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Thermal stability,crystallization behavior,Vickers hardness and magnetic properties of Fe-Co-Ni-Cr-Mo-C-B-Y bulk metallic glasses 被引量:2
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作者 韩佳甲 王翠萍 +1 位作者 寇生中 刘兴军 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第1期148-155,共8页
Thermal stability,crystallization behavior,Vickers hardness and magnetic properties of the Fe41Co7-xNixCr15Mo14C15B6Y2(x=0,1,3,5) bulk metallic glasses were investigated.The Fe41Co7-xNixCr15Mo14C15B6Y2(x=0,1,3,5) ... Thermal stability,crystallization behavior,Vickers hardness and magnetic properties of the Fe41Co7-xNixCr15Mo14C15B6Y2(x=0,1,3,5) bulk metallic glasses were investigated.The Fe41Co7-xNixCr15Mo14C15B6Y2(x=0,1,3,5) metallic glasses were fabricated by copper mold casting method.The thermal stability and crystallization behavior of the metallic glass rods were investigated by differential scanning calorimetry and isothermal experiments.Hardness measurements for samples annealed at different temperatures for different time were carried out at room temperature by the Vickers hardness tester,and magnetic measurements were performed at different temperatures by the vibrating sample magnetometer.It is shown that the addition of Ni does not play a positive role for enlarging ΔTx and GFA from parameter γ(=Tx/(Tg+Tl)),and it can,however,increase the activation energy in the initial stage of crystallization by changing the initial crystallization behavior.The minor addition of Ni can refine the crystal grain obtained from the full crystallization experiment.The primary crystallization causes the decrease of hardness in these alloys,and as the crystallization continues,the hardness in all samples increases instead due to the precipitation of carbide and boride.The annealing temperature has an obvious effect on magnetic properties of these alloys,and the minor addition of Ni can effectively prevent the alloy annealed at high temperature to transform from paramagnetic to ferromagnetic state. 展开更多
关键词 Fe-Co-Ni-Cr-C-B-Y metallic glass thermal stability annealing magnetic properties
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Ultracytochemical Localization of Acid Phosphatase in Nucellar Cells of Wheat During Degeneration 被引量:6
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作者 田国伟 申家恒 尤瑞麟 《Acta Botanica Sinica》 CSCD 1999年第8期791-794,共4页
The distribution of acid phosphatase activity in nucellar cells of wheat ( Triticum aestivum L.) during degeneration has been studied using the lead precipitation method at the electron microscopic level. Acid phos... The distribution of acid phosphatase activity in nucellar cells of wheat ( Triticum aestivum L.) during degeneration has been studied using the lead precipitation method at the electron microscopic level. Acid phosphatase was localized in the slightly condensed nuclear chromatin in nucellar cells without any sign of ultrastructural degeneration. As the nucellar cells started degenerating, the enzyme activity in the cell was observed, in the order from small vacuoles to cell walls, mitochondria, plastids and endoplasmic reticulum. Enzyme activity was the highest in most components of the nucellar cells adjacent to the embryo sac where the degeneration of nucellar cells was the strongest, but it was not observed in the nuclei of the degenerated nucellar cells. The results indicated that the degeneration of nucellar cells was a progressive and orderly process and supported that the degeneration of nucellar cells was a programmed cell death. 展开更多
关键词 Triticum aestivum Nucellar cell DEGENERATION Acid phosphatase Ultracytochemical localization
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“大容量”的诱惑——如何选择大容量电子邮件系统
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作者 刘毅鹏 《中国经济和信息化》 1999年第27期53-53,共1页
互联网上的各种服务正承受着前所未有的压力。E-mail服务作为Internet最为重要的服务之一,具有方便快捷地进行信息交流的特点。作为Internet信息服务提供者,E-mail系统能否满足大容量的要求,将是决定整个服务成败的关键。不久前,广东省... 互联网上的各种服务正承受着前所未有的压力。E-mail服务作为Internet最为重要的服务之一,具有方便快捷地进行信息交流的特点。作为Internet信息服务提供者,E-mail系统能否满足大容量的要求,将是决定整个服务成败的关键。不久前,广东省“21cn”网站与亚信公司签订了大容量电子邮件的购买合同,这使得大容量电子邮件系统再次成为ISP们关注的焦点。 展开更多
关键词 电子邮件系统 大容量 邮件列表 诱惑 管理员 电子邮件服务器 虚拟主机 亚信公司 第四层交换机 退定
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FPGA PLACEMENT OPTIMIZATION BY TWO-STEP UNIFIED GENETIC ALGORITHM AND SIMULATED ANNEALING ALGORITHM 被引量:6
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作者 Yang Meng A.E.A. Almaini Wang Pengjun 《Journal of Electronics(China)》 2006年第4期632-636,共5页
