卷烟吸阻是卷烟设计制造中的核心指标。因涉及影响因素多且具有复杂的非线性特性,无论是基于多孔介质流体力学模型还是基于大量工程实践的经验模型,均无法定量指导设计与生产,至今卷烟吸阻仍以实验测试数据为评价依据。针对卷烟生产过...卷烟吸阻是卷烟设计制造中的核心指标。因涉及影响因素多且具有复杂的非线性特性,无论是基于多孔介质流体力学模型还是基于大量工程实践的经验模型,均无法定量指导设计与生产,至今卷烟吸阻仍以实验测试数据为评价依据。针对卷烟生产过程中产生的大量检测数据及数据的复杂多源和不断更迭的特性,提出了一种利用生产历史积累数据,通过K均值聚类算法清洗数据消除样本差异,结合自适应套索方法对输入变量进行降维处理和辅助变量选择,并利用选择稳定性评估对过程进行一致性约束,在多源数据和滚动过程一致选择出与吸阻原理模型匹配的关键影响指标,并将其作为径向基函数神经网络(RBFNN,radical basis function netural network)的输入,建立吸阻的推理预测模型。经验证,预测模型的均方误差为0.004,相对误差率控制在3%以内,实现了生产场景下的吸阻快速预测。展开更多
The numerical calculation method is widely used in the evaluation of slope stability,but it cannot take the randomness and fuzziness into account that exist in rock and soil engineering objectively.The fuzzy optimizat...The numerical calculation method is widely used in the evaluation of slope stability,but it cannot take the randomness and fuzziness into account that exist in rock and soil engineering objectively.The fuzzy optimization theory is thus introduced to the evaluation of slope stability by this paper and a method of fuzzy optimal selection of similar slopes is put forward to analyze slope stability.By comparing the relative membership degrees that the evaluated object sample of slope is similar to the source samples of which the stabilities are detected clearly,the source sample with the maximal relative membership degree will be chosen as the best similar one to the object sample,and the stability of the object sample can be evaluated by that of the best similar source sample.In the process many uncertain influential factors are considered and characteristics and knowledge of the source samples are obtained.The practical calculation indicates that it can achieve good results to evaluate slope stability by using this method.展开更多
A clustering scheme based on pure V2V communications has two prominent issues i.e. broadcast storm and network disconnection. The application of the fifth generation(5G) technology to vehicular networks is an optimal ...A clustering scheme based on pure V2V communications has two prominent issues i.e. broadcast storm and network disconnection. The application of the fifth generation(5G) technology to vehicular networks is an optimal choice due to its wide coverage and low latency features. In this paper, a Multihop Moving Zone(MMZ) clustering scheme is proposed by combining IEEE 802.11p with the 3rd Generation Partnership Project(3GPP) 5G cellular technology. In MMZ, vehicles are clustered up-to three hops using V2V communications based on IEEE 802.11 p aiming to reduce excessive cellular hand-off cost. While the zonal heads(ZHs) i.e. cluster heads(CHs) are selected by cellular-V2X(C-V2X) on the basis of multi-metrics i.e. relative speed, distance and link life time(LLT). The main goal of MMZ is to form stable clusters achieving high packet delivery and low latency. The simulation results using ns3 show that, 5G wide range technology significantly improves the stability of MMZ in term of ZH duration and change rate. The average Data Packet Delivery Ratio(DPDR) and E2E latency are also improved as compared to the existing clustering schemes.展开更多
The low‐temperature hydrothermal stabilities of Cu‐SAPO‐34samples with various Si contents and Cu loadings were systematically investigated.The NH3oxidation activities and NH3‐selective catalytic reduction(SCR)act...The low‐temperature hydrothermal stabilities of Cu‐SAPO‐34samples with various Si contents and Cu loadings were systematically investigated.The NH3oxidation activities and NH3‐selective catalytic reduction(SCR)activities(mainly the low‐temperature activities)of all the Cu‐SAPO‐34catalysts declined after low‐temperature steam treatment(LTST).These results show that the texture and acid density of Cu‐SAPO‐34can be better preserved by increasing the Cu loading,although the hydrolysis of Si-O-Al bonds is inevitable.The stability of Cu ions and the stability of the SAPO framework were positively correlated at relatively low Cu loadings.However,a high Cu loading(e.g.,3.67wt%)resulted in a significant decrease in the number of isolated Cu ions.Aggregation of CuO particles also occurred during the LTST,which accounts for the decreasing NH3oxidation activities of the catalysts.Among the catalysts,Cu‐SAPO‐34with a high Si content and medium Cu content(1.37wt%)showed the lowest decrease in NH3‐SCR because its Cu2+content was well retained and its acid density was well preserved.展开更多
