CeO2‐ZrO2 (CeZr) and sulfated CeO2‐ZrO2 (S‐CeZr) catalysts were prepared for the selective catalytic reduction of NO with NH3. The CeZr catalysts exhibited higher activity at low temperatures (< 200°C) and ...CeO2‐ZrO2 (CeZr) and sulfated CeO2‐ZrO2 (S‐CeZr) catalysts were prepared for the selective catalytic reduction of NO with NH3. The CeZr catalysts exhibited higher activity at low temperatures (< 200°C) and lower activity at high temperatures (> 200 °C) than the S‐CeZr catalysts. The sulfation ofCeZr was studied in terms of surface acidity, redox properties and NO adsorption‐desorption bytemperature‐dependent experiments and in situ infrared spectroscopy. S‐CeZr displayed high concentrationsof acidic sites and increased surface acidities, but poor reducibility compared with CeZr.The high acidity of S‐CeZr was attributed to the presence of Br?nsted acid sites, arising mainly fromthe surface sulfates. Because the surface was covered with sulfate species, S‐CeZr showed lower NOadsorption and weaker oxidation ability than CeZr. The adsorption of NH3 on the Br?nsted acid sites restricted the reaction with NO at low temperatures, but the selective catalytic reduction cycle occurred easily at relatively low temperatures (150 °C), and the weakly bound nitrite was partially activated on the S‐CeZr catalyst at relatively high temperatures (300 °C). The catalytic mechanisms for the CeZr and S‐CeZr catalysts at 150 and 300 °C were also studied.展开更多
High voltage pulse natural organic matter （NOM） toxic by-products. Fulvic acid discharge plasma can remove and produce no production of solution was treated by high voltage pulse discharge plasma in this paper. It w...High voltage pulse natural organic matter （NOM） toxic by-products. Fulvic acid discharge plasma can remove and produce no production of solution was treated by high voltage pulse discharge plasma in this paper. It was shown that： for the reason of thermolysis and oxidation, the pH and Oxidation Reduction Potential （ORP） of solution decreased gradually with the increase of peak voltage and fulvic acid solution concentration, meanwhile the temperature and turbidity of solution increased gradually. Adding hydrochlorid acid in the treatment could amplify the effect of plasma. When the concentration of NOM as the surrogate parameter, Ultraviolet Absorbancy Degree （UV254） increased slowly by the effect of plasma, while the degradation of Total Organic Carbon （TOC） was first-order reaction. The removal rate of TOC increased from 22.6% to 33.4% by high voltage pulse electrical field of 35 kv, and from 25.6% to 36.7% with the addition of hydrochlorid acid. This paper may provide some basis for the scale-up design of water treatment process by high voltage pulse discharge plasma with other technologies.展开更多
基金supported by the Science Fund for Yong Scholars at Changchun University of Science and Technology(XQNJJ-2014-15)~~
文摘CeO2‐ZrO2 (CeZr) and sulfated CeO2‐ZrO2 (S‐CeZr) catalysts were prepared for the selective catalytic reduction of NO with NH3. The CeZr catalysts exhibited higher activity at low temperatures (< 200°C) and lower activity at high temperatures (> 200 °C) than the S‐CeZr catalysts. The sulfation ofCeZr was studied in terms of surface acidity, redox properties and NO adsorption‐desorption bytemperature‐dependent experiments and in situ infrared spectroscopy. S‐CeZr displayed high concentrationsof acidic sites and increased surface acidities, but poor reducibility compared with CeZr.The high acidity of S‐CeZr was attributed to the presence of Br?nsted acid sites, arising mainly fromthe surface sulfates. Because the surface was covered with sulfate species, S‐CeZr showed lower NOadsorption and weaker oxidation ability than CeZr. The adsorption of NH3 on the Br?nsted acid sites restricted the reaction with NO at low temperatures, but the selective catalytic reduction cycle occurred easily at relatively low temperatures (150 °C), and the weakly bound nitrite was partially activated on the S‐CeZr catalyst at relatively high temperatures (300 °C). The catalytic mechanisms for the CeZr and S‐CeZr catalysts at 150 and 300 °C were also studied.
文摘High voltage pulse natural organic matter （NOM） toxic by-products. Fulvic acid discharge plasma can remove and produce no production of solution was treated by high voltage pulse discharge plasma in this paper. It was shown that： for the reason of thermolysis and oxidation, the pH and Oxidation Reduction Potential （ORP） of solution decreased gradually with the increase of peak voltage and fulvic acid solution concentration, meanwhile the temperature and turbidity of solution increased gradually. Adding hydrochlorid acid in the treatment could amplify the effect of plasma. When the concentration of NOM as the surrogate parameter, Ultraviolet Absorbancy Degree （UV254） increased slowly by the effect of plasma, while the degradation of Total Organic Carbon （TOC） was first-order reaction. The removal rate of TOC increased from 22.6% to 33.4% by high voltage pulse electrical field of 35 kv, and from 25.6% to 36.7% with the addition of hydrochlorid acid. This paper may provide some basis for the scale-up design of water treatment process by high voltage pulse discharge plasma with other technologies.