Genetic Algorithm (GA) is a biologically inspired technique and widely used to solve numerous combinational optimization problems. It works on a population of individuals, not just one single solution. As a result, it... Genetic Algorithm (GA) is a biologically inspired technique and widely used to solve numerous combinational optimization problems. It works on a population of individuals, not just one single solution. As a result, it avoids converging to the local optimum. However, it takes too much CPU time in the late process of GA. On the other hand, in the late process Simulated Annealing (SA) converges faster than GA but it is easily trapped to local optimum. In this letter, a useful method that unifies GA and SA is introduced, which utilizes the advantage of the global search ability of GA and fast convergence of SA. The experimental results show that the proposed algorithm outperforms GA in terms of CPU time without degradation of performance. It also achieves highly comparable placement cost compared to the state-of-the-art results obtained by Versatile Place and Route (VPR) Tool. 展开更多
关键词 Genetic Algorithm (GA) Simulated Annealing (SA) PLACEMENT FPGA EDA
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Microstructure and mechanical properties of Al-5.8Mg-Mn-Sc-Zr alloy after annealing treatment 被引量:1
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作者 陈琴 潘清林 +3 位作者 王迎 张志野 周坚 刘畅 《Journal of Central South University》 SCIE EI CAS 2012年第7期1785-1790,共6页
An A1-5.8Mg-0.4Mn-0.35(Sc+Zr) (mass fraction, %) alloy sheet was prepared using water chilling copper mould ingot metallurgy processing which was protected by active flux. The influence of stabilizing annealing o... An A1-5.8Mg-0.4Mn-0.35(Sc+Zr) (mass fraction, %) alloy sheet was prepared using water chilling copper mould ingot metallurgy processing which was protected by active flux. The influence of stabilizing annealing on mechanical properties and microstructure of the cold rolling sheet was studied. The results show that the strength and hardness of the alloy decrease, while the elongation increases with increasing the stabilizing annealing temperature. With the increase of stabilizing annealing time, the strength and hardness of the alloy drop slightly but its ductility exhibits no change. Partial recovery and recrystallization orderly occur with the increase of annealing temperature during stabilizing treatment. Only different degrees of recovery occur in the alloys annealed below 400 ℃ for 1 h. Partial recrystallization occurs after annealed at 450 ℃ for 1 h. By annealing at 300 ℃ for 1 h, the alloy can obtain the optimum application values of δb, δ0.2 and δ, which are 436 MPa, 327 MPa and 16.7%, respectively. 展开更多
关键词 A1-Mg-Mn-Sc-Zr alloy stabilizing treatment A13(Sc Zr) particle microstructure mechanical property
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Determination of the Financing Scale,Time Limit and Returns from the Investment in BOT Projects
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作者 Chen Shouke Wei Zhuobin 《Engineering Sciences》 EI 2008年第1期83-89,共7页
The key aspect to the successful implementation of BOT concept is the raising of finance by project sponsor,so financial engineering techniques and capital structuring skills are required to find the proper mix of deb... The key aspect to the successful implementation of BOT concept is the raising of finance by project sponsor,so financial engineering techniques and capital structuring skills are required to find the proper mix of debt and equity.The capital structure and present a model to determine the equity level from the aspects of financing scale,construction time and return on investment are analyzed.The resulting model can help the sponsor to avoid the capital risk,and offer the government a criterion to evaluate management ability of the sponsor.To show the application and availability of this model,a case study is conducted.Thus,this paper is concern with the determination of financing scale,construction time,and return on investment which would assist the sponsor to ensure that the equity level for optimal capital structure is available prior to the implementation stage in BOT project operation. 展开更多
关键词 capital risk financing scale time limit returns of investment BOT project
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Quantitative Simulation of Dynamic Changes in Cultivated Land in Areas of Reclamation and Returning Cultivated Land to Forest or Pastures under RCPs Climate Scenarios 被引量:1
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作者 刘唯清 齐元静 +1 位作者 姜群鸥 聂承静 《Agricultural Science & Technology》 CAS 2016年第1期178-187,共10页
