针对层析介质的孔径分析,基于刚性球状分子进入柱状孔的假设,分别采用高斯正态分布和对数正态分布描述孔径分布,利用简化的单孔分配因子模型,建立了孔径分布函数和分配因子Kd的关联,通过体积排阻层析实验测定系列标准物的Kd,从而拟合得...针对层析介质的孔径分析,基于刚性球状分子进入柱状孔的假设,分别采用高斯正态分布和对数正态分布描述孔径分布,利用简化的单孔分配因子模型,建立了孔径分布函数和分配因子Kd的关联,通过体积排阻层析实验测定系列标准物的Kd,从而拟合得到孔径分布信息,建立了逆体积排阻层析法。以葡聚糖作为分子大小的标准物,测定了5种典型层析介质(SP Sepharose FAST FLOW、Q Sepharose FAST FLOW、ToyopearlDEAE-650M、Streamline DEAE和Sephadex G-150)的Kd,计算和比较了不同介质的孔径分布,分析了介质的可吸附孔表面积等结构参数,证实了逆体积排阻层析法分析层析介质孔径分布的可行性和实用性。展开更多
The Kebao coal basin is located at the middle segment of the Xiaojiang fault zone in the central part of Yunnan Province. The coal-bearing strata of Tertiary age are made up of alluvial fan-lacustrine-swamp genetic se...The Kebao coal basin is located at the middle segment of the Xiaojiang fault zone in the central part of Yunnan Province. The coal-bearing strata of Tertiary age are made up of alluvial fan-lacustrine-swamp genetic sequences. Sinistral strike-slip motion of the N-S trending fault zone has created a locally transtensional or transpres sional tectonic environment, giving rise to the relative movement of fault blocks in the basement, and the development of a strike-slip coal basin at the surface. Based on de tailed sedimentary-structural analyses, the paper proposes geodynamic models for the coal basin formation and its deformation.展开更多
文摘针对层析介质的孔径分析,基于刚性球状分子进入柱状孔的假设,分别采用高斯正态分布和对数正态分布描述孔径分布,利用简化的单孔分配因子模型,建立了孔径分布函数和分配因子Kd的关联,通过体积排阻层析实验测定系列标准物的Kd,从而拟合得到孔径分布信息,建立了逆体积排阻层析法。以葡聚糖作为分子大小的标准物,测定了5种典型层析介质(SP Sepharose FAST FLOW、Q Sepharose FAST FLOW、ToyopearlDEAE-650M、Streamline DEAE和Sephadex G-150)的Kd,计算和比较了不同介质的孔径分布,分析了介质的可吸附孔表面积等结构参数,证实了逆体积排阻层析法分析层析介质孔径分布的可行性和实用性。
文摘The Kebao coal basin is located at the middle segment of the Xiaojiang fault zone in the central part of Yunnan Province. The coal-bearing strata of Tertiary age are made up of alluvial fan-lacustrine-swamp genetic sequences. Sinistral strike-slip motion of the N-S trending fault zone has created a locally transtensional or transpres sional tectonic environment, giving rise to the relative movement of fault blocks in the basement, and the development of a strike-slip coal basin at the surface. Based on de tailed sedimentary-structural analyses, the paper proposes geodynamic models for the coal basin formation and its deformation.