An input-output signal selection based on Phillips-Heffron model of a parallel high voltage alternative current/high voltage direct current(HVAC/HVDC) power system is presented to study power system stability. It is w...An input-output signal selection based on Phillips-Heffron model of a parallel high voltage alternative current/high voltage direct current(HVAC/HVDC) power system is presented to study power system stability. It is well known that appropriate coupling of inputs-outputs signals in the multivariable HVDC-HVAC system can improve the performance of designed supplemetary controller. In this work, different analysis techniques are used to measure controllability and observability of electromechanical oscillation mode. Also inputs–outputs interactions are considered and suggestions are drawn to select the best signal pair through the system inputs-outputs. In addition, a supplementary online adaptive controller for nonlinear HVDC to damp low frequency oscillations in a weakly connected system is proposed. The results obtained using MATLAB software show that the best output-input for damping controller design is rotor speed deviation as out put and phase angle of rectifier as in put. Also response of system equipped with adaptive damping controller based on HVDC system has appropriate performance when it is faced with faults and disturbance.展开更多
The high-temperature(HT) and low-temperature(LT) hydrothermal stabilities of molecular-sieve-based catalysts are important for the selective catalytic reduction of NOx with ammonia(NH3-SCR). In this paper, we report a...The high-temperature(HT) and low-temperature(LT) hydrothermal stabilities of molecular-sieve-based catalysts are important for the selective catalytic reduction of NOx with ammonia(NH3-SCR). In this paper, we report a catalyst, Cu2+ loading SAPO-17, synthesized using cyclohexylamine(CHA), which is commercially available and inexpensive and is utilized in NH3-SCR reduction for the first time. After systematic investigations on the optimization of Si and Cu2+ contents, it was concluded that Cu-SAPO-17-8.0%-0.22 displays favorable catalytic performance, even after being heated at 353 K for 24 h and at 973 K for 16 h. Moreover, the locations of CHAs, host–guest interaction and the Bronsted acid sites were explored by Rietveld refinement against powder X-ray diffraction data of as-made SAPO-17-8.0%. The refinement results showed that two CHAs exist within one eri cage and that the protonated CHA forms a hydrogen bond with O4, which indicates that the proton bonding with O4 will form the Bronsted acid site after the calcination.展开更多
The research process,main contents,methods and conclusions for some major engineering geological problems of the Three Gorges Project (TGP) are reviewed and introduced,including dam site selection,regional tectonic st...The research process,main contents,methods and conclusions for some major engineering geological problems of the Three Gorges Project (TGP) are reviewed and introduced,including dam site selection,regional tectonic stability and seismic activity,stability of reservoir bank and reservoir-induced earthquake.Meanwhile,the above mentioned engineering geological problems are evaluated according to the preliminary test results since TGP operation and impoundment in 2003.展开更多
The performance of ion-exchange resin catalysts during isobutene (IB) dimerization was investigated under different IB contents,temperatures and liquid-volume hourly space velocity (LHSV) using a plug flow reactor in ...The performance of ion-exchange resin catalysts during isobutene (IB) dimerization was investigated under different IB contents,temperatures and liquid-volume hourly space velocity (LHSV) using a plug flow reactor in the absence of any selectivity enhancing component.High IB content and temperature resulted in a high conversion and C12 selectivity bu low C8 selectivity.The influence of LHSV was related with the IB content:LHSV had great effect at high IB content,while the performance of ion-exchange resin changed little with LHSV if IB content was low.The effect of water on the stability of resins was also studied.Desulfonation was observed during the C4 dimerization reaction when water was added to the feed.Chlorinated resin was more stable than conventional polystyrene-based resins during the test.展开更多