Northeast China as one of important agricultural production bases is an area under reclamation and returning cultivated land to forests or pastures. Therefore, it is of great practical significance in guaranteeing the... Northeast China as one of important agricultural production bases is an area under reclamation and returning cultivated land to forests or pastures. Therefore, it is of great practical significance in guaranteeing the sustainable development and national food security to study the spatial and temporal variation of cultivated land in Northeast China under future climate scenarios. In this study, based on data of land use, natural environment and social-economy, dynamics of land system(DLS) model was used to to simulate the spatial distribution and changing trends of cultivated land in the typical areas of reclamation and returning cultivated land to forest or pastures in Northeast China during 2010-2030 under land use planning scenario and representative concentration pathways(RCPs) scenarios quantitatively.The results showed that the area of cultivated land had an overall decreasing trend under the land use planning scenario, but the area of upland field increased slightly from 2000 to 2010 and then declined greatly, while the area of paddy field continuously declined from 2000 to 2030. Under the Asia-Pacific Integrated model(AIM)scenario, the total area of cultivated land had a tendency to increase considerably,with the upland field expanding more obviously and the paddy field declining slightly.In addition, the cultivated land showed a greater decreasing trend under the model for energy supply strategy alternatives and their general environmental impact(MESSAGE) scenario compared to the land use planning scenario. Moreover, analysis on the conversion between different land use types indicated that the reclamation and returning cultivated land to forests or pastures was likely to continue under future scenarios, but the frequency of occurrence could decrease as the time goes by. The conclusions can provide significant decision-making information for the rational agricultural planning and cultivated land protection in Northeast China to adapt to the climate change. 展开更多
关键词 Land use Climate change Planning Cultivated land change Quantitative simulation Scenario Areas of reclamation and returning cultivated land to forest or pastures
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Restoration Prospects for Heitutan Degraded Grassland in the Sanjiangyuan 被引量:24
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作者 LI Xi-lai PERRY LW George +3 位作者 BRIERLEY Gary GAO Jay ZHANG Jing YANG Yuan-wu 《Journal of Mountain Science》 SCIE CSCD 2013年第4期687-698,共12页
In many ecosystems ungulates have coexisted with grasslands over long periods of time. However, high densities of grazing animals may change the floristic and structural characteristics of vegetation, reduce biodivers... In many ecosystems ungulates have coexisted with grasslands over long periods of time. However, high densities of grazing animals may change the floristic and structural characteristics of vegetation, reduce biodiversity, and increase soil erosion, potentially triggering abrupt and rapid changes in ecosystem condition. Alternate stable state theory provides a framework for understanding this type of dynamic. In the Sanjiangyuan atop the Qinghai-Tibetan plateau (QTP), grassland degradation has been accompanied by irruptions of native burrowing animals, which has accentuated the loss of ground cover. Severely degraded areas of alpine meadows are referred to as 'Heitutan'. Here, using the framework of alternate stable state theory, we describe the proximate and ultimate drivers of the formation of Heitutan on the QTP, and we assess prospects for recovery, in relation to the degree of biophysical alteration, of these alpine meadows. Effective rehabilitation measures must address the underlying causes of degradation rather than their symptoms. Heitutan degradation is not uni-causal. Rather it reflects different mechanisms operating at different spatio-temporal scales across this vast region. Underlying causes include overly aggressive exploitation of the grasslands (e.g. overgrazing), amplification of grazing and erosion damage by small mammals when outbreaks occur, and/or climate change. Given marked variability in environmental conditions and stressors, restorative efforts must vary across the region. Restoration efforts are likely toyield greatest success if moderately and severely degraded areas are targeted as the first priority in management programmes, before these areas are transformed into extreme Heitutan. 展开更多
