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连续型超临界水氧化反应器中NaCl沉积现象与机理探讨 被引量:1
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作者 赵光明 刘玉存 +2 位作者 柴涛 王洪伟 田江霞 《现代化工》 CAS CSCD 北大核心 2015年第3期147-151,共5页
对连续型超临界水氧化装置中出现的几种有关Na Cl结晶的现象进行了系统的理论解释,对Na Cl在超临界水氧化反应器中的结晶、沉积、结块的机理进行了探讨。在温度、流场等条件较为稳定的情况下,Na Cl超临界水可能处于稳定的过饱和状态而... 对连续型超临界水氧化装置中出现的几种有关Na Cl结晶的现象进行了系统的理论解释,对Na Cl在超临界水氧化反应器中的结晶、沉积、结块的机理进行了探讨。在温度、流场等条件较为稳定的情况下,Na Cl超临界水可能处于稳定的过饱和状态而无明显结晶现象。温度突然升高、Na Cl过饱和度增加、流场扰动、壁面微孔、近壁层高温、壁面吸附、重结晶等诸多因素,都是导致Na Cl在反应器壁面结晶沉积、结块蓬起的原因,其中前3项最为重要。 展开更多
关键词 废水处理 盐沉积 超临界水氧化 连续型反应
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“一招”解决多重化学平衡中多种平衡常数计算问题 被引量:1
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作者 徐兴宇 《数理化解题研究》 2023年第4期132-134,共3页
新高考化学高频考点——多重化学平衡,涉及平衡常数计算.文章介绍了应用“三段式”计算多种平衡常数(K_(c)、K_(p)、K^(r)_(p)、K_(x))的方法.
关键词 平衡常数 连续型反应 竞争型反应 高中化学
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An aligned mixture probabilistic principal component analysis for fault detection of multimode chemical processes 被引量:5
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作者 杨雅伟 马玉鑫 +1 位作者 宋冰 侍洪波 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第8期1357-1363,共7页
A novel approach named aligned mixture probabilistic principal component analysis(AMPPCA) is proposed in this study for fault detection of multimode chemical processes. In order to exploit within-mode correlations,the... A novel approach named aligned mixture probabilistic principal component analysis(AMPPCA) is proposed in this study for fault detection of multimode chemical processes. In order to exploit within-mode correlations,the AMPPCA algorithm first estimates a statistical description for each operating mode by applying mixture probabilistic principal component analysis(MPPCA). As a comparison, the combined MPPCA is employed where monitoring results are softly integrated according to posterior probabilities of the test sample in each local model. For exploiting the cross-mode correlations, which may be useful but are inadvertently neglected due to separately held monitoring approaches, a global monitoring model is constructed by aligning all local models together. In this way, both within-mode and cross-mode correlations are preserved in this integrated space. Finally, the utility and feasibility of AMPPCA are demonstrated through a non-isothermal continuous stirred tank reactor and the TE benchmark process. 展开更多
关键词 Multimode process monitoring Mixture probabilistic principal component analysis Model alignment Fault detection
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A self-tuning control method for Wiener nonlinear systems and its application to process control problems 被引量:1
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作者 Ping Yuan Bi Zhang Zhizhong Mao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第2期193-201,共9页
Many chemical processes can be modeled as Wiener models, which consist of a linear dynamic subsystem followed by a static nonlinear block. In this paper, an effective discrete-time adaptive control method is proposed ... Many chemical processes can be modeled as Wiener models, which consist of a linear dynamic subsystem followed by a static nonlinear block. In this paper, an effective discrete-time adaptive control method is proposed for Wiener nonlinear systems with uncertainties. The parameterization model is derived based on the inverse of the nonlinear function block. The adaptive control method is motivated by self-tuning control and is derived from a modified Clarke criterion function, which considers both tracking properties and control efforts. The uncertain parameters are updated by a recursive least squares algorithm and the control law exhibits an explicit form. The closed-loop system stability properties are discussed. To demonstrate the effectiveness of the obtained results, two groups of simulation examples including an application to composition control in a continuously stirred tank reactor(CSTR) system are studied. 展开更多
关键词 Wiener systemsAdaptive controlUncertaintiesStabilityCSTR
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