Various mathematical models have been commonly used in time series analysis and forecasting. In these processes, academic researchers and business practitioners often come up against two important problems. One is whe...Various mathematical models have been commonly used in time series analysis and forecasting. In these processes, academic researchers and business practitioners often come up against two important problems. One is whether to select an appropriate modeling approach for prediction purposes or to combine these different individual approaches into a single forecast for the different/dissimilar modeling approaches. Another is whether to select the best candidate model for forecasting or to mix the various candidate models with different parameters into a new forecast for the same/similar modeling approaches. In this study, we propose a set of computational procedures to solve the above two issues via two judgmental criteria. Meanwhile, in view of the problems presented in the literature, a novel modeling technique is also proposed to overcome the drawbacks of existing combined forecasting methods. To verify the efficiency and reliability of the proposed procedure and modeling technique, the simulations and real data examples are conducted in this study.The results obtained reveal that the proposed procedure and modeling technique can be used as a feasible solution for time series forecasting with multiple candidate models.展开更多
The present study reports a highly selective and stable catalytic approach for producing tetralin, an important chemical, solvent, and H2 storage material. Transition metal phosphides (MOP, Ni2P, Co2P, and Fe2P) wer...The present study reports a highly selective and stable catalytic approach for producing tetralin, an important chemical, solvent, and H2 storage material. Transition metal phosphides (MOP, Ni2P, Co2P, and Fe2P) were prepared by wet impregnation and temperature-programmed reduction and characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), EDX mapping, scanning electron microscopy (SEM), transmission electron microscopy (TEM), brunauer-emmett- teller (BET), temperature-programmed desorption of ammonia (NH3-TPD), and fourier transform infrared spectroscopy of pyridine (pyridine-FTIR). Of all the transition metal phosphides MoP was formed at a lower reduction temperature, which resuited in smaller particle size that enhanced the overall surface area of the catalyst. The existence of weak, moderate, and Lewis acidic sites over MoP were responsible for its high tetralin selectivity (90%) and stability during the 100 h reaction on-stream in a fixed-bed reactor.展开更多
Ionic covalent organic framework(COF)materials with high specific surface areas and well-defined pore structures are desired for many applications yet seldom reported.Herein,we report a cationic pyridinium salt-based ...Ionic covalent organic framework(COF)materials with high specific surface areas and well-defined pore structures are desired for many applications yet seldom reported.Herein,we report a cationic pyridinium salt-based COF(PS-COF-1)with a Brunauer-Emmett-Teller(BET)surface area of 2703 m^(2) g^(-1),state-ofthe-art for an ionic COF.Aided by its ordered pore structure,chemical stability,and radiation resistance,PS-COF-1 showed exceptional adsorption properties toward aqueous ReO_(4)^(-)(1262 mg g^(-1))and ^(99)TcO_(4)^(-).Its adsorption performance surpassed its corresponding amorphous analogue.Importantly,PS-COF-1 exhibited fast adsorption kinetics,high adsorption capacities,and selectivity for ^(99)TcO_(4)^(-)and ReO_(4)^(-)at high ionic strengths,leading to the successful removal of ^(99)TcO_(4)^(-)under conditions relevant to low-activity waste streams at US legacy Hanford nuclear sites.In addition,PS-COF-1 can rapidly decontaminate ReO_(4)^(-)/^(99)TcO_(4)^(-)polluted potable water(~10 ppb)to drinking water level(0 ppb,part per billion)within 10 min.Density functional theory(DFT)calculations revealed PS-COF-1 has a strong affinity for ReO_(4)^(-)and ^(99)TcO_(4)^(-),thereby favoring adsorption of these low charge density anions over other common anions(e.g.,Cl^(-),NO_(3)^(-),SO_(4)^(2-),CO_(3)^(2-)).Our work demonstrates a novel cationic COF sorbent for selective radionuclide capture and legacy nuclear waste management.展开更多
Uranium extraction from seawater is of strategic significance for nuclear power generation.Amidoximebased functional adsorbents play indispensable roles in the recovery of seawater uranium with high efficiency.Neverth...Uranium extraction from seawater is of strategic significance for nuclear power generation.Amidoximebased functional adsorbents play indispensable roles in the recovery of seawater uranium with high efficiency.Nevertheless,balancing the adsorption capacity and selectivity is challenging in the presence of complicated interfering ions especially vanadium.Herein,a polyarylether-based covalent organic framework functionalized with open-chain amidoxime(COF-HHTF-AO)was synthesized with remarkable chemical stability and excellent crystallinity.Impressively,the adsorption capacity of COF-HHTF-AO towards uranium in natural seawater reached up to 5.12 mg/g,which is 1.61 times higher than that for vanadium.Detailed computational calculations revealed that the higher selectivity for uranium over vanadium originated from the specific bonding nature and coordination pattern with amidoxime.Combining enhanced adsorption capacity,excellent selectivity and ultrahigh stability,COF-HHTF-AO serves as a promising adsorbent for uranium extraction from the natural seawater.展开更多