关键词 Heitutan degraded grassland Alpinemeadow Restoration/rehabilitation Sanjiangyuan Qinghai-Tibet Plateau (QTP)
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Fabrication of Polymer Nonlinear Directional Coupler by Photo-bleaching 被引量:1
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作者 JIA Zhen hong (College of Information Science & Engineering, Xinjiang Univ., Urumqi 830046, CHN) 《Semiconductor Photonics and Technology》 CAS 2001年第4期217-220,246,共5页
The preparation of a nonlinear directional coupler in polymer PMMA/DR1 film by photobleaching is studied. We find it easier to obtain a required coupling length by controlling photo bleaching time than by controlling ... The preparation of a nonlinear directional coupler in polymer PMMA/DR1 film by photobleaching is studied. We find it easier to obtain a required coupling length by controlling photo bleaching time than by controlling the dimension of the coupler. The transmittance of each arm is measured when the pulse input light energy changes in our experiment. The experimental results show that the coupling length will change with the intensity of input light due to optical nonlinearities of the polymer PMMA/DR1 at 1 064 nm. 展开更多
关键词 Photo bleaching PMMA/DR1 polymer films Nonlinear directional coupler
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Quantitative Analysis on Postponement Strategies of Decoupling Points in Mass Customization
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作者 汪蓉 邵晓峰 +1 位作者 黄培清 季建华 《Journal of Donghua University(English Edition)》 EI CAS 2003年第1期74-76,共3页
The key to mass customizing effectively is postponing the deco upling point of customer order in the supply network. This paper focused on quantitative analysis on postponement strategies of multiple decoupling points... The key to mass customizing effectively is postponing the deco upling point of customer order in the supply network. This paper focused on quantitative analysis on postponement strategies of multiple decoupling points in mass customization to improve operating efficiency and quickly meet customer demands with a minimum amount of inventory. 展开更多
关键词 mass customization postponement strategy decoupling points.
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Stabilization of stochastic nonholonomic systems
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作者 KE Hai-sen YE Xu-dong 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2006年第10期1742-1747,共6页
In this work, we investigate the stabilization control design of nonholonomic stochastic system in strict-feedback form. Under the condition of all states being available for feedback, a state feedback controller was ... In this work, we investigate the stabilization control design of nonholonomic stochastic system in strict-feedback form. Under the condition of all states being available for feedback, a state feedback controller was developed via the stochastic Lyapunov-like theorem and backstepping design technique. The controllers guarantee all states of the closed-loop system are bounded in probability, and largely asymptotically stable when the stochastic disturbances equal to zero at the equilibrium point of the open-loop system. Besides, the time-varying technique was introduced to avoid the uncontrollable state of chained system. 展开更多
关键词 Time-varying technique NONHOLONOMIC BACKSTEPPING Stochastic
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Stopping and Remaking Approaches to Degradation of the Black Sea Coast in the Romanian Seaside Area
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作者 B. Cazacu D. Zarojanu 《Journal of Agricultural Science and Technology(B)》 2011年第3期448-453,共6页
There is presented a degradation case study of the Romanian shoreline belonging to the seaside of the Black Sea. The Romanian coastal Black Sea is in a continuously degradation due to the destructive action exerted by... There is presented a degradation case study of the Romanian shoreline belonging to the seaside of the Black Sea. The Romanian coastal Black Sea is in a continuously degradation due to the destructive action exerted by waves on the shore and, respectively, to the instability phenomena that manifest itself in the area. There are presented the influences of different causes of the degradation, the characteristics of the seaside shoreline and the interventions already made. There are done evolution foresights of the ground instability phenomena as well as shoreline degradation and recommend measures for rehabilitation. 展开更多
关键词 Shoreline degradation/withdrawal FLOOD seawater macro-pore soil waves influence.
