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近-中红外光谱融合技术速测奶牛场粪水氮磷含量 被引量:5
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作者 孙迪 李梦婷 +2 位作者 牟美睿 赵润 张克强 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2021年第10期3092-3098,共7页
快速准确测定粪水/沼液中的氮磷养分含量,是现阶段我国规模化奶牛场在种养结合道路上亟需破解的技术瓶颈。针对传统的实验室湿化学检测方法难以满足奶牛场粪水还田前任一节点氮磷快速定量的现实问题,研究开发了基于近红外、中红外及近-... 快速准确测定粪水/沼液中的氮磷养分含量,是现阶段我国规模化奶牛场在种养结合道路上亟需破解的技术瓶颈。针对传统的实验室湿化学检测方法难以满足奶牛场粪水还田前任一节点氮磷快速定量的现实问题,研究开发了基于近红外、中红外及近-中红外光谱融合技术,实现规模化奶牛场粪水运移全链条环节氮磷含量的本土化快速检测方法。采集了天津地区27家种养结合型规模化奶牛场粪水流经全程环节(集粪沟、集污池、氧化塘等)共计144个样品,使用傅里叶变换近红外光谱仪和中红外光谱仪分别采集了12000~4000和4000~650 cm^(-1)区间的光谱数据,对所有样品的近红外光谱、中红外光谱及近-中红外光谱融合数据进行归一化、基线校正、SNV等预处理,分析了近红外光谱和中红外光谱特征,采用浓度梯度法进行样品分集,运用偏最小二乘(PLS)、间隔偏最小二乘(IPLS)和联合区间偏最小二乘(SIPLS)法,构建了粪水总氮(TN)、总磷(TP)的近红外模型和中红外模型。粪水TN模型预测结果较好,近红外和中红外最佳模型趋近一致;粪水TP模型的预测性能不理想,近红外和中红外SIPLS最佳模型的R 2 pred仅分别为0.790和0.631,RPD分别为2.213和1.479,四分位数间隔(RPIQ)分别为3.616和2.351,难以用于实际检测;为实现粪水氮磷同步有效的测定分析,进一步提升模型整体预测性能,综合近红外光谱和中红外光谱数据建立了粪水氮磷近-中红外融合模型,光谱区间为12000~650 cm^(-1),预测性能整体表现良好,以近-中红外融合IPLS模型预测结果最为理想,其R 2 pred分别为0.970和0.861,RPD分别为5.615和2.684,RPIQ分别为12.874和4.394,总体优于单一近、中红外模型,尤其TP的最佳融合模型,其R 2 pred相比近、中红外最佳单一模型分别高出0.071和0.170。研究表明,近-中红外光谱融合技术可以实现对规模化奶牛场粪水运移全链条环节氮磷含量的准确速测,为粪水科学还田提供技术支撑。 展开更多
关键词 粪水运移 全链条环节 近-中红外光谱 速测 氮磷含量 融合模型
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Determination of Soil Parameters in Apple-Growing Regions by Near-and Mid-Infrared Spectroscopy 被引量:8
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作者 DONG Yi-Wei YANG Shi-Qi +5 位作者 XU Chun-Ying LI Yu-Zhong BAI Wei FAN Zhong-Nan WANG Ya-Nan LI Qiao-Zhen 《Pedosphere》 SCIE CAS CSCD 2011年第5期591-602,共12页
Soil quality monitoring is important in precision agriculture.This study aimed to examine the possibility of assessing the soil parameters in apple-growing regions using spectroscopic methods.A total of 111 soil sampl... Soil quality monitoring is important in precision agriculture.This study aimed to examine the possibility of assessing the soil parameters in apple-growing regions using spectroscopic methods.A total of 111 soil samples were collected from 11 typical sites of apple orchards,and the croplands surrounding them.Near-infrared(NIR) and mid-infrared(MIR) spectra,combined with partial least square regression,were used to predict the soil parameters,including organic matter(OM) content,pH,and the contents of As,Cu,Zn,Pb,and Cr.Organic matter and pH were closely correlated with As and the heavy metals.The NIR model showed a high prediction accuracy for the determination of OM,pH,and As,with correlation coefficients(r) of 0.89,0.89,and 0.90,respectively.The predictions of these three parameters by MIR showed reduced accuracy,with r values of 0.77,0.84,and 0.92,respectively.The heavy metals could also be measured by spectroscopy due to their correlation with organic matter.Both NIR and MIR had high correlation coefficients for the determination of Cu,Zn,and Cr,with standard errors of prediction of 2.95,10.48,and 9.49 mg kg-1 for NIR and 3.69,5.84,and 6.94 mg kg-1 for MIR,respectively.Pb content behaved differently from the other parameters.Both NIR and MIR underestimated Pb content,with r values of 0.67 and 0.56 and standard errors of prediction of 3.46 and 2.99,respectively.Cu and Zn had a higher correlation with OM and pH and were better predicted than Pb and Cr.Thus,NIR spectra could accurately predict several soil parameters,metallic and nonmetallic,simultaneously,and were more feasible than MIR in analyzing soil parameters in the study area. 展开更多
关键词 heavy metals partial least square regression prediction accuracy soil quality spectroscopic method
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Determination of Spectrum Characteristic of Near Infrared Radiated by Indirect Moxibustion 被引量:5
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作者 杨华元 肖元春 +2 位作者 刘堂义 顾训杰 夏锦杉 《Journal of Acupuncture and Tuina Science》 2005年第6期55-57,共3页
MS96A type spectrum analyzer was applied to determine the spectral characteristic of near infrared radiated by moxa stick moxi-bustion, ginger-partitioned moxibustion, garlicpartitioned moxibustion and Aconium Carmich... MS96A type spectrum analyzer was applied to determine the spectral characteristic of near infrared radiated by moxa stick moxi-bustion, ginger-partitioned moxibustion, garlicpartitioned moxibustion and Aconium Carmichaeli-p ar titioned moxibustion. The spectrum of moxa stick moxibustion was relatively discrete and several wave crests are appeared. But in the spectrum of ginger-partitioned moxibustion, garlic-partitioned moxibustion or Aconium Carmichaeli partitioned moxibustion, a specific and relatively steady wave crest formed respectively. It was concluded different indirect moxibustion could bring respective spectrum of near infrared and have the relevant physiologic and biochemical effects. 展开更多
关键词 Indirect Moxibustion Near Infrared Spectrum ACUPUNCTURE-MOXIBUSTION
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