Water-based rechargeable metal-air batteries play an important role in the storage and conversion of renewable electric energy.However,the sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution re...Water-based rechargeable metal-air batteries play an important role in the storage and conversion of renewable electric energy.However,the sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)have limited the practical application of rechargeable metal-air batteries.Most of reviews were focused on single functional electrocatalysts while few on bifunctional electrocatalysts.It is indispensable but challenging to design a bifunctional electrocatalyst that is active and stable to the two reactions.Recently,attempts to develop high active bifunctional electrocatalysts for both ORR and OER increase rapidly.Much work is focused on the micro-nano design of advanced structures to improve the performance of bifunctional electrocatalyst.Transition-metal materials,carbon materials and composite materials,and the methods developed to prepare micro-nano structures,such as electrochemical methods,chemical vapor deposition,hydrothermal methods and template methods are reported in literatures.Additionally,many strategies,such as adjustments of electronic structures,oxygen defects,metal-oxygen bonds,interfacial strain,nano composites,heteroatom doping etc.,have been used extensively to design bifunctional electrocatalysts.To well understand the achievements in the recent literatures,this review focuses on the micro-nano structural design of materials,and the related methods and strategies are classed into two groups for the improvement of intrinsic and apparent activities.The fine adjustment of nano structures and an in-depth understanding of the reaction mechanism are also discussed briefly.展开更多
Converters with pulse width modulation are used for connections between the direct current (DC) and alternating current (AC) networks, e.g., in uninterrupted power supply systems, AC electromotor drives, for power...Converters with pulse width modulation are used for connections between the direct current (DC) and alternating current (AC) networks, e.g., in uninterrupted power supply systems, AC electromotor drives, for powering induction furnaces, in audio technique. Spectrum of signals sampled by pulse amplitude modulation and output voltage spectrum of the converter with pulse width modulation have similar properties. Spectrum of signals sampled by pulse amplitude modulation contains a harmonic of frequency equal to the frequency of the modulating signal and the harmonics of frequencies equal to the sum of frequency of the modulating signal and multiples of the sampling frequency. The output voltage spectrum of the converter with bipolar pulse width modulation contains harmonic of frequency equal to the frequency of the modulating signal and harmonics of frequencies equal to sum of the frequency of the modulating signal and multiples of the frequency of the carrier signal. It also contains harmonics of frequencies equal to the sum of the multiples of the frequency of the modulating signal and the multiples of the carrier signal. The comparison analysis was carried out for the harmonics of the output voltage of the converter with bipolar pulse width modulation in time domain. The dependency of the amplitudes and frequency spectrum on the wave forms of the carrier signal and modulating signal was shown. Similarity of the output voltage spectrum of the converter and signal spectrum sampled by the pulse width modulation was also shown. Key words: Output voltage converter with bipolar pulse width modulation, spectral analysis, Fourier series, carrier signal, reference signal.展开更多
Modeling method for the current control loop of a grid-connected PWM inverter with the LCL output filter was discussed.Firstly,the current control loop with the LCL inverter-side current as feedback was established.Th...Modeling method for the current control loop of a grid-connected PWM inverter with the LCL output filter was discussed.Firstly,the current control loop with the LCL inverter-side current as feedback was established.Then,parameters of PI controller were calculated on the basis of an equivalent controlled object.Finally,Norton equivalent circuit for the current control loop of grid-connected system was derived by integrating one control equation,which connected the PWM inverter output voltage and the LCL inverter-side current,with two circuit equations,separately using the LCL inverter-side current and the injected current as loop currents.With the induced Norton equivalent circuit,system-level resonant and unstable issues on real grid-connected system applied in weak distributed power systems can be easily analyzed.The validity of substituting Norton equivalent circuit for grid-connected system is verified by simulation and experiment.展开更多