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Effect of Annealing Temperatures on the Structural and Electrical Properties of Laser Induced Plasma for TiO2x-1Bix Thin Films
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作者 Sabah N. Mazhir Ghuson H. Mohamed +1 位作者 Kadhim A. Aadem Maysoon D. Radhi 《Journal of Physical Science and Application》 2016年第1期36-43,共8页
In this study, Bismuth doped Titanium dioxide thin films were deposited on glass substrates by a pulse laser deposition using laser. The effect of annealing temperature on the structural and electrical properties was ... In this study, Bismuth doped Titanium dioxide thin films were deposited on glass substrates by a pulse laser deposition using laser. The effect of annealing temperature on the structural and electrical properties was investigated. X-ray diffraction pattern for pure and doped titanium dioxide films with different doping different ratio with Bi show that these films have amorphous structure oanvert to polycrystalline structure with annealing and doping and have a good identically with standard peaks for Anatase and Rutile phases. The orientation was at specific direction for Rutile. The crystalline of films increases by the increase of doping ratio. The crystalline increased with annealing temperature. Annealed films at different annealing temperatures have been studied. The results show that these films have two activation energies and by increasing the doping ratio, the activation energies and the conductivity increase. Both the annealing and composition effects on Hall constant, density of electron carders and Hall mobility are studied. Hall Effect measurements show that all films have n- type charge conductivity and the concentration increases while the mobility decreases with doping and annealing. 展开更多
关键词 Electrical properties structural properties TiO2 thin films pulse laser deposition technique.
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Evolutions of texture and grain boundary plane distributions in a ferritic stainless steel
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作者 方晓英 王卫国 +2 位作者 郭红 秦聪祥 周邦新 《Journal of Central South University》 SCIE EI CAS 2012年第12期3363-3368,共6页
The grain size, textures and grain boundary plane distributions in a cold-rolled and annealed ferritic stainless steel were investigated by means of EBSD techniques. The results show that, following cold rolling with ... The grain size, textures and grain boundary plane distributions in a cold-rolled and annealed ferritic stainless steel were investigated by means of EBSD techniques. The results show that, following cold rolling with the thickness reduction of 85%, relatively low temperature (780℃) annealing brings an extremely sluggish grain growth and no grain texture develops when the annealing time varies from 5 min to 480 min. The free energy reduction of the system is mainly caused by the grain boundary plane re-orientation in addition to minor grain growth because the distributions of grain boundary planes are moderately preferred on { 100} according to the five parameter analyses (FPA) concerning the grain boundary plane characteristics. However, in the case of high-temperature (1 000 ℃) annealing, the average grain size does not increase until annealing time is prolonged to 90 min, after which extensive grain growth occurs and strong {100}(hkl) texture emerges whereas nearly random grain boundary plane distributions are observed. The free energy reduction of the system is most likely attributed to the selective growth. 展开更多
关键词 grain texture grain boundary plane EBSD ferritic stainless steel
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The Degenerated Second Main Theorem and Schmidt's Subspace Theorem 被引量:4
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作者 CHEN ZhiHua RU Min YAN QiMing 《Science China Mathematics》 SCIE 2012年第7期1367-1380,共14页
In this paper, we establish a Second Main Theorem for an algebraically degenerate holomorphic curve f : C → Pn(C) intersecting hypersurfaces in general position. The related Diophantine problems are also considered.