文摘卷烟吸阻是卷烟设计制造中的核心指标。因涉及影响因素多且具有复杂的非线性特性,无论是基于多孔介质流体力学模型还是基于大量工程实践的经验模型,均无法定量指导设计与生产,至今卷烟吸阻仍以实验测试数据为评价依据。针对卷烟生产过程中产生的大量检测数据及数据的复杂多源和不断更迭的特性,提出了一种利用生产历史积累数据,通过K均值聚类算法清洗数据消除样本差异,结合自适应套索方法对输入变量进行降维处理和辅助变量选择,并利用选择稳定性评估对过程进行一致性约束,在多源数据和滚动过程一致选择出与吸阻原理模型匹配的关键影响指标,并将其作为径向基函数神经网络(RBFNN,radical basis function netural network)的输入,建立吸阻的推理预测模型。经验证,预测模型的均方误差为0.004,相对误差率控制在3%以内,实现了生产场景下的吸阻快速预测。
基金Sponsored by the Natural Science Foundation of Liaoning Province in China(Grant No.20022106).
文摘The numerical calculation method is widely used in the evaluation of slope stability,but it cannot take the randomness and fuzziness into account that exist in rock and soil engineering objectively.The fuzzy optimization theory is thus introduced to the evaluation of slope stability by this paper and a method of fuzzy optimal selection of similar slopes is put forward to analyze slope stability.By comparing the relative membership degrees that the evaluated object sample of slope is similar to the source samples of which the stabilities are detected clearly,the source sample with the maximal relative membership degree will be chosen as the best similar one to the object sample,and the stability of the object sample can be evaluated by that of the best similar source sample.In the process many uncertain influential factors are considered and characteristics and knowledge of the source samples are obtained.The practical calculation indicates that it can achieve good results to evaluate slope stability by using this method.
基金supported by the NSFC key project under Grant No.61731017the 111 project under Grant No.111-2-14
文摘A clustering scheme based on pure V2V communications has two prominent issues i.e. broadcast storm and network disconnection. The application of the fifth generation(5G) technology to vehicular networks is an optimal choice due to its wide coverage and low latency features. In this paper, a Multihop Moving Zone(MMZ) clustering scheme is proposed by combining IEEE 802.11p with the 3rd Generation Partnership Project(3GPP) 5G cellular technology. In MMZ, vehicles are clustered up-to three hops using V2V communications based on IEEE 802.11 p aiming to reduce excessive cellular hand-off cost. While the zonal heads(ZHs) i.e. cluster heads(CHs) are selected by cellular-V2X(C-V2X) on the basis of multi-metrics i.e. relative speed, distance and link life time(LLT). The main goal of MMZ is to form stable clusters achieving high packet delivery and low latency. The simulation results using ns3 show that, 5G wide range technology significantly improves the stability of MMZ in term of ZH duration and change rate. The average Data Packet Delivery Ratio(DPDR) and E2E latency are also improved as compared to the existing clustering schemes.
基金supported by the National Natural Science Foundation of China(21676262,21506207,21606221)the Key Research Program of Frontier Sciences,CAS(QYZDB-SSW-JSC040)~~
文摘The low‐temperature hydrothermal stabilities of Cu‐SAPO‐34samples with various Si contents and Cu loadings were systematically investigated.The NH3oxidation activities and NH3‐selective catalytic reduction(SCR)activities(mainly the low‐temperature activities)of all the Cu‐SAPO‐34catalysts declined after low‐temperature steam treatment(LTST).These results show that the texture and acid density of Cu‐SAPO‐34can be better preserved by increasing the Cu loading,although the hydrolysis of Si-O-Al bonds is inevitable.The stability of Cu ions and the stability of the SAPO framework were positively correlated at relatively low Cu loadings.However,a high Cu loading(e.g.,3.67wt%)resulted in a significant decrease in the number of isolated Cu ions.Aggregation of CuO particles also occurred during the LTST,which accounts for the decreasing NH3oxidation activities of the catalysts.Among the catalysts,Cu‐SAPO‐34with a high Si content and medium Cu content(1.37wt%)showed the lowest decrease in NH3‐SCR because its Cu2+content was well retained and its acid density was well preserved.
