in apple-growing regions using spectroscopic methods.A total of 111 soil sampl... Soil quality monitoring is important in precision agriculture.This study aimed to examine the possibility of assessing the soil parameters in apple-growing regions using spectroscopic methods.A total of 111 soil samples were collected from 11 typical sites of apple orchards,and the croplands surrounding them.Near-infrared(NIR) and mid-infrared(MIR) spectra,combined with partial least square regression,were used to predict the soil parameters,including organic matter(OM) content,pH,and the contents of As,Cu,Zn,Pb,and Cr.Organic matter and pH were closely correlated with As and the heavy metals.The NIR model showed a high prediction accuracy for the determination of OM,pH,and As,with correlation coefficients(r) of 0.89,0.89,and 0.90,respectively.The predictions of these three parameters by MIR showed reduced accuracy,with r values of 0.77,0.84,and 0.92,respectively.The heavy metals could also be measured by spectroscopy due to their correlation with organic matter.Both NIR and MIR had high correlation coefficients for the determination of Cu,Zn,and Cr,with standard errors of prediction of 2.95,10.48,and 9.49 mg kg-1 for NIR and 3.69,5.84,and 6.94 mg kg-1 for MIR,respectively.Pb content behaved differently from the other parameters.Both NIR and MIR underestimated Pb content,with r values of 0.67 and 0.56 and standard errors of prediction of 3.46 and 2.99,respectively.Cu and Zn had a higher correlation with OM and pH and were better predicted than Pb and Cr.Thus,NIR spectra could accurately predict several soil parameters,metallic and nonmetallic,simultaneously,and were more feasible than MIR in analyzing soil parameters in the study area. 展开更多
关键词 heavy metals partial least square regression prediction accuracy soil quality spectroscopic method
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