关键词 Nevanlinna theory holomorphic curve Second Main Theorem Diophantine approximation Schmidt's Subspace Theorem
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A note on the ill-posedness of shear flow for the MHD boundary layer equations 被引量:2
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作者 Cheng-Jie Liu Feng Xie Tong Yang 《Science China Mathematics》 SCIE CSCD 2018年第11期2065-2078,共14页
For the two-dimensional Magnetohydrodynamics(MHD)boundary layer system,it has been shown that the non-degenerate tangential magnetic field leads to the well-posedness in Sobolev spaces and high Reynolds number limits ... For the two-dimensional Magnetohydrodynamics(MHD)boundary layer system,it has been shown that the non-degenerate tangential magnetic field leads to the well-posedness in Sobolev spaces and high Reynolds number limits without any monotonicity condition on the velocity field in our previous works.This paper aims to show that sufficient degeneracy in the tangential magnetic field at a non-degenerate critical point of the tangential velocity field of shear flow indeed yields instability as for the classical Prandtl equations without magnetic field studied by G′erard-Varet and Dormy(2010).This partially shows the necessity of the non-degeneracy in the tangential magnetic field for the stability of the boundary layer of MHD in 2D at least in Sobolev spaces. 展开更多
关键词 MHD boundary layer Prandtl equations shear flows ILL-POSEDNESS Sobolev spaces
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DEGENERATE SEMI-GROUP METHODS FOR THE EXPONENTIAL STABILITY OF THE FIRST ORDER SINGULAR DISTRIBUTED PARAMETER SYSTEMS 被引量:13
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作者 Zhaoqiang GE Guangtian ZHU Dexing FENG 《Journal of Systems Science & Complexity》 SCIE EI CSCD 2008年第2期260-266,共7页
Exponential stability of the first order singular distributed parameter systems is discussedin the light of degenerate semi-group methods,which is described by the abstract developing equationin Hilbert space.The nece... Exponential stability of the first order singular distributed parameter systems is discussedin the light of degenerate semi-group methods,which is described by the abstract developing equationin Hilbert space.The necessary and sufficient conditions concerning the exponential stability of thefirst order singular distributed parameter systems are given. 展开更多
关键词 Degenerate semi-group exponential stability first order singular distributed parameter systems.
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ASYMPTOTIC NORMALITY OF SOME ESTIMATORS IN A FIXED-DESIGN SEMIPARAMETRIC REGRESSION MODEL WITH LINEAR TIME SERIES ERRORS 被引量:10
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作者 JinhongYOU CHENMin GemaiCHEN 《Journal of Systems Science & Complexity》 SCIE EI CSCD 2004年第4期511-522,共12页
Consider a semiparametric regression model with linear time series errors Y_k= x′ _kβ + g(t_k) + ε_k, 1 ≤ k ≤ n, where Y_k's are responses, x_k =(x_(k1),x_(k2),···,x_(kp))′ and t_k ∈ T is con... Consider a semiparametric regression model with linear time series errors Y_k= x′ _kβ + g(t_k) + ε_k, 1 ≤ k ≤ n, where Y_k's are responses, x_k =(x_(k1),x_(k2),···,x_(kp))′ and t_k ∈ T is contained in R are fixed design points, β =(β_1,β_2,···,β_p)′ is an unknown parameter vector, g(·) is an unknown bounded real-valuedfunction defined on a compact subset T of the real line R, and ε_k is a linear process given byε_k = ∑ from j=0 to ∞ of ψ_je_(k-j), ψ_0=1, where ∑ from j=0 to ∞ of |ψ_j| < ∞, and e_j,j=0, +-1, +-2,···, ard i.i.d. random variables. In this paper we establish the asymptoticnormality of the least squares estimator of β, a smooth estimator of g(·), and estimators of theautocovariance and autocorrelation functions of the linear process ε_k. 展开更多
关键词 semiparametric regression model fixed-design asymptotic normality lineartime series errors