This paper proposes a novel method for estimating the sparse inverse covariance matrixfor longitudinal data with informative dropouts. Based on the modified Cholesky decomposition,the sparse inverse covariance matrix ...This paper proposes a novel method for estimating the sparse inverse covariance matrixfor longitudinal data with informative dropouts. Based on the modified Cholesky decomposition,the sparse inverse covariance matrix is modelled by the autoregressive regression model,which guarantees the positive definiteness of the covariance matrix. To account for the informativedropouts, we then propose a penalized estimating equation method using the inverse probabilityweighting approach. The informative dropout propensity parameters are estimated by the generalizedmethod of moments. The asymptotic properties are investigated for the resulting estimators.Finally, we illustrate the effectiveness and feasibility of the proposed method through Monte Carlosimulations and a practical application.展开更多
The entransy theory has been applied to the analyses of heat-work conversion systems. The physical meaning and the applications of work entransy are analyzed and discussed in this paper. Work entransy, which is clarif...The entransy theory has been applied to the analyses of heat-work conversion systems. The physical meaning and the applications of work entransy are analyzed and discussed in this paper. Work entransy, which is clarified to be a process dependent quantity, is not the entransy of work, but the system entransy change accompanying work transfer. The relationship between the work entransy and the output work is set up. When the application preconditions are satisfied, larger work entransy leads to larger output work. Entransy loss, which was proposed and applied to heat work conversion processes with irreversible heat transfer, is the net entransy flow into the system and the summation of work entransy and entransy dissipation. The application preconditions of entransy loss are also discussed.展开更多
In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objecti...In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objectives, and the relationships of the output power, the heat-work conversion efficiency, the entropy generation rate, the entropy generation numbers, the entransy loss rate, the entransy loss coefficient, the entransy dissipation rate and the entransy variation rate associated with work are discussed. The applicability of the entropy generation minimization and the entransy theory to the analyses is also analyzed. It is found that smaller entropy generation rate does not always lead to larger output power, while smaller entropy generation numbers do not always lead to larger heat-work conversion efficiency, either. In our calculations, both larger entransy loss rate and larger entransy variation rate associated with work correspond to larger output power, while larger entransy loss coefficient results in larger heat-work conversion efficiency. It is also found that the concept of entransy dissipation is not always suitable for the analyses because it was developed for heat transfer.展开更多
The analysis and the design of turbojet engines are of great importance to the improvement of the system performance.Many researchers focus on these topics,and many important and interesting results have been obtained...The analysis and the design of turbojet engines are of great importance to the improvement of the system performance.Many researchers focus on these topics,and many important and interesting results have been obtained.In this paper,the thermodynamic cycle in a turbojet engine is analyzed with the entransy theory and the T-Q diagram.The ideal thermodynamic cycle in which there is no inner irreversibility is analyzed,as well as the influences from some inner irreversible factors,such as the heat transfer process,the change of the component of the working fluid and the viscosity of the working fluid.For the discussed cases,it is shown that larger entransy loss rate always results in larger output power,while smaller entropy generation rate does not always.The corresponding T-Q diagrams are also presented,with which the change tendencies of the entransy loss rate and the output power can be shown very intuitively.It is shown that the entransy theory is applicable for analyzing the inner irreversible thermodynamic cycles discussed in this paper.Compared with the concept of entropy generation,the concept of entransy loss and the corresponding T-Q diagram are more suitable for describing the change of the output power of the analyzed turbojet engine no matter if the inner irreversible factors are considered.展开更多
The bias stability of differential interferometric fiber optical gyroscope is analyzed.Thermal error causing long-term bias drift are reduced by putting the 90°splice in the middle of the fiber coil and applying ...The bias stability of differential interferometric fiber optical gyroscope is analyzed.Thermal error causing long-term bias drift are reduced by putting the 90°splice in the middle of the fiber coil and applying a wide spectrum light source.Also,a kind of novel optical differential processing,which is much more precise than the electronic differential processing,is proposed for reducing the residual nonreciprocal error in the final differential output.An experimental setup based on optical differential processing was built.An^100 fold reduction in the long-term bias drift is demonstrated experimentally compared with the primary differential interferometric fiber optical gyroscope.展开更多