文摘An input-output signal selection based on Phillips-Heffron model of a parallel high voltage alternative current/high voltage direct current(HVAC/HVDC) power system is presented to study power system stability. It is well known that appropriate coupling of inputs-outputs signals in the multivariable HVDC-HVAC system can improve the performance of designed supplemetary controller. In this work, different analysis techniques are used to measure controllability and observability of electromechanical oscillation mode. Also inputs–outputs interactions are considered and suggestions are drawn to select the best signal pair through the system inputs-outputs. In addition, a supplementary online adaptive controller for nonlinear HVDC to damp low frequency oscillations in a weakly connected system is proposed. The results obtained using MATLAB software show that the best output-input for damping controller design is rotor speed deviation as out put and phase angle of rectifier as in put. Also response of system equipped with adaptive damping controller based on HVDC system has appropriate performance when it is faced with faults and disturbance.
文摘The high-temperature(HT) and low-temperature(LT) hydrothermal stabilities of molecular-sieve-based catalysts are important for the selective catalytic reduction of NOx with ammonia(NH3-SCR). In this paper, we report a catalyst, Cu2+ loading SAPO-17, synthesized using cyclohexylamine(CHA), which is commercially available and inexpensive and is utilized in NH3-SCR reduction for the first time. After systematic investigations on the optimization of Si and Cu2+ contents, it was concluded that Cu-SAPO-17-8.0%-0.22 displays favorable catalytic performance, even after being heated at 353 K for 24 h and at 973 K for 16 h. Moreover, the locations of CHAs, host–guest interaction and the Bronsted acid sites were explored by Rietveld refinement against powder X-ray diffraction data of as-made SAPO-17-8.0%. The refinement results showed that two CHAs exist within one eri cage and that the protonated CHA forms a hydrogen bond with O4, which indicates that the proton bonding with O4 will form the Bronsted acid site after the calcination.
文摘The research process,main contents,methods and conclusions for some major engineering geological problems of the Three Gorges Project (TGP) are reviewed and introduced,including dam site selection,regional tectonic stability and seismic activity,stability of reservoir bank and reservoir-induced earthquake.Meanwhile,the above mentioned engineering geological problems are evaluated according to the preliminary test results since TGP operation and impoundment in 2003.
基金supported financially by the Purolite Company and the Chinese National Natural Science Foundation (20674069)
文摘The performance of ion-exchange resin catalysts during isobutene (IB) dimerization was investigated under different IB contents,temperatures and liquid-volume hourly space velocity (LHSV) using a plug flow reactor in the absence of any selectivity enhancing component.High IB content and temperature resulted in a high conversion and C12 selectivity bu low C8 selectivity.The influence of LHSV was related with the IB content:LHSV had great effect at high IB content,while the performance of ion-exchange resin changed little with LHSV if IB content was low.The effect of water on the stability of resins was also studied.Desulfonation was observed during the C4 dimerization reaction when water was added to the feed.Chlorinated resin was more stable than conventional polystyrene-based resins during the test.
基金This paper was partially supported by NSFC,CAS,RGC of Hong Kong and Ministry of Education and Technology of Japan.
文摘Various mathematical models have been commonly used in time series analysis and forecasting. In these processes, academic researchers and business practitioners often come up against two important problems. One is whether to select an appropriate modeling approach for prediction purposes or to combine these different individual approaches into a single forecast for the different/dissimilar modeling approaches. Another is whether to select the best candidate model for forecasting or to mix the various candidate models with different parameters into a new forecast for the same/similar modeling approaches. In this study, we propose a set of computational procedures to solve the above two issues via two judgmental criteria. Meanwhile, in view of the problems presented in the literature, a novel modeling technique is also proposed to overcome the drawbacks of existing combined forecasting methods. To verify the efficiency and reliability of the proposed procedure and modeling technique, the simulations and real data examples are conducted in this study.The results obtained reveal that the proposed procedure and modeling technique can be used as a feasible solution for time series forecasting with multiple candidate models.