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Influence of lumbar disc degeneration on the efficacy of lumbar fixed-point rotation manipulation in sitting position:a finite element study 被引量:7
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作者 陈金凤 舒新农 +2 位作者 唐树杰 吴英 张玉佩 《Journal of Acupuncture and Tuina Science》 CSCD 2016年第4期295-299,共5页
Objective:To investigate the influence of lumbar disc degeneration on the efficacy of lumbar fixed-point rotation manipulation in sitting position in treating lumbar intervertebral disc herniation(LIDH).Methods:We... Objective:To investigate the influence of lumbar disc degeneration on the efficacy of lumbar fixed-point rotation manipulation in sitting position in treating lumbar intervertebral disc herniation(LIDH).Methods:We simulated lumbar fixed-point rotation manipulation of sitting position using three finite element models including a normal model,a mild degeneration model and a moderate degeneration model of L3-5,in which the herniated disc was assumed at the left rear of L4 disc and the rotation manipulation was carried out on the right side.The displacement and stress at the left rear of L4 disc of the three models were analyzed.Results:When lumbar fixed-point rotation manipulation in sitting position was carried out,a displacement and stress were generated at the left rear of L4 intervertebral disc of the three models directing forward.The displacement and stress in degeneration models were less than those in the normal model,and the smallest values were found in the moderate degeneration model.From normal model to mild and then to the moderate degeneration model,the displacement decreased by 36% and 59%,and the stress decreased by 22.3% and 45.2%,respectively.Conclusion:The lumbar disc degeneration affects adversely the effectiveness of lumbar fixed-point rotation manipulation in sitting position in the treatment of LIDH.The severer the lumbar degeneration,the greater the influence. 展开更多
关键词 TUINA MASSAGE Intervertebral Disc Degeneration Lumbar Fixed-point Rotation Manipulation in Sitting Position Finite Element Analysis
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Synthesis of Large Area, Homogeneous, Single Layer Graphene Films by Annealing Amorphous Carbon on Co and Ni 被引量:5
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作者 Carlo M. Orofeo Hiroki Ago +1 位作者 Baoshan Hu Masaharu Tsuji 《Nano Research》 SCIE EI CAS CSCD 2011年第6期531-540,共10页
The synthesis of large area, homogenous, single layer graphene on cobalt (Co) and nickel (Ni) is reported. The process involves vacuum annealing of sputtered amorphous carbon (a-C) deposited on Co/sapphire or Ni... The synthesis of large area, homogenous, single layer graphene on cobalt (Co) and nickel (Ni) is reported. The process involves vacuum annealing of sputtered amorphous carbon (a-C) deposited on Co/sapphire or Ni/sapphire substrates. The improved crystallinity of the metal film, assisted by the sapphire substrate, proves to be the key to the quality of as-grown graphene film. The crystallinity of the Co and Ni metal films was improved by sputtering the metal at elevated temperature as was verified by X-ray diffraction (XRD). After sputtering of a-C and annealing, large area, single layer graphene that occupies almost the entire area of the substrate was produced. With this method, 100 mm2-area single layer graphene can be synthesized and is limited only by the substrate and vacuum chamber size. The homogeneity of the graphene film is not dependent on the cooling rate, in contrast to syntheses using polycrystalline metal films and conventional chemical vapor deposition (CVD) growth. Our facile method of producing single layer graphene on Co and Ni metal films should lead to large scale graphene-based applications. 展开更多
关键词 Single layer graphene amorphous carbon epitaxial metal ANNEALING
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