基金the financial supports from the National Natural Science Foundation of China(91545202,U1508203)the Strategic Priority Research Program of the Chinese Academy of Sciences(CAS)(XDB17000000)+1 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciencesthe Liaoning Revitalization Talents Program(XLYC1807066)~~
文摘Water-based rechargeable metal-air batteries play an important role in the storage and conversion of renewable electric energy.However,the sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)have limited the practical application of rechargeable metal-air batteries.Most of reviews were focused on single functional electrocatalysts while few on bifunctional electrocatalysts.It is indispensable but challenging to design a bifunctional electrocatalyst that is active and stable to the two reactions.Recently,attempts to develop high active bifunctional electrocatalysts for both ORR and OER increase rapidly.Much work is focused on the micro-nano design of advanced structures to improve the performance of bifunctional electrocatalyst.Transition-metal materials,carbon materials and composite materials,and the methods developed to prepare micro-nano structures,such as electrochemical methods,chemical vapor deposition,hydrothermal methods and template methods are reported in literatures.Additionally,many strategies,such as adjustments of electronic structures,oxygen defects,metal-oxygen bonds,interfacial strain,nano composites,heteroatom doping etc.,have been used extensively to design bifunctional electrocatalysts.To well understand the achievements in the recent literatures,this review focuses on the micro-nano structural design of materials,and the related methods and strategies are classed into two groups for the improvement of intrinsic and apparent activities.The fine adjustment of nano structures and an in-depth understanding of the reaction mechanism are also discussed briefly.
文摘Converters with pulse width modulation are used for connections between the direct current (DC) and alternating current (AC) networks, e.g., in uninterrupted power supply systems, AC electromotor drives, for powering induction furnaces, in audio technique. Spectrum of signals sampled by pulse amplitude modulation and output voltage spectrum of the converter with pulse width modulation have similar properties. Spectrum of signals sampled by pulse amplitude modulation contains a harmonic of frequency equal to the frequency of the modulating signal and the harmonics of frequencies equal to the sum of frequency of the modulating signal and multiples of the sampling frequency. The output voltage spectrum of the converter with bipolar pulse width modulation contains harmonic of frequency equal to the frequency of the modulating signal and harmonics of frequencies equal to sum of the frequency of the modulating signal and multiples of the frequency of the carrier signal. It also contains harmonics of frequencies equal to the sum of the multiples of the frequency of the modulating signal and the multiples of the carrier signal. The comparison analysis was carried out for the harmonics of the output voltage of the converter with bipolar pulse width modulation in time domain. The dependency of the amplitudes and frequency spectrum on the wave forms of the carrier signal and modulating signal was shown. Similarity of the output voltage spectrum of the converter and signal spectrum sampled by the pulse width modulation was also shown. Key words: Output voltage converter with bipolar pulse width modulation, spectral analysis, Fourier series, carrier signal, reference signal.
基金Project(51307009)supported by the National Natural Science Foundation of ChinaProject(12JJ4045)supported by Hunan Provincial Natural Science Foundation,China+2 种基金Project(2011KFJJ003)supported by the Key Laboratory for Power Technology of Renewable Energy Sources of Hunan Province,ChinaProject(2011kfj14)supported by the Fund of Key Laboratory of Hunan Province about Power System Operation and Control,ChinaProject(454.13S-20)supported by the Enterprises’Postdoctoral Funds of Pudong Area of Shanghai,China
文摘Modeling method for the current control loop of a grid-connected PWM inverter with the LCL output filter was discussed.Firstly,the current control loop with the LCL inverter-side current as feedback was established.Then,parameters of PI controller were calculated on the basis of an equivalent controlled object.Finally,Norton equivalent circuit for the current control loop of grid-connected system was derived by integrating one control equation,which connected the PWM inverter output voltage and the LCL inverter-side current,with two circuit equations,separately using the LCL inverter-side current and the injected current as loop currents.With the induced Norton equivalent circuit,system-level resonant and unstable issues on real grid-connected system applied in weak distributed power systems can be easily analyzed.The validity of substituting Norton equivalent circuit for grid-connected system is verified by simulation and experiment.
基金supported by the National Natural Science Foundation of China(Grant No.12171450).