基金financial support from the Special Funds of the National Natural Science Foundation of China(21127011)National High Technology Research and Development Program of China(2011AA050606)National Natural Science Foundation of China(Petrochemical Joint Fund,U1162106)
文摘The present study reports a highly selective and stable catalytic approach for producing tetralin, an important chemical, solvent, and H2 storage material. Transition metal phosphides (MOP, Ni2P, Co2P, and Fe2P) were prepared by wet impregnation and temperature-programmed reduction and characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), EDX mapping, scanning electron microscopy (SEM), transmission electron microscopy (TEM), brunauer-emmett- teller (BET), temperature-programmed desorption of ammonia (NH3-TPD), and fourier transform infrared spectroscopy of pyridine (pyridine-FTIR). Of all the transition metal phosphides MoP was formed at a lower reduction temperature, which resuited in smaller particle size that enhanced the overall surface area of the catalyst. The existence of weak, moderate, and Lewis acidic sites over MoP were responsible for its high tetralin selectivity (90%) and stability during the 100 h reaction on-stream in a fixed-bed reactor.
基金supported by the National Natural Science Foundation of China(U2167218 and 22006036)the National Key Research and Development Program of China(2017YFA0207002 and 2018YFC1900105)+2 种基金the Science Challenge Project(TZ2016004)the Beijing Outstanding Young Scientist Program(H.Y.and X.W.)the Robert A.Welch Foundation(B-0027)(S.M.)。
文摘Ionic covalent organic framework(COF)materials with high specific surface areas and well-defined pore structures are desired for many applications yet seldom reported.Herein,we report a cationic pyridinium salt-based COF(PS-COF-1)with a Brunauer-Emmett-Teller(BET)surface area of 2703 m^(2) g^(-1),state-ofthe-art for an ionic COF.Aided by its ordered pore structure,chemical stability,and radiation resistance,PS-COF-1 showed exceptional adsorption properties toward aqueous ReO_(4)^(-)(1262 mg g^(-1))and ^(99)TcO_(4)^(-).Its adsorption performance surpassed its corresponding amorphous analogue.Importantly,PS-COF-1 exhibited fast adsorption kinetics,high adsorption capacities,and selectivity for ^(99)TcO_(4)^(-)and ReO_(4)^(-)at high ionic strengths,leading to the successful removal of ^(99)TcO_(4)^(-)under conditions relevant to low-activity waste streams at US legacy Hanford nuclear sites.In addition,PS-COF-1 can rapidly decontaminate ReO_(4)^(-)/^(99)TcO_(4)^(-)polluted potable water(~10 ppb)to drinking water level(0 ppb,part per billion)within 10 min.Density functional theory(DFT)calculations revealed PS-COF-1 has a strong affinity for ReO_(4)^(-)and ^(99)TcO_(4)^(-),thereby favoring adsorption of these low charge density anions over other common anions(e.g.,Cl^(-),NO_(3)^(-),SO_(4)^(2-),CO_(3)^(2-)).Our work demonstrates a novel cationic COF sorbent for selective radionuclide capture and legacy nuclear waste management.
基金supported by the Science Challenge Project(TZ2016004)the National Natural Key Research and Development Program of China(2018YFC1900105 and 2017YFA0207002)Beijing Outstanding Young Scientist Program。
文摘Uranium extraction from seawater is of strategic significance for nuclear power generation.Amidoximebased functional adsorbents play indispensable roles in the recovery of seawater uranium with high efficiency.Nevertheless,balancing the adsorption capacity and selectivity is challenging in the presence of complicated interfering ions especially vanadium.Herein,a polyarylether-based covalent organic framework functionalized with open-chain amidoxime(COF-HHTF-AO)was synthesized with remarkable chemical stability and excellent crystallinity.Impressively,the adsorption capacity of COF-HHTF-AO towards uranium in natural seawater reached up to 5.12 mg/g,which is 1.61 times higher than that for vanadium.Detailed computational calculations revealed that the higher selectivity for uranium over vanadium originated from the specific bonding nature and coordination pattern with amidoxime.Combining enhanced adsorption capacity,excellent selectivity and ultrahigh stability,COF-HHTF-AO serves as a promising adsorbent for uranium extraction from the natural seawater.