文摘This paper proposes a novel method for estimating the sparse inverse covariance matrixfor longitudinal data with informative dropouts. Based on the modified Cholesky decomposition,the sparse inverse covariance matrix is modelled by the autoregressive regression model,which guarantees the positive definiteness of the covariance matrix. To account for the informativedropouts, we then propose a penalized estimating equation method using the inverse probabilityweighting approach. The informative dropout propensity parameters are estimated by the generalizedmethod of moments. The asymptotic properties are investigated for the resulting estimators.Finally, we illustrate the effectiveness and feasibility of the proposed method through Monte Carlosimulations and a practical application.
基金supported by the National Natural Science Foundation of China(Grant No.51376101)the Science Fund for Creative Research Groups(Grant No.51321002)
文摘The entransy theory has been applied to the analyses of heat-work conversion systems. The physical meaning and the applications of work entransy are analyzed and discussed in this paper. Work entransy, which is clarified to be a process dependent quantity, is not the entransy of work, but the system entransy change accompanying work transfer. The relationship between the work entransy and the output work is set up. When the application preconditions are satisfied, larger work entransy leads to larger output work. Entransy loss, which was proposed and applied to heat work conversion processes with irreversible heat transfer, is the net entransy flow into the system and the summation of work entransy and entransy dissipation. The application preconditions of entransy loss are also discussed.
基金supported by the Scientific and Technological Research Program of Chongqing Municipal Education Commission(Grant No.KJ1710251)
文摘In this paper, the endoreversible Otto cycle is analyzed with the entropy generation minimization and the entransy theory. The output power and the heat-work conversion efficiency are taken as the optimization objectives, and the relationships of the output power, the heat-work conversion efficiency, the entropy generation rate, the entropy generation numbers, the entransy loss rate, the entransy loss coefficient, the entransy dissipation rate and the entransy variation rate associated with work are discussed. The applicability of the entropy generation minimization and the entransy theory to the analyses is also analyzed. It is found that smaller entropy generation rate does not always lead to larger output power, while smaller entropy generation numbers do not always lead to larger heat-work conversion efficiency, either. In our calculations, both larger entransy loss rate and larger entransy variation rate associated with work correspond to larger output power, while larger entransy loss coefficient results in larger heat-work conversion efficiency. It is also found that the concept of entransy dissipation is not always suitable for the analyses because it was developed for heat transfer.
基金supported by the National Natural Science Foundation of China(Grant Nos.51376101&51356001)
文摘The analysis and the design of turbojet engines are of great importance to the improvement of the system performance.Many researchers focus on these topics,and many important and interesting results have been obtained.In this paper,the thermodynamic cycle in a turbojet engine is analyzed with the entransy theory and the T-Q diagram.The ideal thermodynamic cycle in which there is no inner irreversibility is analyzed,as well as the influences from some inner irreversible factors,such as the heat transfer process,the change of the component of the working fluid and the viscosity of the working fluid.For the discussed cases,it is shown that larger entransy loss rate always results in larger output power,while smaller entropy generation rate does not always.The corresponding T-Q diagrams are also presented,with which the change tendencies of the entransy loss rate and the output power can be shown very intuitively.It is shown that the entransy theory is applicable for analyzing the inner irreversible thermodynamic cycles discussed in this paper.Compared with the concept of entropy generation,the concept of entransy loss and the corresponding T-Q diagram are more suitable for describing the change of the output power of the analyzed turbojet engine no matter if the inner irreversible factors are considered.
基金supported by the National Natural Science Foundation of China(Grant No.61205077)
文摘The bias stability of differential interferometric fiber optical gyroscope is analyzed.Thermal error causing long-term bias drift are reduced by putting the 90°splice in the middle of the fiber coil and applying a wide spectrum light source.Also,a kind of novel optical differential processing,which is much more precise than the electronic differential processing,is proposed for reducing the residual nonreciprocal error in the final differential output.An experimental setup based on optical differential processing was built.An^100 fold reduction in the long-term bias drift is demonstrated experimentally compared with the primary differential interferometric fiber optical gyroscope.